Picoscale materials engineering Nat. Rev. Mater. Pub Date : 2017-09-19 Sohrab Ismail-Beigi, Frederick J. Walker, Ankit S. Disa, Karin M. Rabe, Charles H. Ahn
The way in which atoms bond to form a material — in particular the pattern of bond lengths and angles — is the fundamental determinant of the properties of the resulting material. Functional materials often derive their properties from alterable or reversible bond distortions at the picometre length scale that modify the electronic configuration. By considering several examples, we discuss how picoscale bond perturbations can be used to achieve specific materials properties. In particular, we examine the orbital engineering demonstrated in nickelates, the functional properties obtained in perovskite superlattices and the influence of interfacial effects on the high superconductive transition temperature of iron selenide. Moreover, we emphasize the relation between band topology and picoscale distortions in transition metal dichalcogenides and the effect of the excitation of lattice modes on materials properties. We use these examples to highlight how the combination of first-principles methods, materials growth techniques that allow control of the composition of individual atomic layers and state-of-the-art methods to characterize or dynamically excite picoscale bond distortions provides a powerful approach for discovering rules and concepts for picoscale materials engineering.
Biomaterials: Don't stress over it Nat. Rev. Mater. Pub Date : 2017-09-19 Christine-Maria Horejs
Biomaterials: Don't stress over itNature Reviews Materials, Published online: 19 September 2017; doi:10.1038/natrevmats.2017.67
Super-resolution microscopy: Always look on the bright side of the fluorophore Nat. Rev. Mater. Pub Date : 2017-09-19 Giulia Pacchioni
Super-resolution microscopy: Always look on the bright side of the fluorophoreNature Reviews Materials, Published online: 19 September 2017; doi:10.1038/natrevmats.2017.65
Tools for translation: non-viral materials for therapeutic mRNA delivery Nat. Rev. Mater. Pub Date : 2017-09-12 Khalid A. Hajj, Kathryn A. Whitehead
In recent years, messenger RNA (mRNA) has come into the spotlight as a versatile therapeutic with the potential to prevent and treat a staggering range of diseases. Billions of dollars have been invested in the commercial development of mRNA drugs, with ongoing clinical trials focused on vaccines (for example, influenza and Zika viruses) and cancer immunotherapy (for example, myeloma, leukaemia and glioblastoma). Although significant progress has been made in the design of in vitro-transcribed mRNA that retains potency while minimizing unwanted immune responses, the widespread use of mRNA drugs requires the development of safe and effective drug delivery vehicles. In this Review, we provide an overview of the field of mRNA therapeutics and describe recent advances in the development of synthetic materials that encapsulate and deliver mRNA payloads.
Tetradymites as thermoelectrics and topological insulators Nat. Rev. Mater. Pub Date : 2017-09-05 Joseph P. Heremans, Robert J. Cava, Nitin Samarth
Tetradymites are M2X3 compounds — in which M is a group V metal, usually Bi or Sb, and X is a group VI anion, Te, Se or S — that crystallize in a rhombohedral structure. Bi2Se3, Bi2Te3 and Sb2Te3 are archetypical tetradymites. Other mixtures of M and X elements produce common variants, such as Bi2Te2Se. Because tetradymites are based on heavy p-block elements, strong spin-orbit coupling greatly influences their electronic properties, both on the surface and in the bulk. Their surface electronic states are a cornerstone of frontier work on topological insulators. The bulk energy bands are characterized by small energy gaps, high group velocities, small effective masses and band inversion near the centre of the Brillouin zone. These properties are favourable for high-efficiency thermoelectric materials but make it difficult to obtain an electrically insulating bulk, which is a requirement of topological insulators. This Review outlines recent progress made in bulk and thin-film tetradymite materials for the optimization of their properties both as thermoelectrics and as topological insulators.
Design and synthesis of polyoxometalate-framework materials from cluster precursors Nat. Rev. Mater. Pub Date : 2017-08-31 Laia Vilà-Nadal, Leroy Cronin
Inorganic oxide materials are used in semiconductor electronics, ion exchange, catalysis, coatings, gas sensors and as separation materials. Although their synthesis is well understood, the scope for new materials is reduced because of the stability limits imposed by high-temperature processing and top-down synthetic approaches. In this Review, we describe the derivatization of polyoxometalate (POM) clusters, which enables their assembly into a range of frameworks by use of organic or inorganic linkers. Additionally, bottom-up synthetic approaches can be used to make metal oxide framework materials, and the features of the molecular POM precursors are retained in these structures. Highly robust all-inorganic frameworks can be made using metal-ion linkers, which combine molecular synthetic control without the need for organic components. The resulting frameworks have high stability, and high catalytic, photochemical and electrochemical activity. Conceptually, these inorganic oxide materials bridge the gap between zeolites and metal–organic frameworks (MOFs) and establish a new class of all-inorganic POM frameworks that can be designed using topological and reactivity principles similar to MOFs.
