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Synthesis, Characterization, and Polymorphism of [H3O][NbF6]: A Polar and Possibly Ferroelectric Oxonium Salt Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-18 Martin Möbs, Malte Sachs, Konstantin Rolheiser, Clemens Pietzonka, Antti Karttunen, Florian Kraus
[H3O][NbF6] was obtained from the controlled hydrolysis of NbF5 in anhydrous liquid HF. It adopts a polar, orthorhombic crystal structure with space group Iba2 (no. 45, oI88) at room temperature. A first-order phase transition at 137 K leads to a cubic non-centrosymmetric polymorph in space group I213 (no. 199, cI88). This low-temperature modification results from a distinct rotation of the [H3O]+
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Elucidating the Structure of the Eu‐EDTA Complex in Solution at various Protonation States Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-14 Gerra Licup, Thomas Summers, Josiane Sobrinho, Ana de Bettencourt-Dias, David Cantu
Ethylenediaminetetraacetic acid (EDTA), which has two amine and four carboxylate protonation sites, forms stable complexes with lanthanide ions. This work analyzes the coordination structure, in atomic resolution, of the Eu3+ ion complexed with EDTA in all its protonation states in aqueous solution. Eu‐EDTA complexes were modeled using classical molecular dynamics (MD) simulations using force field
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Solvent effects on the spin crossover properties of manganese (III) (sal‐N‐1,5,8,12) complexes Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-13 Shengze Zhao, Chang Liu, Haozhe Zhang, Huawei Zhou, Senyu Zhang, Chunyan Qin, Yonghua Li, Chao Tang, Shi Wang
The interplay of host−guest interactions and controlled modulation of spin‐crossover (SCO) behavior is one of the most exploited topics regarding data storage, molecular sensing, and optical technologies. This study examines the effect of solvents on the spin‐crossover (SCO) behavior of manganese(III) complexes [Mn(sal‐N‐1,5,8,12)]I•S (S = CH3OH, C2H5OH, CH3CN) (1) and [Mn(sal‐N‐1,5,8,12)]I3 (2), where
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Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-13 Laura Köring, Bernhard Birenheide, Felix Krämer, Jonas O. Wenzel, Roland Schoch, Martin Brehm, Frank Breher, Jan Henry Hakan Paradies
A series of substituted ferrocenyl boron derivatives was synthesized. The oxidation of the ferrocenyl unit resulted in a significant increase of the boron‐centered Lewis acidity. The neutral and cationic Lewis acids were characterized by NMR‐spectroscopy, crystal structure analysis and by computational methods. The new Lewis acids were then applied in the Meinwald rearrangement of epoxides, predominantly
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Molecular Complexes for Catalytic Ammonia Oxidation to Dinitrogen and the Cleavage of N−H Bonds Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-13 David N. Stephens, Michael Thomas Mock
The molecular complexes described herein use main‐group elements or transition metals to control the stoichiometric cleavage of N−H bonds of ammonia (NH3) and/or catalyze chemical and electrochemical NH3 oxidation to dinitrogen (N2). We highlight the phenomenon of coordination‐induced bond weakening and a variety of N−H bond cleavage mechanisms of NH3 including H atom abstraction, inter‐ and intra‐molecular
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High Inhibition for a CoII Tetrazole Bi‐pyrazole Dinuclear Complex against Fusarium Oxysporum f. sp. Albedinis Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-12 Yousra Bahjou, Smaail Radi, Mohamed El Massaoudi, Youssef Draoui, Nayarassery N. Adarsh, Haralampos N. Miras, Marilena Ferbinteanu, Koen Robeyns, Sabir Ouahhoud, Redouan Benabbes, Kai C. Hultzsch, Mariusz Wolff, Yann Garcia
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Rare Earth 2‐Methyl‐3‐furoate Complexes: Effect of Steric Hindrance on Corrosion Inhibitor Properties Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-12 Vidushi P. Vithana, Zhifang Guo, Glen B. Deacon, Peter C. Junk
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Synthesis, Structure and Antiferromagnetic Large‐Distance Long‐Range Coupling of the Ruthenate(V) Sr3(Ag2/3Sr1/6)RuO6 Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-11 Gohil S. Thakur, Michael Ruck
