-
Collaborating with the code of life Chem (IF 23.5) Pub Date : 2024-04-29 Jeffrey Gorman
Download : Download high-res image (494KB) Download : Download full-size imageJeffrey Gorman received his master’s degree in chemistry from Imperial College London under the supervision of Prof. Iain McCulloch and spent a year in industry at Merck KGaA, where he pursued the development of organic photovoltaics. He received his PhD in physics in 2020 under the direction of Prof. Sir Richard Friend at
-
Quantitative and qualitative analysis of nitrogen species in carbon at the ppm level Chem (IF 23.5) Pub Date : 2024-04-29 Takeharu Yoshii, Ginga Nishikawa, Viki Kumar Prasad, Shunsuke Shimizu, Ryo Kawaguchi, Rui Tang, Koki Chida, Nobuhiro Sato, Ryota Sakamoto, Kouhei Takatani, Daniel Moreno-Rodríguez, Peter Škorňa, Eva Scholtzová, Robert Karoly Szilagyi, Hirotomo Nishihara
-
Neglected no longer: Selective C–H activation of the non-resonant C3 benzylic position of pyridine Chem (IF 23.5) Pub Date : 2024-04-29 Katelyn Le, Jeffrey F. Van Humbeck
Unlike the 2- and 4-positions, benzylic C(sp3)–H sites in 3-alkylpyridines have no direct communication with the pyridine nitrogen and are not susceptible to traditional forms of catalysis. In this issue of Chem, Stahl and co-workers disclose an effective benzylic chlorination of 3-alkylpyridines, providing valuable access to this resistant position.
-
Cinchona-alkaloid-catalyzed asymmetric formation of sulfinamides and sulfinate esters Chem (IF 23.5) Pub Date : 2024-04-24 Charles Bell, Michael C. Willis
The asymmetric synthesis of sulfur(IV) functionalities presents a substantial challenge given that direct catalytic methods are underexplored. In this issue of Chem, Chi and co-workers use quinine as the chiral catalyst for the asymmetric conversion of sulfinate salts to high-value sulfinate esters and sulfinamides.
-
Radical chlorination of non-resonant heterobenzylic C‒H bonds and high-throughput diversification of heterocycles Chem (IF 23.5) Pub Date : 2024-04-24 Dung L. Golden, Kaitlyn M. Flynn, Santeri Aikonen, Christopher M. Hanneman, Dipannita Kalyani, Shane W. Krska, Robert S. Paton, Shannon S. Stahl
-
Biomimetic synthesis of pallavicinin, neopallavicinin, pallambins A–D, pallaviambins A/B, and pallavicinolides B/C Chem (IF 23.5) Pub Date : 2024-04-24 Lijun Chen, Peng Chen, Xiwu Zhang, Yu Zhang, Yanxing Jia
-
Catalyst: Curtailing the scalable supply of fentanyl by using chemical AI Chem (IF 23.5) Pub Date : 2024-04-23 Barbara Mikulak-Klucznik, Tomasz Klucznik, Wiktor Beker, Martyna Moskal, Bartosz A. Grzybowski
-
Conjugated ladder polymers: Advances from syntheses to applications Chem (IF 23.5) Pub Date : 2024-04-23 James Shao-Jiun Yang, Lei Fang
-
Reaction: Don’t hate the player in chemical AI; hate the game Chem (IF 23.5) Pub Date : 2024-04-23 Gordon Broderick
-
Reaction: Navigating the promises and perils of AI-powered drug synthesis Chem (IF 23.5) Pub Date : 2024-04-23 Rick A. Bright
Rick Bright is the chief executive of Bright Global Health and former deputy assistant secretary for preparedness and response and director of BARDA at the US Department of Health and Human Services. An international expert in biodefense, emergency preparedness, pharmaceutical innovation, and public health, Dr. Bright is a member of the Council on Foreign Relations, senior fellow of the Foreign Policy
