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Dearomative Insertion of Fluoroalkyl Carbenes into Azoles Leading to Fluoroalkyl Heterocycles with a Quaternary Center Linxuan Li, Yongquan Ning, Hongzhu Chen, Yongyue Ning, Paramasivam Sivaguru, Peiqiu Liao, Qingwen Zhu, Yong Ji, Graham de Ruiter, Xihe Bi*Angew. Chem. Int. Ed. 2023, e202313807
Ligand-enabled silver-catalyzed carbene insertion into the N–H bond of aliphatic and electron-rich aromatic amines Linxuan Li, Paramasivam Sivaguru, Xinyue Han, Swastik Karmakar and Xihe Bi* Org. Chem. Front. 2023, 10, 1746-1753
Silver catalysis in organic synthesis: A computational view Yong Wu, Nils Frank, Qingmin Song, Miao Liu, Edward A.Anderson*, Xihe Bi* Adv Organometal Chem 2023, DOI:10.1016/bs.adomc.2022.12.004
Chemoselective carbene insertion into the N−H bonds of NH3·H2O Zhaohong Liu, Yong Yang, Qingmin Song, Linxuan Li, Giuseppe Zanoni, Shaopeng Liu, Meng Xiang, Edward A. Anderson, Xihe Bi* Nat. Commun. 2022, 13, 7649
Site-Selective C−H Allylation of Alkanes: Facile Access to Allylic Quaternary sp3-Carbon Centers Yong Yang, Shaopeng Liu, Shuang Li, Zhaohong Liu, Peiqiu Liao, Paramasivam Sivaguru, Ying Lu, Jiaojiao Gao, Xihe Bi* Angew. Chem. Int. Ed. 2022, DOI: 10.1002/anie.202214519
Silver-Catalyzed Vinylcarbene Insertion into C–C Bonds of 1,3-Diketones with Vinyl-N-triftosylhydrazones Yong Wu, Yongquan Ning*, Xinyue Han, Peiqiu Liao, Ying Xia, Paramasivam Sivaguru, and Xihe Bi* Org. Lett. 2022, DOI: 10.1021/acs.orglett.2c03176
Carbodefluorination of fluoroalkyl ketones via a carbene-initiated rearrangement strategy Linxuan Li, Xinyu Zhang, Yongquan Ning, Xiaolong Zhang, Binbin Liu, Zhansong Zhang, Paramasivam Sivaguru, Giuseppe Zanoni, Shuang Li, Edward A. Anderson, Xihe Bi* Nat. Commun. 2022, 13, 4280
Defluorinative Carboimination of Trifluoromethyl Ketones Xiaolong Zhang, Yongquan Ning, Zhaohong Liu, Shuang Li, Giuseppe Zanoni, and Xihe Bi* ACS Catal. 2022, 12, 8802–8810
Silver-catalyzed site-selective C(sp3)−H benzylation of ethers with N-triftosylhydrazones Zhaohong Liu, Hongwei Wang, Paramasivam Sivaguru, Steven P. Nolan, Qingmin Song, Weijie Yu, Xinyu Jiang, Edward A. Anderson, Xihe Bi* Nat. Commun. 2022, 13, 1674
The merger of vinyl-N-triftosylhydrazones and silver catalysis to enable stereoselective vinylcyclopropanation of alkenes Yong Yang, Zhaohong Liu, Qingmin Song, Paramasivam Sivaguru, Giuseppe Zanoni, Kuan Wang, Qiaowei Bi, Xihe Bi* Chem Catalysis 2022, 2, 563-57780
A Carbene Strategy for Progressive (Deutero)Hydrodefluorination of Fluoroalkyl Ketones.Xiaolong Zhang, Xinyu Zhang, Qingmin Song, Paramasivam Sivaguru, Zikun Wang, Giuseppe Zanoni and Xihe Bi* Angew. Chem. Int. Ed. 2021, 7, e202116190
Catalytic Asymmetric C(sp3)–H Carbene Insertion Approach to Access Enantioenriched 3-Fluoroalkyl 2,3-Dihydrobenzofurans Xinyu Zhang, Paramasivam Sivaguru, Giuseppe Zanoni, Xinyue Han, Minghui Tong，and Xihe Bi* ACS Catal. 2021, 11, 14293–14301