Black, air‐stable crystals of the new ruthenate(V) Sr3(Ag2/3Sr1/6)RuO6 were grown in a silver ampoule using KO2 as oxidative flux. X‐ray diffraction on single‐crystals revealed a rhombohedral structure with the space group R[[EQUATION]]c. Sr3(Ag2/3Sr1/6)RuO6 crystallizes isostructural to Sr4PtO6 in the K4CdCl6 structure type. By sharing trigonal faces, alternating [RuO6] octahedra and [(Ag2/3Sr1/6□1/6)O6]
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Unprecedented Pyrazine‐Bridged Guanidinate Rare Earth Complexes through a Bridge Splitting Reaction Path Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-11 Francis Delano, Selvan Demir
The development of reaction pathways and ancillary ligand scaffolds is essential in the pursuit of higher nuclearity rare earth metal clusters that are relevant in storage materials and catalysis. Guanidinate anions represent attractive ligands due to their high degree of customizability allowing for facile alterations of both their steric and electronic properties. Here, we demonstrate an unprecedented
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Water‐soluble μ‐oxo triruthenium compound of biological interest: H‐bonds network and interaction with HSA Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-11 Bruno Faria Abrantes Pinheiro, Nathan Campos Fernandes, Otavio Augusto Chaves, Javier Alcides Ellena, Mariana Santos de Queiroz, Antônio Cláudio Tedesco, João Honorato de Araújo Neto, Sofia Nikolaou
The water‐soluble compound [Ru3O(CH3COO)6(4‐ampy)3]Cl (1, 4‐ampy = 4‐aminopyridine) was evaluated in terms of its biologically relevant properties. Compound 1 participates in a hydrogen bonding network which includes the NH2 substituents of the ancillary ligands, methanol molecules, the Cl‐ counter‐ion, and a non‐conventional hydrogen bond with the neighboring 4‐ampy molecules' π‐cloud, as determined
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Reduced 2,2’‐Bipyridine Lanthanide Metallocenes Provide Access to Mono‐C5Me5 and Polyazide Complexes Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-07 Cary R. Stennett, Joseph W. Ziller, William J. Evans
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Novel Ruthenium‐based Nitrosyl Complexes: NO Donation and Vasorelaxant Potentials for Cardiovascular Therapeutics Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-07 Florêncio Sousa Gouveia Jr, Allandeiverson S Sousa, Renally B Silva, Danillo G Rocha, Edson H Teixeira, Manoel Odorico de Moraes Filho, Francisco Vagnaldo F. Jamacaru, Helena Serra Azul Monteiro, Roberta Jeane B Jorge, David A Wink, Eduardo Henrique S Sousa, Luiz Gonzaga de França Lopes
Nitrosyl ruthenium complexes have emerged as promising platforms for the controlled delivery of nitric oxide (NO) and nitroxyl (HNO), both of which possess significant therapeutic implications. Considering this scenario, we synthesized and characterized the metal complex cis‐[RuNO(phen)2(2MIM)]3+ and its precursors, where phen and 2MIM correspond to 1,10‐phenantroline and 2‐methylimidazole, respectively
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Theoretical Investigation of Structural, Electronic and Optical Properties of Cs3MoO4(HCO3) with NLO Active Functional Units Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-06 Jinyu Hu, Yinsheng Huang, Hui Zhu, Huiyan Zhao, Chao He, Xihu Wang
Employing functional building units with microscopic second‐order NLO response has been proposed to explore high performance NLO materials. Herein, structural, electronic and optical properties of non‐centrosymmetric molybdenyl carbonate Cs3MoO4(HCO3) with NLO active functional units have been examined based on density functional theory. Theoretical results are consistent with experimentally mentioned
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Uranium Chemistry in liquid Ammonia: Compounds obtained by adventitious Presence of Moisture or Air Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-06 Tim Graubner, Patrick Woidy, Sebastian Baer, Antti Karttunen, Florian Kraus