-
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling Chem (IF 23.5) Pub Date : 2024-04-22 Le Shi, Zhangyi Xiong, Hao Wang, Honghao Cao, Zhijie Chen
-
A copper-masked monosubstituted carbene as a general transmetalating agent toward stable carbene complexes Chem (IF 23.5) Pub Date : 2024-04-22 María Álvarez, Francisco Villalba, Martina Casciotti, Francisco Molina, Giuseppe Sciortino, Agustí Lledós, Ana C. Albéniz, Tomás R. Belderrain, Pedro J. Pérez
-
Electrochemical synthesis of formamide by C–N coupling with amine and CO2 with a high faradaic efficiency of 37.5% Chem (IF 23.5) Pub Date : 2024-04-19 Yun Fan, Tianyang Liu, Yunhui Yan, Zhongcheng Xia, Yuxuan Lu, Yuping Pan, Ruiqi Wang, Dianke Xie, Zhonghuan Zhu, Ta Thi Thuy Nga, Chung-Li Dong, Yu Jing, Yafei Li, Shuangyin Wang, Yuqin Zou
-
Machine learning-guided yield optimization for palladaelectro-catalyzed annulation reaction Chem (IF 23.5) Pub Date : 2024-04-19 Xiaoyan Hou, Shuwen Li, Johanna Frey, Xin Hong, Lutz Ackermann
-
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser Chem (IF 23.5) Pub Date : 2024-04-18 Lauren E. McNamara, Christopher Melnychuk, Jan-Niklas Boyn, Sophie W. Anferov, David A. Mazziotti, Richard D. Schaller, John S. Anderson
-
Curved plane increases the d vacancy population of Pd for green production of cyclohexanone Chem (IF 23.5) Pub Date : 2024-04-17 Yang Yang, Guohua Yao, Xiaojuan Zhu, Meiqi Gao, Lili Wang, Shunlin Li, Xuerong Li, Xuezhi Duan, De Chen, Weimin Yang, Ying Wan
-
A multistate memory cell based on electrochromic metallo-organic assemblies Chem (IF 23.5) Pub Date : 2024-04-16 Yonatan Hamo, Julia Narevicius, Elad Gaver, Mark A. Iron, Michal Lahav, Milko E. van der Boom
-
Tuning the selectivity of CO2 hydrogenation to alcohols by crystal structure engineering Chem (IF 23.5) Pub Date : 2024-04-15 Haiyan Yang, Zhangqian Wei, Jian Zhang, Yaru Dang, Shenggang Li, Xianni Bu, Zixuan Zhou, Chenfan Gong, Hao Wang, Jiong Li, Yang Liu, Yong Yang, Tianci Xiao, Chengyuan Liu, Yuhan Sun, Peng Gao
-
Spin-coupled electron densities of iron-sulfur cluster imaged by in situ serial Laue diffraction Chem (IF 23.5) Pub Date : 2024-04-13 Zhong Ren, Fan Zhang, Weijia Kang, Cong Wang, Heewhan Shin, Xiaoli Zeng, Semini Gunawardana, Kalinga Bowatte, Norbert Krauß, Tilman Lamparter, Xiaojing Yang
-
Rapid, multiplexed, and enzyme-free nucleic acid detection using programmable aptamer-based RNA switches Chem (IF 23.5) Pub Date : 2024-04-12 Zhaoqing Yan, Amit Eshed, Anli A. Tang, Nery R. Arevalos, Zachary M. Ticktin, Soma Chaudhary, Duo Ma, Griffin McCutcheon, Yudan Li, Kaiyue Wu, Sanchari Saha, Jonathan Alcantar-Fernandez, Jose L. Moreno-Camacho, Abraham Campos-Romero, James J. Collins, Peng Yin, Alexander A. Green
-
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture Chem (IF 23.5) Pub Date : 2024-04-12 Patrick W. Fritz, Timur Ashirov, Ali Coskun
-
Macroscopic spiral rotation of microscopic objects induced by nanoscale rotaxane dynamics Chem (IF 23.5) Pub Date : 2024-04-11 Alexander Ryabchun, Romain Jamagne, Javier Echavarren, Manee Patanapongpibul, Liang Zhang, Nathalie Katsonis, David A. Leigh
-
-