Computationally guided discovery of thermoelectric materials Nat. Rev. Mater. Pub Date : 2017-08-22 Prashun Gorai, Vladan Stevanović, Eric S. Toberer
The potential for advances in thermoelectric materials, and thus solid-state refrigeration and power generation, is immense. Progress so far has been limited by both the breadth and diversity of the chemical space and the serial nature of experimental work. In this Review, we discuss how recent computational advances are revolutionizing our ability to predict electron and phonon transport and scattering, as well as materials dopability, and we examine efficient approaches to calculating critical transport properties across large chemical spaces. When coupled with experimental feedback, these high-throughput approaches can stimulate the discovery of new classes of thermoelectric materials. Within smaller materials subsets, computations can guide the optimal chemical and structural tailoring to enhance materials performance and provide insight into the underlying transport physics. Beyond perfect materials, computations can be used for the rational design of structural and chemical modifications (such as defects, interfaces, dopants and alloys) to provide additional control on transport properties to optimize performance. Through computational predictions for both materials searches and design, a new paradigm in thermoelectric materials discovery is emerging.
Drug delivery: Ultrasound soothes the pain Nat. Rev. Mater. Pub Date : 2017-08-16 Adam Brotchie
Drug delivery: Ultrasound soothes the pain Nature Reviews Materials, Published online: 16 August 2017; doi:10.1038/natrevmats.2017.58
Lithium batteries: A protective film Nat. Rev. Mater. Pub Date : 2017-08-16 Alison Stoddart
Lithium batteries: A protective film Nature Reviews Materials, Published online: 16 August 2017; doi:10.1038/natrevmats.2017.61
Lithium-ion batteries: Stress relief for silicon Nat. Rev. Mater. Pub Date : 2017-08-08 Alison Stoddart
Lithium-ion batteries: Stress relief for silicon Nature Reviews Materials, Published online: 8 August 2017; doi:10.1038/natrevmats.2017.57
Graphene-based smart materials Nat. Rev. Mater. Pub Date : 2017-08-01 Xiaowen Yu, Huhu Cheng, Miao Zhang, Yang Zhao, Liangti Qu, Gaoquan Shi
The high specific surface area and the excellent mechanical, electrical, optical and thermal properties of graphene make it an attractive component for high-performance stimuli-responsive or ‘smart’ materials. Complementary to these inherent properties, functionalization or hybridization can substantially improve the performance of these materials. Typical graphene-based smart materials include mechanically exfoliated perfect graphene, chemical vapour deposited high-quality graphene, chemically modified graphene (for example, graphene oxide and reduced graphene oxide) and their macroscopic assemblies or composites. These materials are sensitive to a range of stimuli, including gas molecules or biomolecules, pH value, mechanical strain, electrical field, and thermal or optical excitation. In this Review, we outline different graphene-based smart materials and their potential applications in actuators, chemical or strain sensors, self-healing materials, photothermal therapy and controlled drug delivery. We also introduce the working mechanisms of graphene-based smart materials and discuss the challenges facing the realization of their practical applications.
Particulate photocatalysts for overall water splitting Nat. Rev. Mater. Pub Date : 2017-08-01 Shanshan Chen, Tsuyoshi Takata, Kazunari Domen
The conversion of solar energy to chemical energy is a promising way of generating renewable energy. Hydrogen production by means of water splitting over semiconductor photocatalysts is a simple, cost-effective approach to large-scale solar hydrogen synthesis. Since the discovery of the Honda–Fujishima effect, considerable progress has been made in this field, and numerous photocatalytic materials and water-splitting systems have been developed. In this Review, we summarize existing water-splitting systems based on particulate photocatalysts, focusing on the main components: light-harvesting semiconductors and co-catalysts. The essential design principles of the materials employed for overall water-splitting systems based on one-step and two-step photoexcitation are also discussed, concentrating on three elementary processes: photoabsorption, charge transfer and surface catalytic reactions. Finally, we outline challenges and potential advances associated with solar water splitting by particulate photocatalysts for future commercial applications.
