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Development of a Pseudocellular System to Quantify Specific Interactions Determining the G-Quadruplex Function in Cells J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Hisae Tateishi-Karimata, Keiko Kawauchi, Shuntaro Takahashi, Naoki Sugimoto
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Superconductivity and Charge-Density-Wave-Like Transition in Th2Cu4As5 J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Shaohua Liu, Qingchen Duan, Baizhuo Li, Jiaojiao Meng, Wuzhang Yang, Yi Liu, Yi-Qiang Lin, Si-Qi Wu, Jiayi Lu, Jin-Ke Bao, Yusen Xiao, Xinyu Zhao, Yu-Xue Mei, Yuping Sun, Shugang Tan, Qiang Jing, Dan Yu, Ruidan Zhong, Yongliang Chen, Yong Zhao, Zhi Ren, Cao Wang, Guang-Han Cao
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How Concerted Are Ionic Hops in Inorganic Solid-State Electrolytes? J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Cibrán López, Riccardo Rurali, Claudio Cazorla
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Red Light–Blue Light Chromoselective C(sp2)–X Bond Activation by Organic Helicenium-Based Photocatalysis J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Md Mubarak Hossain, Aslam C. Shaikh, Ramandeep Kaur, Thomas L. Gianetti
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Platform for Multiple Isotope Labeling via Carbon–Sulfur Bond Exchange J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Bouchaib Mouhsine, Maylis Norlöff, Juba Ghouilem, Antoine Sallustrau, Frédéric Taran, Davide Audisio
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Light in a Heartbeat: Bond Scission by a Single Photon above 800 nm J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Marina Russo, Hana Janeková, Debora Meier, Melanie Generali, Peter Štacko
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Ion Mobility Mass Spectrometry for Large Synthetic Molecules: Expanding the Analytical Toolbox J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Niklas Geue, Richard E. P. Winpenny, Perdita E. Barran
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Ion Pairing Enables Targeted Prodrug Activation via Red Light Photocatalysis: A Proof-of-Concept Study with Anticancer Gold Complexes J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Zhiying Xie, Bei Cao, Jing Zhao, Moyi Liu, Yuhan Lao, Hejiang Luo, Zhi Zhong, Xiaolin Xiong, Wei Wei, Taotao Zou
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Mechanistic Investigation into Single-Electron Oxidative Addition of Single-Atom Cu(I)-N4 Site: Revealing the Cu(I)–Cu(II)–Cu(I) Catalytic Cycle in Photochemical Hydrophosphinylation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Guanglin Wang, Yichang Liu, Xiangyu Zhang, Xupeng Zong, Xu Zhang, Kun Zheng, Dan Qu, Li An, Xiaotian Qi, Zaicheng Sun
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Isolation of Cationic η3-Allenylnickel(II) Key Intermediate Complexes: Origins of Enantioselectivity and Regioselectivity in Nickel(0)-Catalyzed Asymmetric Propargylic Substitutions J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Yusuke Miyazaki, Kenichi Michigami, Masato Ohashi
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In Situ Visualization of RNA-Specific Sialylation on Living Cell Membranes to Explore N-Glycosylation Sites J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Huipu Liu, Xuemei Li, Yi Ren, Yuanjiao Yang, Yunlong Chen, Huangxian Ju
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Field-Induced Antiferroelectric–Ferroelectric Transformation in Organometallic Perovskite Displaying Giant Negative Electrocaloric Effect J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Shiguo Han, Jie Bie, Wei Fa, Shuang Chen, Liwei Tang, Wuqian Guo, Haojie Xu, Yu Ma, Yi Liu, Xitao Liu, Zhihua Sun, Junhua Luo
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Engineering the Coordination Environment of Ir Single Atoms with Surface Titanium Oxide Amorphization for Superior Chlorine Evolution Reaction J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Jiaxian Wang, Long Zhao, Yunjie Zou, Jie Dai, Qian Zheng, Xingyue Zou, Lufa Hu, Wei Hou, Ruizhao Wang, Kaiyuan Wang, Yanbiao Shi, Guangming Zhan, Yancai Yao, Lizhi Zhang
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Pyrogenic Carbon Degradation by Galvanic Coupling with Sprayed Seawater Microdroplets J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Ruolan Zhang, Zhenyuan Zhang, Xuke Chen, Jichun Jiang, Lei Hua, Xiuquan Jia, Rui Bao, Feng Wang
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Enantioselective Divergent Syntheses of Diterpenoid Pyrones J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-18 Yunpeng Ji, Yaqian Liu, Weiqiang Guan, Chuning Guo, Hongli Jia, Benke Hong, Houhua Li