UCl4, UBr4, UBr5, or UO2Cl2 reacted with excess liquid ammonia—in adventitious presence of moisture and/or air—and formed some peculiar uranium compounds of which we present the crystal structures. [(NH3)7(N3)U(µ‐O)U(NH3)8]Cl5∙7NH3 contains a dinuclear µ‐O‐bridged uranium(IV) cation, [{(NH3)4UO2}2(µ‐O)]Cl2∙4NH3 features a dinuclear µ‐O‐bridged uranyl(VI) cation, while the compounds [(U(VI)O2)2(U(V
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Main Group Analogs of Dichalcogeniranes Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-06 Masaichi Saito, Norihiro Tokitoh, Renji Okazaki
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A Distibene with Extremely Long Sb=Sb Distance and Related Heavier Dipnictenes from Salt‐Free Metathesis Reactions Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-06 Clara A. Roller, Berenike Doler, Beate G. Steller, Robert Saf, Roland C. Fischer
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Enhanced Red Emission of Na5Lu9F32: Eu3+ Single Crystal by Introducing of GdF3 Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-03-01 Zhoujuan Zou, Lizhi Fang, Xiong Zhou, Haiping Xia, Hongwei Song, Baojiu Chen
The bulk Na5Lu9F32 single crystals with high quality Serial Eu3+/Gd3+ co‐doped were grown by an ameliorative Bridgman technique. The measurement of X‐ray diffraction (XRD) and analysis of Rietveld refinement were implemented to validate the crystal phase. The Eu3+ doped Na5Lu9F32 single crystal emits intense red emission at 611 nm excited by 394 nm light. The intensity of 1.8 mol% Gd3+ doped sample
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Beyond the Limits of Perbromo‐Substituted Octahedral Pnictogenaboranes: A Spectroscopic and Computational Study Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-28 Willi Keller, Jindřich Fanfrlík, Drahomír Hnyk
Octahedral closo‐1,2‐Pn2B4Br4 (Pn = P, As) molecules react with tetrahydrothiophene (THT), regarded as a soft base, much slower than with tetrahydrofuran (THF), considered a hard base. Namely, the reaction begins with only Pn = P at temperatures above 140 °C; 4‐Br(CH2)4S‐closo‐1,2‐P2B4Br3 has been detected as the first product resulting in the cleavage and insertion of a thiobutylate group into the
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Biocompatible Phosphorescent Ir(III) Complexes for Hypoxia Sensing in PLIM Mode Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-28 Mozhgan Samandarsangari, Nina A. Zharskaia, Sergey A. Silonov, Ekaterina E. Galenko, Daria O. Karpitskaya, Angelika Rück, Ilya S. Kritchenkov, Sergey P. Tunik
In this work, two new biscyclometalated Ir(III) complexes with diimine ligands were synthesized. The compounds were characterized by 1D and 2D NMR spectroscopy and HR ESI mass spectrometry. All complexes exhibit efficient phosphorescence with pronounced sensitivity to the presence of oxygen. The photophysical properties of the obtained compounds, including absorption, emission spectra, lifetimes and
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The Molecular Structures of Lithium Trichlate, Li[Cl3CSO3]⋅2H2O, and Lithium Tribrate, Li[Br3CSO3]⋅2H2O Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-26 Alisha Mertens, Katrin Eppers, David van Gerven, Mathias S. Wickleder
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Ruthenium Complexes with a Tridentate Anionic Bisfluoroalkoxy-Carbene Ligand – Valuable Latent Olefin Metathesis Catalysts for Polymerisation Reactions Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-26 Manuel Zier, Sebastian Planer, Izabela Czeluśniak, Anna Marczyk, Katarzyna Młodzikowska-Pieńko, Bartosz Trzaskowski, Dirk Bockfeld, Matthias Tamm, Anna Kajetanowicz
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Acid-Free Intermolecular Hydroarylation of Acetylene Catalyzed by Dicationic Palladium(II) and Platinum(II) Ethylene Complexes Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-25 Billy Garcia, Mostafa M. Manjahi, Trent A. Pinion, Christine Hahn, Christian Adams, Joseph Medina, Leonel Garcia, Ngoc T. B. Nguyen
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Assembly of Titanium-oxo Clusters from Embonic Acid-Modified {Ti2} Molecular Building Blocks with Efficient Sulfur-Catalyzed Oxidation Activities Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-23 Xiaoyan Gu, Yaomei Fu, Liang Zhao, Yuanyuan Zhang, Xinlong Wang, Baoli Li
