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Ruthenium-Catalyzed Selective Mono N-Ethylation of Arylamines and Tandem Reduction/N-Ethylation of Nitroarenes Using Triethylamine and Formic Acid J. Org. Chem. (IF 3.6) Pub Date : 2024-06-01 MatíAs Concha-Puelles, Simón Torres-González, Ramiro Robles-Henríquez, Susan Lühr
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Conformational Analysis of 1,3-Difluorinated Alkanes J. Org. Chem. (IF 3.6) Pub Date : 2024-05-31 William G. Poole, Florent Peron, Stephen J. Fox, Neil Wells, Chris-Kriton Skylaris, Jonathan W. Essex, Ilya Kuprov, Bruno Linclau
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Gold-Catalyzed Oxidative Rearrangement Strategy to Yield 2-Hydroxycyclohepta-1,3-diene-1-carbonyl Compounds J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Jiang Zhu, Jianghao Yan, Fudong Wang, Lianjie Zhang, Jiaji Li, Maosheng Cheng, Lu Yang, Yongxiang Liu
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Protecting Group-Free Total Synthesis of (−)-Boscartin H J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Hiroto Aihara, Daisuke Kounai, Akihiko Kasamatsu, Junya Shiraiwa, Akinobu Matsuzawa, Shogo Kamo, Kazuyuki Sugita
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Direct Construction of 1,4-Dihydropyridazines and Parazoles via Annulation of Alkyl 2-Aroyl-1-chlorocyclopropanecarboxylates J. Org. Chem. (IF 3.6) Pub Date : 2024-06-01 Pengwei Zhang, Huili Liu, Shuo Xu, Yiqun He, Xinhao He, Bing Sun, Junhao Hu
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Phosphine-Catalyzed Stereospecific and Enantioselective Desymmetrizative [3+2] Cycloaddition of MBH Carbonates and N-(2-tert-Butylphenyl)maleimides J. Org. Chem. (IF 3.6) Pub Date : 2024-06-01 Jie Hou, Wei Hao, Ying Chen, Zhen Wang, Weijun Yao
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Synthesis of gem-Difluorohomoallyl Amines via a Transition-Metal-Free Defluorinative Alkylation of Benzyl Amines with Trifluoromethyl Alkenes J. Org. Chem. (IF 3.6) Pub Date : 2024-05-31 Man Ren, Shengjiao Yu, Xuefeng Li, Wenlong Yuan, Ji Lu, Ying Xiong, Hongliang Liu, Jun Wang, Jun Wei
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Samarium-Oxo/Hydroxy Cluster: A Solar Photocatalyst for Chemoselective Aerobic Oxidation of Thiols for Disulfide Synthesis J. Org. Chem. (IF 3.6) Pub Date : 2024-05-31 Lijun Wang, Lingxia Chen, Zixuan Qin, Bihan Zhao, Ke Ni, Hengzhao Li, Junyu Li, Hongxia Duan, Fazheng Ren, Jie An
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Cascade Radical Pathway-Enabled Nitrogen–Sulfur Coupling: Access to Isothiazolo[3,4-b]-meso-tetraarylporphyrins J. Org. Chem. (IF 3.6) Pub Date : 2024-05-31 Abhijeet Singh, Mahendra Nath
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Total Synthesis of (−)-Piericone D J. Org. Chem. (IF 3.6) Pub Date : 2024-05-31 Shaopan Yuan, Wanqing Pei, Xuan Di, Yali Qin, Hongming Jin, Zhanchao Meng, Xiaoli Hou
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Synthesis of Benzo[a]carbazoles and Dibenzo[c,g]carbazoles via Sequential Gold Catalysis and Photomediated Cyclization J. Org. Chem. (IF 3.6) Pub Date : 2024-05-31 Lijun Zhang, Zhuo Wang, Zhiguang Song
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Construction of Hydroindole Skeleton by Photocatalytic Oxidative Dearomatization and Cyclization Sequence, and a Concise Synthesis of Melodamide A and (±)-Toussaintine C J. Org. Chem. (IF 3.6) Pub Date : 2024-05-31 Tomohiro Tsutsumi, Ryui Yamagami, Ichiro Hayakawa
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Catalyst-Free α-trans-Selective Hydroboration and (E)-Selective Deuterated Semihydrogenation of Alkynyl Sulfones J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Yunnan Duan, Zhouqing Zheng, Zhiwei Yu, Shitao Sun, Bin Lin, Xiaozu Liu, Peijun Liu