Low-bandgap conjugated polymers enabling solution-processable tandem solar cells Nat. Rev. Mater. Pub Date : 2017-07-25 Gang Li, Wei-Hsuan Chang, Yang Yang
The technology of polymer-based organic photovoltaic (OPV) cells has made great progress in the past decade, with the power conversion efficiency increasing from just a few per cent to around 12%, and the stability increasing from hours to years. One of the important milestones in this progress has been the invention of infrared-absorbing low-bandgap polymers, which allows the OPV cells to form effective tandem structures for harvesting near-infrared energy from the solar spectrum. In this Review, we focus on the progress in low-bandgap conjugated polymers and several tandem OPV cells enabled by these low-bandgap polymers. Specifically, we cover polymer-based tandem solar cells; hybrid tandem solar cells combining polymers with hydrogenated amorphous silicon; and unconventional solar cells. For each of these technologies, we address the challenges and offer our perspectives for future development.
Polymers: Phosphorus analogues of rubber Nat. Rev. Mater. Pub Date : 2017-07-25 Alison Stoddart
Polymers: Phosphorus analogues of rubber Nature Reviews Materials, Published online: 25 July 2017; doi:10.1038/natrevmats.2017.55
The chemistry of metal–organic frameworks for CO2 capture, regeneration and conversion Nat. Rev. Mater. Pub Date : 2017-07-25 Christopher A. Trickett, Aasif Helal, Bassem A. Al-Maythalony, Zain H. Yamani, Kyle E. Cordova, Omar M. Yaghi
The carbon dioxide challenge is one of the most pressing problems facing our planet. Each stage in the carbon cycle — capture, regeneration and conversion — has its own materials requirements. Recent work on metal–organic frameworks (MOFs) demonstrated the potential and effectiveness of these materials in addressing this challenge. In this Review, we identify the specific structural and chemical properties of MOFs that have led to the highest capture capacities, the most efficient separations and regeneration processes, and the most effective catalytic conversions. The interior of MOFs can be designed to have coordinatively unsaturated metal sites, specific heteroatoms, covalent functionalization, other building unit interactions, hydrophobicity, porosity, defects and embedded nanoscale metal catalysts with a level of precision that is crucial for the development of higher-performance MOFs. To realize a total solution, it is necessary to use the precision of MOF chemistry to build more complex materials to address selectivity, capacity and conversion together in one material.
Active matter at the interface between materials science and cell biology Nat. Rev. Mater. Pub Date : 2017-07-20 Daniel Needleman, Zvonimir Dogic
The remarkable processes that characterize living organisms, such as motility, self-healing and reproduction, are fuelled by a continuous injection of energy at the microscale. The field of active matter focuses on understanding how the collective behaviours of internally driven components can give rise to these biological phenomena, while also striving to produce synthetic materials composed of active energy-consuming components. The synergistic approach of studying active matter in both living cells and reconstituted systems assembled from biochemical building blocks has the potential to transform our understanding of both cell biology and materials science. This methodology can provide insight into the fundamental principles that govern the dynamical behaviours of self-organizing subcellular structures, and can lead to the design of artificial materials and machines that operate away from equilibrium and can thus attain life-like properties. In this Review, we focus on active materials made of cytoskeletal components, highlighting the role of active stresses and how they drive self-organization of both cellular structures and macroscale materials, which are machines powered by nanomachines.
Chiroplasmonic DNA-based nanostructures Nat. Rev. Mater. Pub Date : 2017-07-20 Alessandro Cecconello, Lucas V. Besteiro, Alexander O. Govorov, Itamar Willner
Chiroplasmonic properties of nanoparticles, organized using DNA-based nanostructures, have attracted both theoretical and experimental interest. Theory suggests that the circular dichroism spectra accompanying chiroplasmonic nanoparticle assemblies are controlled by the sizes, shapes, geometries and interparticle distances of the nanoparticles. In this Review, we present different methods to assemble chiroplasmonic nanoparticle or nanorod systems using DNA scaffolds, and we discuss the operations of dynamically reconfigurable chiroplasmonic nanostructures. The chiroplasmonic properties of the different systems are characterized by circular dichroism and further supported by high-resolution transmission electron microscopy or cryo-transmission electron microscopy imaging and theoretical modelling. We also outline the applications of chiroplasmonic assemblies, including their use as DNA-sensing platforms and as functional systems for information processing and storage. Finally, future perspectives in applying chiroplasmonic nanoparticles as waveguides for selective information transfer and their use as ensembles for chiroselective synthesis are discussed. Specifically, we highlight the upscaling of the systems to device-like configurations.