Pyridine-terminated small molecular photocatalyst for water reduction Chem (IF 23.5) Pub Date : 2024-04-09 Kun Tang, Jiang-Yang Shao, Jikun Li, Shumu Li, Jian-Hong Tang, Ran Duan, Jiannian Yao, Yu-Wu Zhong
-
Revealing hidden non-centrosymmetry in globally centrosymmetric 2D halide perovskites Chem (IF 23.5) Pub Date : 2024-04-09 Willa Mihalyi-Koch, Songhao Guo, Zhenbang Dai, Dongxu Pan, David P. Lafayette, Jason M. Scheeler, Kyana M. Sanders, Simon J. Teat, John C. Wright, Xujie Lü, Andrew M. Rappe, Song Jin
-
Construction of single-crystal 3D covalent organic framework with three crossing sets of 2D sheets entanglement Chem (IF 23.5) Pub Date : 2024-04-09 Baoqiu Yu, Shubo Geng, Xu Ding, Xin Zhou, Yucheng Jin, Hailong Wang, Xiao Wang, Tianyu Zheng, Zhenjie Zhang, Jianzhuang Jiang
-
Sculpting photoproducts with DNA origami Chem (IF 23.5) Pub Date : 2024-04-05 Jeffrey Gorman, Stephanie M. Hart, Torsten John, Maria A. Castellanos, Dvir Harris, Molly F. Parsons, James L. Banal, Adam P. Willard, Gabriela S. Schlau-Cohen, Mark Bathe
-
An old polymer class revisited: Versatile, degradable, non-alternating polyketones Chem (IF 23.5) Pub Date : 2024-04-05 Lejla Čamdžić, Cassandra A. Haynes, Erin E. Stache
-
Aqueous electrocatalytic small-molecule valorization trilogy Chem (IF 23.5) Pub Date : 2024-04-04 Yuxuan Lu, Mingyu Chen, Yuqing Wang, Chunming Yang, Yuqin Zou, Shuangyin Wang
-
Narrowing the reactivity gap between transition metals and silicon for catalysis Chem (IF 23.5) Pub Date : 2024-04-02 Samuel R. Baird, Eric Rivard
In this issue of Chem, Inoue and co-workers uncover distinct migratory insertion, oxidative addition, and reductive elimination steps at a single silicon center during the activation of aryl isocyanides (Ar–NC) by an acyclic imino(silyl)silylene; thus, this work offers a peak into the future use of silicon in catalysis.
-
Bioorthogonally activated reactive species for target identification Chem (IF 23.5) Pub Date : 2024-04-02 Surached Siriwongsup, Anna M. Schmoker, Scott B. Ficarro, Jarrod A. Marto, Justin Kim
-
Targeting metalloimmunology via a nanoenabled approach to effectively treating solid tumors Chem (IF 23.5) Pub Date : 2024-03-29 Mengmeng Qin, Zhenhan Feng, Huan Meng
The significance of metals in activating antitumoral immune responses has sparked widespread interest. In this issue of Chem, Bao et al. present preclinical success with ethylenediaminetetraacetate-loaded layered double hydroxide (EDTA/LDH) nanoparticles, which are capable of stimulating antitumoral immune reactions and promoting the infiltration of immune cells into solid tumors by inducing calcium
-
Implantable and bio-compatible Na-O2 battery Chem (IF 23.5) Pub Date : 2024-03-27 Yang Lv, Xizheng Liu, Jiucong Liu, Shuang Wu, Shuangyong Sun, Pingli Wu, Yonggang Wang, Yi Ding
-
Supramolecular umpolung: Converting electron-rich resorcin[4]arenes into potent CH-bonding anion receptors and transporters Chem (IF 23.5) Pub Date : 2024-03-27 Esma R. Abdurakhmanova, Debashis Mondal, Hanna Jędrzejewska, Piotr Cmoch, Oksana Danylyuk, Michał J. Chmielewski, Agnieszka Szumna
-
Reactant-induced activation over amorphous metal-metalloid electrocatalysts for HMF electrooxidation Chem (IF 23.5) Pub Date : 2024-03-27 Hao Guan Xu, Xin Ran Ning, Jia Yue Zhao, Hao Yang Lin, Huai Qin Fu, Siyu Wang, Yong Guo, Haoran Wu, Minghui Zhu, Hai Yang Yuan, Peng Fei Liu, Hua Gui Yang
-