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Intramolecular Hosomi–Sakurai Reaction for the Synthesis of Benzoxasiloles J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Xin-Long Yu, Jia-Wei Hu, Jian Cao, Li-Wen Xu
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Iridium-Catalyzed C–H Borylations: Regioselective Functionalizations of Calix[4]arene Macrocycles J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Gabriele Giovanardi, Silvia Cattani, Davide Balestri, Andrea Secchi, Gianpiero Cera
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NIS-Promoted Chemodivergent and Diastereoselective Synthesis of Pyrrolinyl and Cyclopentenyl Spiropyrazolones via Regulated Cyclization of Alkylidene Pyrazolones with Enamino Esters J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Hui Xu, Ming-Yue Weng, Peng Xu, Ze-Ming Huang, Qing-Hai Li, Ze Zhang
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Oxidative Syntheses of N,N-Dialkylhydroxylamines J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Daniel Barriault, Huy M. Ly, Meredith A. Allen, Monica A. Gill, André M. Beauchemin
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Organocatalytic Csp2–O Amination of Quinolin-4(1H)-ones with 3-Alkynyl-3-hydroxyisoindolinones J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Tingting Huang, Chenxiao Qian, Pengfei Li
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Synthesis of Functionalized 4-Hydroxy Carbazoles and Carbazole Alkaloids via Ring Expansion of Indole Cyclopentanone J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Xiaolong Pan, Boyang Dong, Yangang Wu, Beiling Gao, Chuanjun Song
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Palladium-Catalyzed (4 + 1) Annulation of 4-Vinylbenzodioxinones with Sulfur Ylides: Diastereoselective Synthesis of Dihydrobenzofuran Derivatives J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Yi Tang, Xiaojing Sun, Yu Tan, Lan Wang, Yanmei Xiong, Hongchao Guo
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Correction to “Preparation of Blatter Radicals via Aza-Wittig Chemistry: The Reaction of N-Aryliminophosphoranes with 1-(Het)aroyl-2-aryldiazenes” J. Org. Chem. (IF 3.6) Pub Date : 2024-05-30 Anastasia C. Savva, Styliana I. Mirallai, Georgia A. Zissimou, Andrey A. Berezin, Marina Demetriades, Andreas Kourtellaris, Christos P. Constantinides, Constantinos Nicolaides, Theodossis Trypiniotis, Panayiotis A. Koutentis
The equations (section 4.3) used to calculate the EHOMO and ELUMO values in Table 5 were incorrect, which led to a systematic error in the reported data. In light of this, we corrected the equations and introduced the more commonly accepted value of −4.8 eV for ferrocene’s HOMO level rather than the less used value of −5.1 eV. The corrected text and table should read as follows. All redox potentials
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Synthesis of 6H-Chromeno[4,3-b]quinolin-7-ylphosphonates through Three Component Phosphonylation of Coumarin Carbaldehyde and Their Antimicrobial and Photophysical Properties J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Mojtaba Ghashghaee, Babak Kaboudin, Foad Kazemi, Maryam Hassan, Haruhiko Fukaya, Hikaru Yanai
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Ring Contraction by Rearrangement of Sterically Congested Cyclic (Amino)(aryl)carbenes J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Xiaoyu Zhang, Shangru Yang, Xiaoming Zeng
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Scalable Total Synthesis of (+)-Desmethylxestospongin B J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Alana K. Borum, Karen Y. Chen, Armen Zakarian