Spin qubits: Useful defects in silicon carbide Nat. Rev. Mater. Pub Date : 2017-07-11 Giulia Pacchioni
Spin qubits: Useful defects in silicon carbide Nature Reviews Materials, Published online: 11 July 2017; doi:10.1038/natrevmats.2017.52
Wood: a construction material for tall buildings Nat. Rev. Mater. Pub Date : 2017-07-11 Guido Wimmers
Wood: a construction material for tall buildings Nature Reviews Materials, Published online: 11 July 2017; doi:10.1038/natrevmats.2017.51 Wood has great potential as a building material, because it is strong and lightweight, environmentally friendly and can be used in prefabricated buildings. However, only changes in building codes will make wood competitive with steel and concrete.
Understanding the physical properties of hybrid perovskites for photovoltaic applications Nat. Rev. Mater. Pub Date : 2017-07-04 Jinsong Huang, Yongbo Yuan, Yuchuan Shao, Yanfa Yan
New photovoltaic materials have been searched for in the past decades for clean and renewable solar energy conversion with an objective of reducing the levelized cost of electricity (that is, the unit price of electricity over the course of the device lifetime). An emerging family of semiconductor materials — organic–inorganic halide perovskites (OIHPs) — are the focus of the photovoltaic research community owing to their use of low cost, nature-abundant raw materials, low-temperature and scalable solution fabrication processes, and, in particular, the very high power conversion efficiencies that have been achieved within the short time of their development. In this Review, we summarize and critically assess the most recent advances in understanding the physical properties of both 3D and low-dimensional OIHPs that favour a small open-circuit voltage deficit and high power conversion efficiency. Several prominent topics in this field on the unique properties of OIHPs are surveyed, including defect physics, ferroelectricity, exciton dissociation processes, carrier recombination lifetime and photon recycling. The impact of ion migration on solar cell efficiency and stability are also critically analysed. Finally, we discuss the remaining challenges in the commercialization of OIHP photovoltaics.
Computational development of the nanoporous materials genome Nat. Rev. Mater. Pub Date : 2017-07-04 Peter G. Boyd, Yongjin Lee, Berend Smit
There is currently a push towards big data and data mining in materials research to accelerate discovery. Zeolites, metal–organic frameworks and other related crystalline porous materials are not immune to this phenomenon, as evidenced by the proliferation of porous structure databases and computational gas-adsorption screening studies over the past decade. The endeavour to identify the best materials for various gas separation and storage applications has led not only to thousands of synthesized structures, but also to the development of algorithms for building hypothetical materials. The materials databases assembled with these algorithms contain a much wider range of complex pore structures than have been synthesized, with the reasoning being that we have discovered only a small fraction of realizable structures and expanding upon these will accelerate rational design. In this Review, we highlight the methods developed to build these databases, and some of the important outcomes from large-scale computational screening studies.
Acoustic metasurfaces: Ultrathin sound diffusers Nat. Rev. Mater. Pub Date : 2017-06-27 Giulia Pacchioni
Acoustic metasurfaces: Ultrathin sound diffusers Nature Reviews Materials, Published online: 27 June 2017; doi:10.1038/natrevmats.2017.47
Nature-inspired superwettability systems Nat. Rev. Mater. Pub Date : 2017-06-27 Mingjie Liu, Shutao Wang, Lei Jiang
Superwettability is a centuries-old concept that has been rediscovered in past decades, largely owing to new understanding of the mechanisms of special wetting phenomena in nature. Combining multiscale structures and surface chemical compositions is crucial to fabricate interfacial materials with superwettability. In this Review, we detail the historical development and summarize the various combined superwetting states in superwettability systems. Nature-inspired design principles of superwettable materials are also briefly introduced. Superwettability systems can be extended from 2D surfaces to 0D nanoparticles, 1D fibres and channels, and 3D integrated materials. We discuss new phenomena and the advantages that superwettability-based systems have for chemical reactions and materials fabrication, including emerging applications that utilize single extreme wetting states or that combine two extreme wetting states. Finally, we provide our perspective for future research directions.
Metamaterials: Graphene makes ceramics multifunctional Nat. Rev. Mater. Pub Date : 2017-06-20 Adam Brotchie
Metamaterials: Graphene makes ceramics multifunctional Nature Reviews Materials, Published online: 20 June 2017; doi:10.1038/natrevmats.2017.44
Engineering charge transport by heterostructuring solution-processed semiconductors Nat. Rev. Mater. Pub Date : 2017-05-23 Oleksandr Voznyy, Brandon R. Sutherland, Alexander H. Ip, David Zhitomirsky, Edward H. Sargent
Solution-processed semiconductor devices are increasingly exploiting heterostructuring — an approach in which two or more materials with different energy landscapes are integrated into a composite system. Heterostructured materials offer an additional degree of freedom to control charge transport and recombination for more efficient optoelectronic devices. By exploiting energetic asymmetry, rationally engineered heterostructured materials can overcome weaknesses, augment strengths and introduce emergent physical phenomena that are otherwise inaccessible to single-material systems. These systems see benefit and application in two distinct branches of charge-carrier manipulation. First, they influence the balance between excitons and free charges to enhance electron extraction in solar cells and photodetectors. Second, they promote radiative recombination by spatially confining electrons and holes, which increases the quantum efficiency of light-emitting diodes. In this Review, we discuss advances in the design and composition of heterostructured materials, consider their implementation in semiconductor devices and examine unexplored paths for future advancement in the field.
