18. S. Li, K. Yuan, G. Zhang*, R. Guo*, Recent Advances in the Synthesis of Chiral Allenes via Asymmetric 1,4-Difunctionalization of 1,3-Enynes. Eur. J. Org. Chem. 2024, doi.org/10.1002/ejoc.202301316.

17. K.-Q. Tian^#, S.-J. Zhang^#, J. Zhao, G.-Y. Duan, Q.-L. Wang, G.-H. Cui, R. Guo*, H.-S. Li*, Regio- and Diastereoselective Highly Strained Alkylidenecyclobutane Isomerization/Hydroacylation: Synthesis of Multisubstituted Cyclobutanes with Consecutive Stereocenters.  ACS Catal. 2024, 14, 1505−1513. (# contributed equally)

16. J. Zheng, H. Zhang, S. Kong, Y. Ma, Q. Du, B. Yi, G. Zhang*, and R. Guo*, Copper-Catalyzed General and Selective α-C(sp3)–H Silylation of Amides via 1,5-Hydrogen Atom Transfer.  ACS Catal. 2024, 14,  1725–1732.

15. J. Lu^#, M. Zhang^#, X. Zheng, P. Shen, Y. Xu, Q. Zhang, Y. Tang, G. Zhang*, and R. Guo*,Rhodium(I)-Catalyzed Enantioselective Ring-Opening and Isomerization of Cyclobutanols through a (Z)-Unsaturated Ketone Intermediate. Org. Lett. 2023, 25, 5151–5156. (# contributed equally)

14. H. Huang, H. Zhang, Q. Wang, Y. Sun, L. Su, W. Xu, Y. Ma, S. Kong,  G. Zhang*, R. Guo* Copper-Catalyzed Asymmetric 1,4-Aryl/Alkynylation of 1,3-Enynes to Access Axially Chiral Tetrasubstituted Allenes. ChemCatChem 2023, 15, e202300697.

13. X. Mo, H. Huang, G. Zhang*, Tetrasubstituted Carbon Stereocenters via Copper-Catalyzed Asymmetric  Sonogashira Coupling Reactions with gem-dihaloketones and α-bromo-γ-lactams. ACS Catal. 2022, 12, 9944–9952.

12. R. Guo^#, H. Xiao^#, S. Li, Y. Luo, J. Bai, M. Zhang, Y. Guo*, X. Qi*, G. Zhang*, Photoinduced Copper-Catalyzed Asymmetric C(sp3)−H Alkynylation of Cyclic Amines by Intramolecular 1,5-Hydrogen Atom Transfer.  Angew. Chem. Int. Ed. 2022, 61, e202208232. (# contributed equally)

11. J. Li, Y. Peng, B. Chen, R. Guo, X. Ma, X. Xue*, Y. Liu*, G. Zhang*, Azetidine synthesis enabled by photo-induced copper catalysis via [3+1] radical cascade cyclization. The Innovation, 2022, 3, doi.org/10.1016/j.xinn.2022.100244.

10. Z. Cao^#, J. Li^#, G. Zhang*, Photo-induced copper-catalyzed sequential 1,n-HAT enabling the formation of cyclobutanols. Nat. Commun. 2021, 12, 6404. (# contributed equally)

9. Z. Cao, J. Li, Y. Sun, H. Zhang, X. Mo, X. Cao, G. Zhang*, Photo-induced copper catalyzed alkynylation and amination of remote unactivated C(sp³)–H bonds, Chem. Sci. 2021, 12, 4836–4840.

8. C. Li, B. Chen, X. Ma, X. Mo, G. Zhang*, Photo-Promoted Copper-Catalyzed Enantioselective Alkylation of Azoles. Angew. Chem. Int. Ed. 2021, 60, 2130–2134.

7. X. Mo, B. Chen, G. Zhang*, Copper-Catalyzed Enantioselective Sonogashira Type Couplings of Alkynes with α-Bromoamide. Angew. Chem. Int. Ed. 2020, 59, 13998–14002.

6. G. Lei, H. Zhang, B. Chen, M. Xu, G. Zhang*, Copper-Catalyzed Enantioselective Arylalkynylation of Alkenes. Chem. Sci. 2020, 11，1623-1628.

5. Y. Xiong, G. Zhang*, Enantioselective 1,2-Difunctionalization of 1,3-Butadiene by Sequential Alkylation and Carbonyl Allylation. J. Am. Chem. Soc., 2018, 140, 2735-2738.

4. X. Zheng, R. Guo, G. Zhang*, D. Zhang*, Rhodium(I)-Catalyzed Asymmetric [4+2] Cycloaddition Reactions of 2-Alkylenecyclobutanols with Cyclic Enones through C-C Bond Cleavage: Efficient Access to trans-Bicyclic Compounds. Chem. Sci., 2018, 9, 1873-1877.

3. R. Guo, G. Zhang*, Expedient Synthesis of 1,5-Diketones by Rhodium-Catalyzed Hydroacylation Enabled by C−C Bond Cleavage. J. Am. Chem. Soc., 2017, 139, 12891-12894.

2. R. Guo, X. Zheng, D. Zhang*, G. Zhang* Rhodium(I)-Catalyzed Stereoselective [4+2] Cycloaddition of Oxetanols with Alkynes through C(sp³)-C(sp³) Bond Cleavage, Chem. Sci., 2017, 8, 3002-3006.

1. C. Yu, B. Chen, T. Zhou, Q. Tian, G. Zhang*, Gold (I)-Catalyzed Tandem Transformation with Diynes: Rapid Access to Cyclopentenone-Fused, Linear Polycyclic Molecules. Angew. Chem. Int. Ed. 2015, 54, 10903-10907.