Enhanced oxidation potential of holes under visible light for organic photo-oxidation Chem (IF 23.5) Pub Date : 2024-03-27 Jiaqi Zhao, Li-Zhu Wu, Tierui Zhang
The balance between oxidation potential and spectral response range is a critical consideration in photocatalysis. In this issue of Chem, Zhu and co-workers present a general approach in which Fe3+ additives initiate the generation of intra-valence band holes in organic conjugated molecular crystals under visible-light irradiation. This approach significantly enhances the oxidation potential for photocatalytic
-
A general atomically dispersed copper catalyst for C–O, C–N, and C–C bond formation by carbene insertion reactions Chem (IF 23.5) Pub Date : 2024-03-20 Qiang Wang, Haifeng Qi, Yujing Ren, Zhusong Cao, Kathrin Junge, Rajenahally V. Jagadeesh, Matthias Beller
-
A new hope for crystallization Chem (IF 23.5) Pub Date : 2024-03-20 James T.F. Dobson, Hannah Kurz, Jonathan R. Nitschke
Recent work from Dan Li and co-workers, published in the March issue of Chem, reports the application of a cyclic trinuclear AgI pyrazolate complex (Ag3Pz3) as an adaptive crystallization agent for a series of difficult-to-crystallize organic molecules. Ag3Pz3 was also employed for the direct structural elucidation of organic compounds from mixtures in addition to natural products in crude extracts
-
Catalysis paves the way to a new era of the petrochemical industry Chem (IF 23.5) Pub Date : 2024-03-20 Lichen Liu, Annai Liu
The energy revolution stimulates the world’s energy landscape to transit from fossil-fuel-based systems to new ones based on renewable energy sources. Threatened by climate change just as the world is, the petrochemical industry faces the need for restructuring. In this article, we discuss collaborations between academia and the petrochemical industry toward upgrading current catalysis technologies
-
From G-protein-coupled receptors to solute carriers—mass spectrometry informs dynamics, function, and regulation Chem (IF 23.5) Pub Date : 2024-03-20 Haiping Tang, Carol V. Robinson
-
Deciphering reactive intermediates in electrooxidative coupling of indoles through real-time mass spectrometry Chem (IF 23.5) Pub Date : 2024-03-19 Xing Liu, Jianxiong Chen, Zhenwei Wei, Hong Yi, Aiwen Lei
-
Enantioselective sulfinylation of alcohols and amines by condensation with sulfinates Chem (IF 23.5) Pub Date : 2024-03-15 Minghong Liao, Yonggui Liu, Hongyan Long, Qin Xiong, Xiaokang Lv, Zhongfu Luo, Xingxing Wu, Yonggui Robin Chi
-
Identification of Cu0/Cu+/Cu0 interface as superior active sites for CO2 electroreduction to C2+ in neutral condition Chem (IF 23.5) Pub Date : 2024-03-15 Xi Cao, Shan Ren, Xue Zhang, Qikui Fan, Qingqing Chen, Jian Yang, Junjie Mao
-
Harnessing charge relocation: A novel approach for the remote difunctionalization of alkenes Chem (IF 23.5) Pub Date : 2024-03-15 Weiyu Kong, Guoyin Yin, Yangyang Li
The field of alkene difunctionalization is undergoing vigorous advancement with a primary focus on two key aspects: the innovation of new reagents and the exploration of novel reaction sites. Recently in Nature, Maulide and co-workers reported a general and synthetically useful methodology for the stereodivergent 1,3- difunctionalization of unactivated alkenes via a charge-relocation pathway.