Antifouling surfaces: Peeling back the solid layers Nat. Rev. Mater. Pub Date : 2017-05-23 Angela Babi
Antifouling surfaces: Peeling back the solid layers Nature Reviews Materials, Published online: 23 May 2017; doi:10.1038/natrevmats.2017.35
Functional carbon nitride materials — design strategies for electrochemical devices Nat. Rev. Mater. Pub Date : 2017-05-31 Fabian K. Kessler, Yun Zheng, Dana Schwarz, Christoph Merschjann, Wolfgang Schnick, Xinchen Wang, Michael J. Bojdys
In the past decade, research in the field of artificial photosynthesis has shifted from simple, inorganic semiconductors to more abundant, polymeric materials. For example, polymeric carbon nitrides have emerged as promising materials for metal-free semiconductors and metal-free photocatalysts. Polymeric carbon nitride (melon) and related carbon nitride materials are desirable alternatives to industrially used catalysts because they are easily synthesized from abundant and inexpensive starting materials. Furthermore, these materials are chemically benign because they do not contain heavy metal ions, thereby facilitating handling and disposal. In this Review, we discuss the building blocks of carbon nitride materials and examine how strategies in synthesis, templating and post-processing translate from the molecular level to macroscopic properties, such as optical and electronic bandgap. Applications of carbon nitride materials in bulk heterojunctions, laser-patterned memory devices and energy storage devices indicate that photocatalytic overall water splitting on an industrial scale may be realized in the near future and reveal a new avenue of ‘post-silicon electronics’.
The first nanocar race Nat. Rev. Mater. Pub Date : 2017-06-06 Gwénaël Rapenne, Christian Joachim
The first nanocar race Nature Reviews Materials, Published online: 6 June 2017; doi:10.1038/natrevmats.2017.40 The first race involving molecular ‘cars’ stimulated technical advances in scanning tunnelling microscopy and provided insights in surface science and synthetic chemistry — it also attracted wide interest from the public.
Smart materials: To grip or not to grip Nat. Rev. Mater. Pub Date : 2017-06-06 Nina Meinzer
Smart materials: To grip or not to grip Nature Reviews Materials, Published online: 6 June 2017; doi:10.1038/natrevmats.2017.38
Magnetic skyrmions: advances in physics and potential applications Nat. Rev. Mater. Pub Date : 2017-06-13 Albert Fert, Nicolas Reyren, Vincent Cros
Magnetic skyrmions are small swirling topological defects in the magnetization texture. Their stabilization and dynamics depend strongly on their topological properties. In most cases, they are induced by chiral interactions between atomic spins in non-centrosymmetric magnetic compounds or in thin films with broken inversion symmetry. Skyrmions can be extremely small, with diameters in the nanometre range, and behave as particles that can be moved, created and annihilated, which makes them suitable for ‘abacus’-type applications in information storage and logic technologies. Until recently, skyrmions had been observed only at low temperature and, in most cases, under large applied magnetic fields. An intense research effort has led to the identification of thin-film and multilayer structures in which skyrmions are now stable at room temperature and can be manipulated by electrical currents. The development of skyrmion-based topological spintronics holds promise for applications in the mid-term furure, even though many challenges, such as the achievement of writing, processing and reading functionalities at room temperature and in all-electrical manipulation schemes, still lie ahead.
2D transition metal dichalcogenides Nat. Rev. Mater. Pub Date : 2017-06-13 Sajedeh Manzeli, Dmitry Ovchinnikov, Diego Pasquier, Oleg V. Yazyev, Andras Kis
Graphene is very popular because of its many fascinating properties, but its lack of an electronic bandgap has stimulated the search for 2D materials with semiconducting character. Transition metal dichalcogenides (TMDCs), which are semiconductors of the type MX2, where M is a transition metal atom (such as Mo or W) and X is a chalcogen atom (such as S, Se or Te), provide a promising alternative. Because of its robustness, MoS2 is the most studied material in this family. TMDCs exhibit a unique combination of atomic-scale thickness, direct bandgap, strong spin–orbit coupling and favourable electronic and mechanical properties, which make them interesting for fundamental studies and for applications in high-end electronics, spintronics, optoelectronics, energy harvesting, flexible electronics, DNA sequencing and personalized medicine. In this Review, the methods used to synthesize TMDCs are examined and their properties are discussed, with particular attention to their charge density wave, superconductive and topological phases. The use of TMCDs in nanoelectronic devices is also explored, along with strategies to improve charge carrier mobility, high frequency operation and the use of strain engineering to tailor their properties.