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Mechanistic Insights into the Antioxidant and Pro-oxidant Activities of Bromophenols from Marine Algae: A DFT Investigation J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Houssem Boulebd
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Photochemical Generation of Allenylidenes from Cyclopropanated Phenanthrenes: An Experimental and Computational Study J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Alexander D. Roth, David R. Ramgren, Yuewei Wen, Megan S. Michie, Dasan M. Thamattoor
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A Modular and Catalytic Methodology To Access 2,5-Furan-Based Phenylene/Thiophene Oligomers through a One-Pot Decarboxylative Cross-Coupling from 5-Bromofurfural J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Brandon Cigana, Victoria Lapointe, Marek B. Majewski, Pat Forgione
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Hybrid Palladium-Catalyzed Intramolecular Carboamination of Conjugated Dienes: Synthesis of Functionalized Pyrrolidines via Selective Trifluoromethylarene Defluorination J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Feijie Zhang, Guocong Zhang, Qixin Zhou, Tiancen Bian, Liejin Zhou, Zuxiao Zhang
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CuH-Catalyzed Reductive Coupling of Nitroarenes with Phosphine Oxides for the Direct Synthesis of Phosphamides J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Jie Tang, Zhiyou Li, Qi Meng, Long Liu, Tianzeng Huang, Chunya Li, Qiang Li, Tieqiao Chen
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Short Total Synthesis of (+)-Colletotryptins B-D and Mucronatin B Derivative J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Wilailak Saetae, Chayamon Chantana, Saowanit Saithong, Kampanart Chayajarus, Jaray Jaratjaroonphong
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Second-Generation Chiral Amino Acid Derivatives Afford High Stereoselectivity and Stability in Aqueous RNA Acylation J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Ryuta Shioi, Sayantan Chatterjee, Lu Xiao, Wenrui Zhong, Eric T. Kool
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Copper-Catalyzed Synthesis of Difluoromethylated/C-4- and C-5-Functionalized Polycyclic Coumarin Derivatives J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Ziwei Li, Shuo Li, Guosong Qian, Zhiwei Ke, Zhiwei Chen
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Total Synthesis of Carbazomycins E and F J. Org. Chem. (IF 3.6) Pub Date : 2024-05-29 Yunosuke Shima, Yuxuan Feng, Atsunori Mori, Kentaro Okano
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Total Synthesis of (±)-Simonsol C J. Org. Chem. (IF 3.6) Pub Date : 2024-05-28 Jia-Jun Sui, Kai Wang, Song-Juan Luo, Kang Guo, Ming-Wei Yuan, Hong-Bo Qin
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Enantioselective α-Trifluoromethylthiolation of Carbonyl Compounds with AgSCF3 and Trichloroisocyanuric Acid J. Org. Chem. (IF 3.6) Pub Date : 2024-05-28 Yakun Wang, Yingying Wang, Wenwen Guo, Yizhe Zhang, Xiaoyu Du, Yan Song, Wenhui Wang, Zhiang Liu, Yingchao Duan, Tao Zhang
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Resolution of 9,10-Diketo[7]helicene and Its Use in One-Step Preparation of Helicene-Based D–A–D Push–Pull Systems J. Org. Chem. (IF 3.6) Pub Date : 2024-05-28 Martin Kos, Tomáš Beránek, Ivana Císařová, Petra Cuřínová, Jaroslav Žádný, Jan Storch, Vladimír Církva, Martin Jakubec
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Palladium-Catalyzed Domino Heck/Cross-Coupling Cyclization Reaction: Diastereoselective Synthesis of Furan-Containing Indolines J. Org. Chem. (IF 3.6) Pub Date : 2024-05-28 Furong Li, Ye Yuan, Donghao Lyu, Yujie Yi, Jingli Zhang, Taolei Sun, Guanbin Gao