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Unprotected Organic Cations─The Dilemma of Highly Li-Concentrated Ionic Liquid Electrolytes J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-17 Shaoning Zhang, Shengan Wu, Jinkwang Hwang, Kazuhiko Matsumoto, Rika Hagiwara
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A Biomimetic Synthetic Strategy Can Provide Keratan Sulfate I and II Oligosaccharides with Diverse Fucosylation and Sulfation Patterns J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-17 Yunfei Wu, Gerlof P. Bosman, Digantkumar Chapla, Chin Huang, Kelley W. Moremen, Robert P. de Vries, Geert-Jan Boons
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Construction of Ideal One-Dimensional Spin Chains by Topochemical Dehydration/Rehydration Route J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Yanhong Wang, Peng Fu, Hiroshi Takatsu, Cédric Tassel, Naoaki Hayashi, Jiaojiao Cao, Thierry Bataille, Hyun-Joo Koo, Zhongwen Ouyang, Myung-Hwan Whangbo, Hiroshi Kageyama, Hongcheng Lu
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Insights into Molecular Diversity within the FUS/EWS/TAF15 Protein Family: Unraveling Phase Separation of the N-Terminal Low-Complexity Domain from RNA-Binding Protein EWS J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-16 Courtney N. Johnson, Kandarp A. Sojitra, Erich J. Sohn, Alma K. Moreno-Romero, Antoine Baudin, Xiaoping Xu, Jeetain Mittal, David S. Libich
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A Compact Reprogrammed Genetic Code for De Novo Discovery of Proteolytically Stable Thiopeptides J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-16 Alexander A. Vinogradov, Yue Zhang, Keisuke Hamada, Shunsuke Kobayashi, Kazuhiro Ogata, Toru Sengoku, Yuki Goto, Hiroaki Suga
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Epitaxial Growth of Two-Dimensional MWW Zeolite J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-16 Hongbin Li, Chunna Zhang, Qiang Lin, Feng Lin, Taishi Xiao, Kexin Yan, Bin Shen, Hongbin Zhang, Yi Tang, Zhengzong Sun
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Photoelectrochemical CO2 Reduction to CO Enabled by a Molecular Catalyst Attached to High-Surface-Area Porous Silicon J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Xiaofan Jia, Eleanor Stewart-Jones, Jose L. Alvarez-Hernandez, Gabriella P. Bein, Jillian L. Dempsey, Carrie L. Donley, Nilay Hazari, Madison N. Houck, Min Li, James M. Mayer, Hannah S. Nedzbala, Rebecca E. Powers
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Control of Zeolite Local Polarity toward Efficient Xenon/Krypton Separation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Shanshan Liu, Xin Lian, Bin Yue, Shutao Xu, Guangjun Wu, Yuchao Chai, Yinghui Zhang, Landong Li
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Unraveling a Concerted Proton-Coupled Electron Transfer Pathway in Atomically Precise Gold Nanoclusters J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Kai-Yuan Huang, Zhi-Qiang Yang, Ming-Rui Yang, Tian-Shui Chen, Shurong Tang, Wei-Ming Sun, Qiaofeng Yao, Hao-Hua Deng, Wei Chen, Jianping Xie
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Synthesis of Collidine from Dinitrogen via a Tungsten Nitride J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Lukas Eberle, Joachim Ballmann
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Multifunctional Biocatalysts for Organic Synthesis J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Thomas W. Thorpe, James R. Marshall, Nicholas J. Turner
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Critical Role of Aromatic C(sp2)–H in Boosting Lithium-Ion Storage J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Jiabiao Lian, Gokila Subburam, Sherif A. El-Khodary, Kai Zhang, Bobo Zou, Juan Wang, Chuan Wang, Jianmin Ma, Xiaojun Wu
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A Nonheme Iron(III) Superoxide Complex Leads to Sulfur Oxygenation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Sudha Yadav, Vishal Yadav, Maxime A. Siegler, Pierre Moënne-Loccoz, Guy N. L. Jameson, David P. Goldberg
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Formation of Polymer-like Nanochains with Short Lithium–Lithium Distances in a Water-in-Salt Electrolyte J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Kateryna Goloviznina, Alessandra Serva, Mathieu Salanne
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Incorporation of the 99TcO4– Anion within the Ag24(C≡CtBu)204+ Cluster Unveiling the Unique Shell-to-Core Charge Transfer J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Ye Tao, Ni Luan, Chunyun Yang, Jiayu Sun, Kai Li, Xing Dai, Hailong Zhang, Zhifang Chai, Shuao Wang, Yaxing Wang