Synthetic biology: Phagocytic protocells Nat. Rev. Mater. Pub Date : 2017-06-13 Adam Brotchie
Synthetic biology: Phagocytic protocells Nature Reviews Materials, Published online: 13 June 2017; doi:10.1038/natrevmats.2017.41
External triggering and triggered targeting strategies for drug delivery Nat. Rev. Mater. Pub Date : 2017-05-09 Yanfei Wang, Daniel S. Kohane
Drug delivery systems that are externally triggered to release drugs and/or target tissues hold considerable promise for improving the treatment of many diseases by minimizing nonspecific toxicity and enhancing the efficacy of therapy. These drug delivery systems are constructed from materials that are sensitive to a wide range of external stimuli, including light, ultrasound, electrical and magnetic fields, and specific molecules. The responsiveness conferred by these materials allows the release of therapeutics to be triggered on demand and remotely by a physician or patient. In this Review, we describe the rationales for such systems and the types of stimuli that can be deployed, and provide an outlook for the field.
Rethinking cancer nanotheranostics Nat. Rev. Mater. Pub Date : 2017-05-09 Hongmin Chen, Weizhong Zhang, Guizhi Zhu, Jin Xie, Xiaoyuan Chen
Advances in nanoparticle synthesis and engineering have produced nanoscale agents affording both therapeutic and diagnostic functions that are often referred to by the portmanteau ‘nanotheranostics’. The field is associated with many applications in the clinic, especially in cancer management. These include patient stratification, drug-release monitoring, imaging-guided focal therapy and post-treatment response monitoring. Recent advances in nanotheranostics have expanded this notion and enabled the characterization of individual tumours, the prediction of nanoparticle–tumour interactions, and the creation of tailor-designed nanomedicines for individualized treatment. Some of these applications require breaking the dogma that a nanotheranostic must combine both therapeutic and diagnostic agents within a single, physical entity; instead, it can be a general approach in which diagnosis and therapy are interwoven to solve clinical issues and improve treatment outcomes. In this Review, we describe the evolution and state of the art of cancer nanotheranostics, with an emphasis on clinical impact and translation.
Plant physiology: Organic electronics take root Nat. Rev. Mater. Pub Date : 2017-05-09 Adam Brotchie
Plant physiology: Organic electronics take root Nature Reviews Materials, Published online: 9 May 2017; doi:10.1038/natrevmats.2017.32
Nanomedicine: Design and conquer Nat. Rev. Mater. Pub Date : 2017-05-16 Amos Matsiko
Nanomedicine: Design and conquer Nature Reviews Materials, Published online: 16 May 2017; doi:10.1038/natrevmats.2017.34
Cancer Immunotherapy: T cells tackle tumours Nat. Rev. Mater. Pub Date : 2017-05-03 Alison Stoddart
Cancer Immunotherapy: T cells tackle tumours Nature Reviews Materials, Published online: 3 May 2017; doi:10.1038/natrevmats.2017.27
Corrigendum: Printing, folding and assembly methods for forming 3D mesostructures in advanced materials Nat. Rev. Mater. Pub Date : 2017-05-03 Yihui Zhang, Fan Zhang, Zheng Yan, Qiang Ma, Xiuling Li, Yonggang Huang, John A. Rogers
Corrigendum: Printing, folding and assembly methods for forming 3D mesostructures in advanced materials Nature Reviews Materials, Published online: 3 May 2017; doi:10.1038/natrevmats.2017.29
Nanomedicine: Design and conquer Nat. Rev. Mater. Pub Date : 2017-05-16 com.springer.oscar.shared.search.Author@558d7b50[name=Amos Matsiko,email=none()]
Nanomedicine: Design and conquer
Plant physiology: Organic electronics take root Nat. Rev. Mater. Pub Date : 2017-05-09 com.springer.oscar.shared.search.Author@386b348d[name=Adam Brotchie,email=none()]
Plant physiology: Organic electronics take root
Rethinking cancer nanotheranostics Nat. Rev. Mater. Pub Date : 2017-05-09 com.springer.oscar.shared.search.Author@4973e1aa[name=Hongmin Chen,email=none()], com.springer.oscar.shared.search.Author@327f7c16[name=Weizhong Zhang,email=none()], com.springer.oscar.shared.search.Author@3aa21800[name=Guizhi Zhu,email=none()], com.springer.oscar.shared.search.Author@5b8c8c85[name=Jin Xie,email=some(firstname.lastname@example.org)], com.springer.oscar.shared.search.Author@d2458ef[name=Xiaoyuan Chen,email=some(email@example.com)]
Nanotheranostics are nanoscale agents with both therapeutic and diagnostic functions. Cancer nanotheranostics that can be used for characterizing individual tumours, understanding and predicting nanoparticle–tumour interactions, and tailoring nanomedicines for optimized treatment hold great potential to revolutionize drug research and development, and clinical oncology.