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Synthesis of N-Hydroxysuccinimide Esters, N-Acylsaccharins, and Activated Esters from Carboxylic Acids Using I2/PPh3 J. Org. Chem. (IF 3.6) Pub Date : 2024-05-28 Kishor L. Handore, Heyuan Lu, Hyeongbin Park, Qingyu Xiong, Robert A. Batey
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Reaction Rate and Stereoselectivity Enhancement in Glycosidations with O-Glycosyl Trihaloacetimidate Donors due to Catalysis by a Lewis Acid–Nitrile Cooperative Effect J. Org. Chem. (IF 3.6) Pub Date : 2024-05-28 Tianlu Li, Tong Li, Yue Yang, Yongshun Qiu, Yingguo Liu, Miaomiao Zhang, Haoru Zhuang, Richard R. Schmidt, Peng Peng
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Unveiling the Selectivity of Ru(II)-Catalyzed C–H Activation for Defluorinative Cyclization of 2-Arylbenzimidazole and Trifluoromethyl Diazo: A DFT Study J. Org. Chem. (IF 3.6) Pub Date : 2024-05-28 Zi-Ming Huang, Yi Sun, Yong Wang, Xing-Wang Wang
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Catalysis-Based Fluorometric Method for Semiquantifying Trace Palladium in Sulfur-Containing Compounds and Ibuprofen J. Org. Chem. (IF 3.6) Pub Date : 2024-05-28 Judey T. DaRos, Miho Naruse, Jasmyne M. Mendoza, Abhimanyu Nangunoori, Jacob H. Smith, Jill E. Millstone, Kazunori Koide
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Synthesis of Isoxazol-5(2H)-one Derivatives via (tBuO)2Mg Promoted [3 + 2] Annulations of δ-Acetoxy Allenoates with Hydroxylamine J. Org. Chem. (IF 3.6) Pub Date : 2024-05-28 Bai Shi, Yu Zhang, Siyan Miao, Fangyi Jin, Chenxia Yu, Kai Zhang, Changsheng Yao
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Amidation of Enones via Beckmann Rearrangement J. Org. Chem. (IF 3.6) Pub Date : 2024-05-27 Saumya Verma, Vikram Singh, Jawahar L. Jat, Bhoopendra Tiwari
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Synthetic Strategies toward Ortho-3-propanoate Substituted Aryl Phosphonates by Three-Component Coupling Reactions of Arynes, Phosphites, and Acrylates J. Org. Chem. (IF 3.6) Pub Date : 2024-05-27 Donghwa Shin, Soomin Kim, Duck-Hyung Lee, Seo-Jung Han
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Red-Light-Driven Bifunctionalization of Styrene Derivatives J. Org. Chem. (IF 3.6) Pub Date : 2024-05-27 Urara Kai, Yoshino Katsurayama, Ryo Nishida, Tatsuya Kameyama, Tsukasa Torimoto, Taniyuki Furuyama
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Thank You, Steve Ritter! J. Org. Chem. (IF 3.6) Pub Date : 2024-05-27 Stefanie Dehnen, Paul J. Chirik, Marisa Kozlowski, Scott Miller, Kai Rossen
Stephen K. Ritter is the best-kept secret for the success of five ACS journals! Most readers and authors of our journals do not realize that there is a dedicated and talented team behind the scenes. As the Senior Managing Editor of Inorganic Chemistry, Organometallics, Organic Letters, The Journal of Organic Chemistry, and Organic Process Research & Development over the years, Steve is the epitome
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Correction to “Reductive Oxy-Nazarov Cyclization toward Expedient Construction of a Cyclopenta[1,2-b]pyrrolo[1,2-a]azepine Ring System: Formal Total Syntheses of Stemonamine and Cephalotaxine” J. Org. Chem. (IF 3.6) Pub Date : 2024-05-24 Xifei Yan, Qin Zhang, Jianfeng Zheng, Wei-Dong Z. Li
The following important comprehensive recent review article on Cephalotaxus alkaloids should be added to ref 2 as ref 2e: Pérard-Viret, J.; Quteishat, L.; Alsalim, R.; Royer, J.; Dumas, F. In The Alkaloids, Vol. 78; Knölker, H.-J., Ed.; Academic Press: London, 2017; pp 205–35210.1016/bs.alkal.2017.07.001. The authors are grateful to Professor Dr. Hans-Joachim Knölker of Technische Universität Dresden