-
-
Dinitrogen Coupling to a Terpyridine-Molybdenum Chromophore Is Switched on by Fermi Resonance Chem (IF 23.5) Pub Date : 2024-03-14 Shahnawaz R. Rather, Máté J. Bezdek, Paul J. Chirik, Gregory D. Scholes
-
Selectivity control in CO2 hydrogenation to one-carbon products Chem (IF 23.5) Pub Date : 2024-03-13 Jingting Hu, Yafeng Cai, Jinghao Xie, Deshan Hou, Liang Yu, Dehui Deng
-
Genetically enabling phosphorus fluoride exchange click chemistry in proteins Chem (IF 23.5) Pub Date : 2024-03-05 Li Cao, Bingchen Yu, Shanshan Li, Pan Zhang, Qingke Li, Lei Wang
-
Advancing beyond Sabatier: Strategies for dynamic synthetic catalysis Chem (IF 23.5) Pub Date : 2024-03-04 Matthias Filez, Jolien Dendooven, Maarten B.J. Roeffaers, Christophe Detavernier
-
Tactics for uncovering intermediates in nickel Kumada cross-coupling catalysis Chem (IF 23.5) Pub Date : 2024-02-29 Julio Lloret-Fillol
-
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles Chem (IF 23.5) Pub Date : 2024-02-29 Sunil Pulletikurti, Kollery S. Veena, Mahipal Yadav, Ashok A. Deniz, Ramanarayanan Krishnamurthy
-
Ligand-enabled Z-retentive Tsuji-Trost reaction Chem (IF 23.5) Pub Date : 2024-02-29 Jiandong Liu, Wen-Bin Cao, Shu-Li You
-
An evolutionary algorithm for interpretable molecular representations Chem (IF 23.5) Pub Date : 2024-02-29 Philipp M. Pflüger, Marius Kühnemund, Felix Katzenburg, Herbert Kuchen, Frank Glorius
-
A multifunctional drug delivery system based on switchable peptide-stabilized emulsions Chem (IF 23.5) Pub Date : 2024-02-29 Daniel Boas, Alexander van Teijlingen, Zohar Shpilt, Deborah E. Shalev, Edit Y. Tshuva, Tell Tuttle, Meital Reches
-
Leveraging bismuth immiscibility to create highly concave noble-metal nanoparticles Chem (IF 23.5) Pub Date : 2024-02-28 Melissa E. King, Yuting Xu, Porvajja Nagarajan, Noah L. Mason, Anthony J. Branco, Connor S. Sullivan, Samantha M. Silva, Sangmin Jeong, Fanglin Che, Michael B. Ross
-
A prebiotic Krebs cycle analog generates amino acids with H2 and NH3 over nickel Chem (IF 23.5) Pub Date : 2024-02-27 Harpreet Kaur, Sophia A. Rauscher, Emilie Werner, Youngdong Song, Jing Yi, Wahnyalo Kazöne, William F. Martin, Harun Tüysüz, Joseph Moran
-
Fusobacterium nucleatum-mimicking nanovehicles to overcome chemoresistance for breast cancer treatment by eliminating tumor-colonizing bacteria Chem (IF 23.5) Pub Date : 2024-02-23 Linfu Chen, Jingjing Shen, Zheyu Kang, Zemin Zhang, Zixuan Zheng, Lin Zhang, Zhisheng Xiao, Qiang Zhang, Huapan Fang, Jun Zhou, Yudong Wang, Yang Yang, Zhuang Liu, Qian Chen
-
Multivalency unlocked: The unique redox traits of the ‟tripak” system Chem (IF 23.5) Pub Date : 2024-02-23 Nayanthara Asok, Thomas Baumgartner
-
Acids catalyze initiation processes in radical polymerization Chem (IF 23.5) Pub Date : 2024-02-23 Nathan Boase, Christopher Barner-Kowollik
-
Rational structure transformation triggered by titanium modulation in metal-organic frameworks for efficient flue gas utilization Chem (IF 23.5) Pub Date : 2024-02-23 Shu-Cong Fan, Jia-Wen Wang, Wenyu Yuan, Peng Zhang, Ying Wang, Quan-Guo Zhai