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Multicomponent Synthesis of α-Branched Amines via a Zinc-Mediated Carbonyl Alkylative Amination Reaction J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Joseph M. Phelps, Roopender Kumar, James D. Robinson, John C. K. Chu, Nils J. Flodén, Sarah Beaton, Matthew J. Gaunt
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Quantification and Mechanistic Investigation of the Spontaneous H2O2 Generation at the Interfaces of Salt-Containing Aqueous Droplets J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Maria Angelaki, Yoan Carreira Mendes Da Silva, Sébastien Perrier, Christian George
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Heterovalent Metal Pair Sites on Metal–Organic Framework Ordered Macropores for Multimolecular Co-Activation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Zhong Zhang, Xujiao Ma, Yameng Li, Nana Ma, Ming Wang, Wei Liu, Jiahui Peng, Yiwei Liu, Yadong Li
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Metal-Free Homogeneous O2 Reduction by an Iminium-Based Electrocatalyst J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Emma N. Cook, Anna E. Davis, Michael K. Hilinski, Charles W. Machan
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Nanodrug Hijacking Blood Transferrin for Ferroptosis-Mediated Cancer Treatment J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Shuyue Zhang, Xiao Wu, Xiaoming Liao, Shiyong Zhang
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Molecular Mechanism for Converting Carbon Dioxide Surrounding Water Microdroplets Containing 1,2,3-Triazole to Formic Acid J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Ke Gong, Yifan Meng, Richard N. Zare, Jing Xie
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Methane–H2S Reforming Catalyzed by Carbon and Metal Sulfide Stabilized Sulfur Dimers J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Yong Wang, Wenru Zhao, Xiaofeng Chen, Yinjie Ji, Xilei Zhu, Xiaomai Chen, Donghai Mei, Hui Shi, Johannes A. Lercher
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High-Throughput Synthesis, Purification, and Application of Alkyne-Functionalized Discrete Oligomers J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Junfeng Chen, Vittal Bhat, Craig J. Hawker
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All-SnTe-Based Thermoelectric Power Generation Enabled by Stepwise Optimization of n-Type SnTe J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-15 Tao Hong, Bingchao Qin, Yongxin Qin, Shulin Bai, Ziyuan Wang, Qian Cao, Zhen-Hua Ge, Xiao Zhang, Xiang Gao, Li-Dong Zhao
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Single-Atom Catalysts Mediated Bioorthogonal Modulation of N6-Methyladenosine Methylation for Boosting Cancer Immunotherapy J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Mengyu Sun, Xuemeng Liu, Zhengwei Liu, Wenting Zhang, Guangming Li, Jinsong Ren, Xiaogang Qu
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Atomically Precise Single-Site Catalysts via Exsolution in a Polyoxometalate–Metal–Organic-Framework Architecture J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Zhihengyu Chen, S. M. Gulam Rabbani, Qin Liu, Wentuan Bi, Jiaxin Duan, Zhiyong Lu, Neil M. Schweitzer, Rachel B. Getman, Joseph T. Hupp, Karena W. Chapman
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Total Syntheses of Phorbol and 11 Tigliane Diterpenoids and Their Evaluation as HIV Latency-Reversing Agents J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Ayumu Watanabe, Masanori Nagatomo, Akira Hirose, Yuto Hikone, Naoki Kishimoto, Satoshi Miura, Tae Yasutake, Towa Abe, Shogo Misumi, Masayuki Inoue
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Correlating π–π Stacking of Aromatic Diammoniums with Stability and Dimensional Reduction of Dion–Jacobson 2D Perovskites J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-13 Yang Liu, Junxue Guo, Hongpeng Zhou, Can Li, Xin Guo
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Molecular Electronics: From Nanostructure Assembly to Device Integration J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Meng Yuan, Yuchen Qiu, Hanfei Gao, Jiangang Feng, Lei Jiang, Yuchen Wu
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High Molar Mass Polycarbonates as Closed-Loop Recyclable Thermoplastics J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Gloria Rosetto, Fernando Vidal, Thomas M. McGuire, Ryan W. F. Kerr, Charlotte K. Williams
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Three-Dimensional Homochiral Covalent Organic Frameworks with Intrinsic Chiral qzd Topology J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Xing Kang, Cheng Cheng, Xu Chen, Jinqiao Dong, Yan Liu, Yong Cui