External triggering and triggered targeting strategies for drug delivery Nat. Rev. Mater. Pub Date : 2017-05-09 com.springer.oscar.shared.search.Author@44f20a91[name=Yanfei Wang,email=none()], com.springer.oscar.shared.search.Author@6eba7817[name=Daniel S. Kohane,email=some(firstname.lastname@example.org)]
Externally triggered drug delivery systems use both new and established materials that are sensitive to various stimuli. These systems provide opportunities to improve the treatment of many diseases.
Corrigendum: Printing, folding and assembly methods for forming 3D mesostructures in advanced materials Nat. Rev. Mater. Pub Date : 2017-05-03 com.springer.oscar.shared.search.Author@51ed39e1[name=Yihui Zhang,email=none()], com.springer.oscar.shared.search.Author@7e21e013[name=Fan Zhang,email=none()], com.springer.oscar.shared.search.Author@2a53dbc4[name=Zheng Yan,email=none()], com.springer.oscar.shared.search.Author@17946459[name=Qiang Ma,email=none()], com.springer.oscar.shared.search.Author@2f0e657b[name=Xiuling Li,email=none()], com.springer.oscar.shared.search.Author@5ede39f1[name=Yonggang Huang,email=none()], com.springer.oscar.shared.search.Author@6ae75415[name=John A. Rogers,email=none()]
Corrigendum: Printing, folding and assembly methods for forming 3D mesostructures in advanced materials
Cancer Immunotherapy: T cells tackle tumours Nat. Rev. Mater. Pub Date : 2017-05-03 com.springer.oscar.shared.search.Author@5e6543bc[name=Alison Stoddart,email=none()]
Cancer Immunotherapy: T cells tackle tumours
Erratum: Interplay between materials and microfluidics Nat. Rev. Mater. Pub Date : 2017-05-03 com.springer.oscar.shared.search.Author@21cd0b6[name=Xu Hou,email=none()], com.springer.oscar.shared.search.Author@2d2270b5[name=Yu Shrike Zhang,email=none()], com.springer.oscar.shared.search.Author@7d35cef8[name=Grissel Trujillo-de Santiago,email=none()], com.springer.oscar.shared.search.Author@9391a41[name=Mario Moisés Alvarez,email=none()], com.springer.oscar.shared.search.Author@6d44e2b0[name=João Ribas,email=none()], com.springer.oscar.shared.search.Author@53dd8075[name=Steven J. Jonas,email=none()], com.springer.oscar.shared.search.Author@4cd6f8[name=Paul S. Weiss,email=none()], com.springer.oscar.shared.search.Author@41662fa2[name=Anne M. Andrews,email=none()], com.springer.oscar.shared.search.Author@bfd045c[name=Joanna Aizenberg,email=none()], com.springer.oscar.shared.search.Author@341cf37e[name=Ali Khademhosseini,email=none()]
Erratum: Interplay between materials and microfluidics
Towards clinically translatable in vivo nanodiagnostics Nat. Rev. Mater. Pub Date : 2017-05-03 com.springer.oscar.shared.search.Author@52811813[name=Seung-min Park,email=none()], com.springer.oscar.shared.search.Author@226a36de[name=Amin Aalipour,email=none()], com.springer.oscar.shared.search.Author@4156192b[name=Ophir Vermesh,email=none()], com.springer.oscar.shared.search.Author@1202957c[name=Jung Ho Yu,email=none()], com.springer.oscar.shared.search.Author@481946af[name=Sanjiv S. Gambhir,email=some(email@example.com)]
Nanodiagnostics is a rapidly emerging field that leverages advances in nanobiotechnology to better visualize and diagnose disease. In this Review, we provide an overview of several clinically relevant imaging modalities and discuss how nanodiagnostics are enhancing their use.