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Cholinium Pyridinolate Ionic Pair-Catalyzed Fixation of CO2 into Cyclic Carbonates J. Org. Chem. (IF 3.6) Pub Date : 2024-05-24 Tianyu Zhu, Yue Xu, Zhenjiang Li, Jun He, Xin Yuan, Dong Qian, Tong Chang, Longlin Lu, Bo Chi, Kai Guo
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Metal-Free Cyanation of gem-Difluoroalkenes via Azide-Mediated C–C Double Bond Fragmentation J. Org. Chem. (IF 3.6) Pub Date : 2024-05-24 Hui Wang, Yuan-Yuan He, Jianwei Han, Zhong-Qiang Zhou, Xiao-Qiang Hu
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Thiopyran-Fused Polycyclic Aromatic Compounds Synthesized via Pt(II)-Catalyzed One-Pot Ring-Expansion and 6-endo Cyclization Reactions J. Org. Chem. (IF 3.6) Pub Date : 2024-05-24 Min Wang, Yangzhe Su, Hangyu Guo, Weinan Chen, Zhanglang Zhou, Si Liu, Gang Zhou
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Unsymmetrization of 1,8-Dibromonaphthalenes by Acid-Induced Halogen Dance Reaction J. Org. Chem. (IF 3.6) Pub Date : 2024-05-24 Kento Iwai, Nagatoshi Nishiwaki
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Sulfinamide Crossover Reaction J. Org. Chem. (IF 3.6) Pub Date : 2024-05-24 Vladimír Nosek, Jiří Míšek
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Chiral Brønsted Acid-Catalyzed Kinetic Resolution of Sulfoximines for the Synthesis of Benzothiadiazine-1-Oxides J. Org. Chem. (IF 3.6) Pub Date : 2024-05-24 Yuhang Chen, Shihao Huang, Tianyi Wang, Jiaomeng Li, Yi Zhao, Qinglong Zhou, Liwen Wei, Xing Yang
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Metal-Free Enantioselective 1,4-Addition of Diarylphosphine Oxides to α,β-Unsaturated Carboxylic Esters J. Org. Chem. (IF 3.6) Pub Date : 2024-05-23 Guangfu Lu, Liangrui Xiao, Qitao Que, Tao Leng, Jiuling Li, Yafei Guo, Baomin Fan
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Synthesis of Amides via the Amination of Aldehydes with Hydroxylamines Promoted by TBAF·3H2O J. Org. Chem. (IF 3.6) Pub Date : 2024-05-23 Huaiyuan Zhang, Nuo Xu, Botao Su, Jingren Zhang, Chongen Zhang, Zhiyuan Zhang, Binbin Guo, Shengjie Xu, Shouwei Wang, Rongping Tang
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Iron(II) Phthalocyanine-Catalyzed Homodimerization and Tandem Diamination of Diazo Compounds with Primary Amines: Access to Construct Substituted 2,3-Diaminosuccinonitriles in One-Pot J. Org. Chem. (IF 3.6) Pub Date : 2024-05-23 Gang Wang, Jia-Li Yuan, Rong Zhou, Huai-Bo Zou
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Elaborating NH-Bridged Nitrogen-Rich Energetic Materials via Base-Mediated Dimroth Rearrangement: Synthesis, Characterization, and Performance Study J. Org. Chem. (IF 3.6) Pub Date : 2024-05-23 Manojkumar Jujam, Vikas D. Ghule, Srinivas Dharavath
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Mechanistic Investigation on the Regioselectivity of Electrochemical Co(II)-Catalyzed [2 + 2 + 2] Cycloaddition of Terminal Acetylenes J. Org. Chem. (IF 3.6) Pub Date : 2024-05-23 Kai-Xin Yu, Sheng-Nan Liu, Yang-Yang Xing, Fang Huang, Wen-Juan Wang, Qiong Wang, De-Zhan Chen, Jin Wang
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One-Pot Oxidative Amidation of Aldehydes via the Generation of Nitrile Imine Intermediates J. Org. Chem. (IF 3.6) Pub Date : 2024-05-23 Martyn C. Henry, Laura Minty, Alexander C. W. Kwok, Jessica M. L. Elwood, Adam J. Foulis, Jonathan Pettinger, Craig Jamieson
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Automated Synthesis for the Safe Production of Organic Azides from Primary Amines J. Org. Chem. (IF 3.6) Pub Date : 2024-05-23 Tuo Jiang, Guillaume Coin, Samuele Bordi, Paula L. Nichols, Jeffrey W. Bode, Benedikt M. Wanner