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Stereoselective Ring Expansion Metathesis Polymerization with Cationic Molybdenum Alkylidyne N-Heterocyclic Carbene Complexes J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Patrick Probst, Jonas Groos, Dongren Wang, Alexander Beck, Katrin Gugeler, Johannes Kästner, Wolfgang Frey, Michael R. Buchmeiser
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Chemical Probes to Interrogate the Extreme Environment of Mosquito Larval Guts J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Lindsay E. Guzmán, Anjalee N. Wijetunge, Brendan F. Riske, Brooke B. Massani, Michael A. Riehle, John C. Jewett
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Carrier Transport Switching of Ferroelectric BTBT Derivative J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Kohei Sambe, Takashi Takeda, Norihisa Hoshino, Wakana Matsuda, Kazuki Shimada, Kanae Tsujita, Shingo Maruyama, Shunsuke Yamamoto, Shu Seki, Yuji Matsumoto, Tomoyuki Akutagawa
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Discovery of a Fungal P450 with an Unusual Two-Step Mechanism for Constructing a Bicyclo[3.2.2]nonane Skeleton J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Huibin Xu, Zhenbo Yuan, Sai Yang, Zengping Su, Xiao-Dong Hou, Zhiwei Deng, Yan Zhang, Yijian Rao
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Selective Reduction of Aqueous Nitrate to Ammonium with an Electropolymerized Chromium Molecular Catalyst J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-11 Maiko J. Askari, Jeremy D. Kallick, Charles C. L. McCrory
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Triple para-Functionalized Cations and Neutral Radicals of Enantiopure Diaza[4]helicenes J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Bibiana Fabri, Tiziana Funaioli, Lucas Frédéric, Christina Elsner, Enrica Bordignon, Francesco Zinna, Lorenzo Di Bari, Gennaro Pescitelli, Jérôme Lacour
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Biodegradable Lipid-Modified Poly(Guanidine Thioctic Acid)s: A Fortifier of Lipid Nanoparticles to Promote the Efficacy and Safety of mRNA Cancer Vaccines J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Kai Yang, Bing Bai, Jiaqi Lei, Xinyang Yu, Shaolong Qi, Yangfan Wang, Feihe Huang, Zaizai Tong, Guocan Yu
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Charge Regulation at the Nanoscale as Evidenced from Light-Responsive Nanoemulsions J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Dana Glikman, Leonard Wyszynski, Valentin Lindfeld, Sebastian Hochstädt, Michael Ryan Hansen, Johannes Neugebauer, Monika Schönhoff, Björn Braunschweig
Emulsions are indispensable in everyday life, and the demand for emulsions’ diversity and control of properties is therefore substantial. As emulsions possess a high internal surface area, an understanding of the oil/water (o/w) interfaces at the molecular level is fundamental but often impaired by experimental limitations to probe emulsion interfaces in situ. Here, we have used light-responsive surfactants
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One-Dimensional High-Entropy Compounds J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Junyi Du, Shuai Liu, Ye Liu, Geng Wu, Xiaocheng Liu, Wujun Zhang, Yong Zhang, Xun Hong, Qingwen Li, Lixing Kang
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CO2-Promoted Electrocatalytic Reduction of Chlorinated Hydrocarbons J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Chungseok Choi, Soonho Kwon, Yuanzuo Gao, Seonjeong Cheon, Jing Li, Fabian Menges, William A. Goddard III, Hailiang Wang
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Efficient Sodium Transmembrane Permeation through Helically Folded Nanopores with Natural Channel-Like Ion Selectivity J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Lei Zhang, Jun Tian, Ze Lin, Zeyuan Dong
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Unraveling Spatially Dependent Hydrophilicity and Reactivity of Confined Carbocation Intermediates during Methanol Conversion over ZSM-5 Zeolite J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Chao Wang, Mingji Zheng, Min Hu, Wenjin Cai, Yueying Chu, Qiang Wang, Jun Xu, Feng Deng
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Precision Cellulose from Living Cationic Polymerization of Glucose 1,2,4-Orthopivalates J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Lianqian Wu, Arjun Chowdhury, Zefeng Zhou, Kuiru Chen, Wenqi Wang, Jia Niu
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Structure Sensitivity of Metal Catalysts Revealed by Interpretable Machine Learning and First-Principles Calculations J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-03-14 Wu Shu, Jiancong Li, Jin-Xun Liu, Chuwei Zhu, Tairan Wang, Li Feng, Runhai Ouyang, Wei-Xue Li