Filtration membranes: The silk road Nat. Rev. Mater. Pub Date : 2017-04-25 com.springer.oscar.shared.search.Author@3b3645b4[name=Giulia Pacchioni,email=none()]
Filtration membranes: The silk road
Interplay between materials and microfluidics Nat. Rev. Mater. Pub Date : 2017-04-20 Xu Hou, Yu Shrike Zhang, Grissel Trujillo-de Santiago, Mario Moisés Alvarez, João Ribas, Steven J. Jonas, Paul S. Weiss, Anne M. Andrews, Joanna Aizenberg, Ali Khademhosseini
In this Review, the interplay between materials and microfluidics is examined, with the discussion focused on how recent advances in materials fabrication have expanded the frontiers of microfluidic platforms and how the new microfluidic capabilities are, in turn, furthering materials design.
Organic electronics: Under pressure Nat. Rev. Mater. Pub Date : 2017-03-14 Giulia Pacchioni
Organic electronics: Under pressure
Atomic force microscopy-based characterization and design of biointerfaces Nat. Rev. Mater. Pub Date : 2017-03-14 David Alsteens, Hermann E. Gaub, Richard Newton, Moritz Pfreundschuh, Christoph Gerber, Daniel J. Müller
Atomic force microscopy (AFM)-based approaches enable the characterization and manipulation of biological and synthetic biointerfaces, including tissues, cells, membranes, proteins, nucleic acid and functional materials. In this Review, the advantages and limitations of imaging, sensing, parameterizing and designing biointerfaces using AFM techniques are discussed.
Nonlinear photonic metasurfaces Nat. Rev. Mater. Pub Date : 2017-03-21 Guixin Li, Shuang Zhang, Thomas Zentgraf
Photonic metasurfaces can be used to control the polarization, phase and amplitude of light. Nonlinear metasurfaces enable giant nonlinear optical chirality, realization of the geometric Berry phase, wavefront engineering, and optical switching and modulation, and hold potential for on-chip applications.
Catalysis: Topology does the water splits Nat. Rev. Mater. Pub Date : 2017-04-04 Nina Meinzer
Catalysis: Topology does the water splits
3D bioimaging: Cells in gels Nat. Rev. Mater. Pub Date : 2017-04-04 Adam Brotchie
3D bioimaging: Cells in gels
Printing, folding and assembly methods for forming 3D mesostructures in advanced materials Nat. Rev. Mater. Pub Date : 2017-03-29 Yihui Zhang, Fan Zhang, Zheng Yan, Qiang Ma, Xiuling Li, Yonggang Huang, John A. Rogers
Emerging materials and methods for fabricating 3D micro- and nanostructures provide powerful capabilities of relevance across diverse areas of technology. This Review highlights the latest results and future trends associated with the most powerful methods in 3D printing, folding and assembly.
Hydrogels: A less than swell time Nat. Rev. Mater. Pub Date : 2017-03-29 Alison Stoddart
Hydrogels: A less than swell time
Erratum: Materials discovery at high pressures Nat. Rev. Mater. Pub Date : 2017-03-07 Lijun Zhang, Yanchao Wang, Jian Lv, Yanming Ma
Erratum: Materials discovery at high pressures
Aperiodic topological order in the domain configurations of functional materials Nat. Rev. Mater. Pub Date : 2017-03-07 Fei-Ting Huang, Sang-Wook Cheong
Domains and domain walls are relevant for the engineering of materials functionalities. In this Review, a new classification scheme for topological domain configurations is presented and applied to several materials, including multiferroics, ferroelectrics, transition metal dichalcogenides and magnetic superconductors.
Lithium battery chemistries enabled by solid-state electrolytes Nat. Rev. Mater. Pub Date : 2017-02-14 Arumugam Manthiram, Xingwen Yu, Shaofei Wang
This Review details recent advances in battery chemistries and systems enabled by solid electrolytes, including all-solid-state lithium-ion, lithium–air, lithium–sulfur and lithium–bromine batteries, as well as an aqueous battery concept with a mediator-ion solid electrolyte.
Biomaterials: Blazing trails Nat. Rev. Mater. Pub Date : 2017-02-21 Amos Matsiko
Biomaterials: Blazing trails
Materials discovery at high pressures Nat. Rev. Mater. Pub Date : 2017-02-21 Lijun Zhang, Yanchao Wang, Jian Lv, Yanming Ma
High pressure offers a unique degree of freedom for the creation of new materials, leading to new superconductors, superhard materials, high-energy-density materials and exotic chemical materials with unprecedented properties. This Review discusses these materials, along with recently developed theoretical and experimental methods for materials discovery at high pressures.
Some contents have been Reproduced by permission of The Royal Society of Chemistry.
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