Synthetic exploration of sulfinyl radicals using sulfinyl sulfones Zikun Wang, Zhansong Zhang, Wanjun Zhao, Paramasivam Sivaguru, Giuseppe Zanoni,Yingying Wang, Edward A. Anderson & Xihe Bi* Nat. Commun. 2021, 12, 5244
Fluoroalkyl N-Triftosylhydrazones as Easily Decomposable Diazo Surrogates for Asymmetric [2 + 1] Cycloaddition: Synthesis of Chiral Fluoroalkyl Cyclopropenes and Cyclopropanes Xinyu Zhang, Chunqi Tian, Zhanjing Wang, Paramasivam Sivaguru, Steven P. Nolan, and Xihe Bi* ACS Catal. 2021, 11, 8527–8537
Silver-catalyzed Unstrained C(CO)–alkyl Bond Scission via [3+2]/retro-[3+2] Cycloaddition of Ketones with N-isocyanoiminotriphenylphosphorane Zikun Wang, Linxuan Li, Xueying Zhang, and Xihe Bi* Sci. China Chem. 2021, 64, 1157-1163
Computational Insights into Different Mechanisms for Ag‐, Cu‐, and Pd‐Catalyzed Cyclopropanation of Alkenes and Sulfonyl Hydrazones Yong Wu, Shanshan Cao, Iskander Douair, Laurent Maron*, and Xihe Bi* Chem. Eur. J. 2021, 27, 5999-6006
Palladium(II)-Catalyzed Cross-Coupling of Diazo Compounds and Isocyanides to Access Ketenimines Zhaohong Liu, Shanshan Cao, Jiayi Wu, Giuseppe Zanoni, Paramasivam Sivaguru, and Xihe Bi* ACS Catal. 2020, 10, 12881-12887
Site-selective C-H Benzylation of Alkanes with N-triftosylhydrazones Leading to Alkyl Aromatics Zhaohong Liu, Shanshan Cao, Weijie Yu, Jiayi Wu, Fanhua Yi, Edward A. Anderson, and Xihe Bi* Chem 2020, 6, 2110-2124
Computational Studies on Reaction Mechanism of the Catalyst-Controlled Selective Insertion of Metal Carbenoids into C-C and C-H Bonds of 1,3-Dicarbonyl Compounds Shanshan Cao, Zhaohong Liu*, Haiyan Yuan, Liu Yang, Jingping Zhang*, and Xihe Bi* Chin. J. Org. Chem. 2020, 40, 2468-2475
AgN3-Catalyzed Hydroazidation of Terminal Alkynes and Mechanistic Studies Shanshan Cao, Qinghe Ji, Huaizhi Li, Maolin Pang*, Haiyan Yuan, Jingping Zhang*, and Xihe Bi*J. Am. Chem. Soc. 2020, 142, 7083-7091
Synthesis of β-Difluoroalkyl Azides via Elusive 1,2-Azide Migration Yongquan Ning, Paramasivam Sivaguru, Giuseppe Zanoni, Edward A. Anderson, Xihe Bi* Chem 2020, 6, 486-496
Difluoroacetaldehyde N-Triftosylhydrazone (DFHZ-Tfs) as a Bench-Stable Crystalline Diazo Surrogate for Diazoacetaldehyde and Difluorodiazoethane Yongquan Ning, Xinyu Zhang, Yi Gai, Yuanqing Dong, Paramasivam Sivaguru, Yingying Wang, Bhoomireddy Rajendra Prasad Reddy, Giuseppe Zanoni, Xihe Bi* Angew. Chem. Int. Ed. 2020, 59, 6473-6481
Neighbouring Carbonyl Group-assisted Sequential 1,2-Azide and 1,4-Oxygen Migrations of Vinyl Azides Leading to α-Azido Ketones Yi Gai, Yongquan Ning, Paramasivam Sivaguru, Xiaomeng Li, Yue Zhao, Jiayi Wu, and Xihe Bi* Sci. China Chem. 2020, 63, 460–466
Cycloaddition of Trifluoroacetaldehyde N-Triftosylhydrazone (TFHZ-Tfs) with Alkynes for Synthesizing 3-Trifluoromethylpyrazoles Hongwei Wang, Yongquan Ning, Yue Sun, Paramasivam Sivaguru, and Xihe Bi* Org. Lett. 2020, 22, 2012-2016
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