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Multi-electron Oxidation of Ce(III) Complexes Facilitated by Redox-Active Ligands Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-23 D. M. Ramitha Y. P. Rupasinghe, Lauren M. Lopez, Andrew T. Poore, Makayla R. Baxter, Nathan J. Lin, Andrew W. Mitchell, Matthias Zeller, Shiliang Tian, Suzanne C. Bart
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Securing Reversibility of UVO2+/UVIO22+ Redox Equilibrium in [emim]Tf2N-Based Liquid Electrolytes towards Uranium Redox-Flow Battery Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-22 Koichiro Takao, Kazuki Ouchi, Atsushi Komatsu, Yoshihiro Kitatsuji, Masayuki Watanabe
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Chair vs. Boat: Conformational Impacts on DNA Binding Capacity in Cu(II) Complexes Featuring cis-1,4-Cyclohexanedicarboxylate Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-21 Sk Khalid Rahaman, Mukti Mohammad, Paula Brandão, Masoom Raza Siddiqui, Saikh M. Wabaidur, Md Maidul Islam, Seikh Mafiz Alam, Mohammad Hedayetullah Mir
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Isolable Dipyrromethene-Based Heavier Group 14 and 15 Element Complexes Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-20 Qidi Bao, Yuyang Dai, Chen Liu, Xiaona Liu, Jing Xiao, Daqian Xu, Yuanting Su
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Mechanistic insights of the Ir‐bipyridonate catalyzed aqueous methanol dehydrogenation and transfer dehydrogenation to acetophenone: Experimental and DFT study Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-19 Nidhi Garg, Rinaldo Poli, Basker Sundararaju
The mechanisms of the Cp*IrIII(bpyOO)‐catalyzed (bpyOO = bidentate (NN) doubly deprotonated 2,2'‐bipyridine‐6,6'‐diol) acceptorless methanol dehydrogenation and acetophenone transfer hydrogenation by methanol under basic conditions have been explored by the combination of 1H NMR, kinetics, and DFT computational studies. During dehydrogenation of methanol and its dehydrogenated derivatives, the presence
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Investigations on Water-Soluble Copper Complexes with the Sterically Demanding Triazacyclononane Derivative (tBu)2(nPrSO3)Htacn Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-19 Lars Schneider, Christian Würtele, Siegfried Schindler
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Atropisomeric N-Heterocyclic Carbene-Palladium(II) Complexes: Influence of the Backbone Substitution Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-19 Yajie Chou, Mathilde Vançon, Muriel Albalat, Carla Deschodt, Paola Nava, Stéphane Humbel, Nicolas Vanthuyne, Hervé Clavier
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Modified gold nanoparticles modulated fluorescence and singlet oxygen generation of pheophorbide a as an effective platform for photodynamic therapy against Staphylococcus aureus Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-15 Daniel Ziental, Paulina Błaszkiewicz, Jolanta Długaszewska, Emre Güzel, Alina Dudkowiak, Lukasz Sobotta
The paper reports on the synthesis and evaluation of photochemical properties of gold nanorods (Au-NRs) coated with PEG with a thiol (–SH) group or SiO2 and their physical mixtures with pheophorbide a. Also biological activity of these systems was tested in photodynamic therapy directed towards Staphylococcus aureus. The potential additive effect between differently functionalized Au-NRs and the dye
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A dual-function Cd-based coordination polymer for the detection of moxifloxacin and SiO32− ions Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-16 Shan Zhu, Zhenqi Tan, Jiajun Pan, Luyao Liu, Tao Yang, Xinhui Zhou, Yujian You, Hongping Xiao
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Tailoring Bandgap and Photocatalytic Performance of Designed Zinc Oxide Platelets by Cobalt Doping Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-13 Bülent ALKAN, Ozan Sukru Ates, Mehmet Tumerkan Kesim, Ender Suvaci
Platelet-shaped zinc oxide (ZnO) particles exhibit certain advantages compared to conventional micron and nano forms. Their superior surface coverage and excellent optical properties make these particles very attractive as UV filters in cosmetics and personal care applications. Although ZnO is non-toxic, it exhibits photocatalytic activity (PCA), which increases when the size of particles approaches
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Pivotal Role of Salicylates in Tuning the Formation and Reactivity of Mn(V)=O's Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-14 Pragya Arora, Sai Kumari Vechalapu, Santhosh Duraisamy, Dharmaraja Allimuthu, Apparao Draksharapu
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Ligand Functionalization of Metal-Organic Frameworks for Photocatalytic H2O2 Production Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-12 Jianhao Qiu, Jianfeng Yao
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Covalent Organic Frameworks as a Versatile Platform for Iron-Catalyzed sp3 C−H Activation and Cross-Coupling via Decarboxylative Oxidation Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-12 Jhonny M. C. Cifuentes, Fábio J. F. S. Henrique, Carolina B. P. Ligiéro, Pierre M. Esteves, Camilla D. Buarque
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Effect of Ge Incorporation on Lead-free Cs-based Triiodide Sn−Ge Co-alloy Perovskite Thin Films by Spin Coating Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-12 Hongyu Li, Chao Ye, Jianming Yang, Yu Jiang, Zhifang Wu, Sardor Burkhanovich Donaev, Shenghao Wang
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Citric acid as multidentate flexible ligand for multinuclear late-3 d-metal complexes and single-molecule magnets Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-12 Masanori Wakizaka, Masahiro Yamashita
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Monocopper model of CuB site of pMMO in N4-environment oxidizes C−H bonds Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-12 Hugo C. Hernández-Toledo, Marcos Flores-Alamo, Ivan Castillo
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Intermolecular Insertion Reactions into the P–P Bond of Oligophosphorus Compounds Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-09 Elena Gorbachuk, Toni Grell, Evamarie Hey-Hawkins, Dmitry G. Yakhvarov
The insertion of unsaturated organic molecules into a P–P bond of oligophosphorus compounds has the potential to expand the organophosphorus and organometallic chemistry and to make it more variable with the selective formation of desirable products. This article reviews the insertion reaction for oligophosphorus compounds and focuses in particular on non-metals, unsaturated organic substrates, carbenes
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Surprising Impact of Donor Charge on the Water Exchange Rates of Gd(III) AAZTA Derivatives Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-09 Lorenzo Tei, Loredana Leone, Daniela Lalli, Mauro Botta, Carlos Platas-Iglesias
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Uranium Cyanides from Reactions in Liquid Ammonia Solution Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-08 Tim Graubner, Stefan S. Rudel, Sergei I. Ivlev, Antti J. Karttunen, Florian Kraus
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Trans-Dioxidomolybdenum(VI) Porphyrins and their Catalytic Activity Mimicking Oxidative Bromination Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-08 Mannar R. Maurya, Ved Prakash, Muniappan Sankar
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Controllably Modulating Oxygen Vacancies on Nonstoichiometric Nd−Ce−O Binary Oxides for Low-temperature Oxidative Coupling of Methane Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-07 Ying Gong, Chengxin Lu, Xusheng Zhong, Junwei Xu, Rumeng Ouyang, Xiuzhong Fang, Xianglan Xu, Chunhui Deng, Xiang Wang
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Redox Reactivity Control Through Electromerism Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-07 Johanna Osterbrink, Fabricio Dos Santos, Elisabeth Kaifer, Hans-Jörg Himmel
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Probing the effects of gold doping on structural, electronic and nonlinear optical properties of caged X20H20 (X=Si, Ge, Sn, Pb) clusters Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-07 Yunfeng Zhang, Xiaojun Li, Jun Lu
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Mechanistic Insights into Ru-catalyzed Alkene Epoxidation with Nitrous Oxide as a Terminal Oxidant Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-07 Vitaliy I. Timokhin, R. David Grigg, Jennifer M. Schomaker
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Chemical Structure Elucidation in the Development of Inorganic Drugs: Evidence from Ru-, Au-, As-, and Sb-based Medicines Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-02-06 Alissa Lance-Byrne, Brent Lindquist-Kleissler, Timothy C. Johnstone
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Comprehensive Photophysical and Nonlinear Spectroscopic Study of Thioanisolyl-Picolinate Triazacyclononane Lanthanide Complexes Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-31 Dina Akl, Lucile Bridou, Maher Hojorat, Guillaume Micouin, Salauat R. Kiraev, François Riobé, Sandrine Denis-Quanquin, Akos Banyasz, Olivier Maury
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Dysprosium-Radical Based Single-Molecule Magnet Containing a Seven Coordinate Dy(III) Ion: A System for ab initio Study Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-30 Saroj Kumar Kushvaha, Prathap Ravichandran, Chen Dan, Liviu Ungur, Nithin Suryadevara, Mario Ruben, Kartik Chandra Mondal
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Successive magnetic transitions and frustrated magnetism in Fe2(HPO3)3 ⋅ 4H2O Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-29 Xiaomeng Cheng, Chengxiang Lv, Shufang Zhang, Mingcui Ding, Bingying Pan
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Hydrophosphorylation of C=O/N Bonds Using Organophosphine Oxides or Sulfides Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-24 Jan-Willem Lamberink-Ilupeju, Paul J. Ragogna, Johanna M. Blacquiere
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Water Adducts of the Lewis Superacids: Tris(pentafluoroethyl)gallane and -indane Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-26 Katharina Tölke, Sven Porath, Yury V. Vishnevskiy, Beate Neumann, Hans-Georg Stammler, Norbert W. Mitzel, Berthold Hoge
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Synthesis and reactivity of a dialkyl-2H-1,2-phosphasiliren-3-olate Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-24 Liping Yan, Lifang Wu, Yunqing Zhao, Rong Zhang, Fan Qi, Liliang Wang, Zhifang Li
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Palladium(II)-Imidoyl Complexes: A New Piece in the Puzzle of Organopalladium Anticancer Agents Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-25 Enrica Bortolamiol, Sofia Novaselich, Chiara Tupini, Sofia Fagnani, Roberto Gambari, Nicola Demitri, Ilaria Lampronti, Fabiano Visentin, Thomas Scattolin
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Slow relaxation of magnetization in the Co(II)-phosphotungstate Keggin polyoxometalate Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-24 Lara Martinez, Pablo Alborés
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Cover Feature: Effect of Apical Ligands, Substituents and Oxidation States on the Electronic Structure of Co(III) Corrolates (Eur. J. Inorg. Chem. 8/2024) Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-24 Nicolás I. Neuman
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Front Cover: Investigations into the AuI and PtII Coordination Chemistry of Bidentate “cis-Spanning” Ligands (Eur. J. Inorg. Chem. 8/2024) Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-24 Luisa Kaufmann, Steffen A. Föhrenbacher, Michael C. Krummer, Burkhard Butschke
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A Water-Stable Europium Metal–Organic Framework as a Turn-Off Fluorescence Sensor for Ascorbic Acid Detection in Human Serum Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-19 Yu-Xing Yin, Bing Liu, Le-Fang Zheng, Xin Zhou, Ling Xu
Ascorbic acid (AA) is a biomarker of some nervous system diseases, whose detection is of significance in many fields. The hydrothermal reaction of naphthalene-2,6-dicarboxylic acid (H2NDBC) with Eu3+ produced a europium MOF, Eu-NDBC. Eu-NDBC emits the combined emissions from the intraligand charge transfer (ILCT) of NDBC2‒ ligand and 5D0→7Fj (j = 1-4) transfers of Eu(III). The factors of MOF dosage
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Synthesis, Structural and Redox Properties of Vanadyl β-Cyanoporphyrin and its Utilization as Efficient Catalyst for Epoxidation of Olefins and Oxidative Bromination of Phenols Eur. J. Inorg. Chem. (IF 2.3) Pub Date : 2024-01-21 Soni Kumari, Ved Prakash, Siddharth S, Mannar R. Maurya, Muniappan Sankar