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研究领域

More details are available on the website of the Mark Murrie group. Current magnetic materials are made using a 'top-down' approach. However, these magnetic grains cannot continue to decrease in size indefinitely and new magnetic materials must be developed. If the bit size is to decrease further towards a few nanometres, we move into the realm of magnetic molecules and the possibility of information storage and processing at the molecular level. Our research involves the synthesis and characterisation of new molecular magnetic and nanomagnetic materials, with an ever-growing list of potential applications.

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Woodall, C. H. et al. (2016) Pressure induced enhancement of the magnetic ordering temperature in rhenium(IV) monomers. Nature Communications, 7, 13870. (doi:10.1038/ncomms13870) (PMID:28000676) Marriott, K. E.R., Bhaskaran, L., Wilson, C., Ochsenbein, S. T., Hill, S., and Murrie, M. (2015) Pushing the limits of magnetic anisotropy in trigonal bipyramidal Ni(II). Chemical Science, 2015(6), pp. 6823-6828. (doi:10.1039/C5SC02854J) Heras Ojea, M. J., Milway, V. A., Velmurugan, G., Thomas, L. H., Coles, S. J., Wilson, C., Wernsdorfer, W., Rajaraman, G., and Murrie, M. (2016) Enhancement of TbIII-CuII single-molecule magnet performance through structural modification. Chemistry: A European Journal, 22(36), pp. 12839-12848. (doi:10.1002/chem.201601971) (PMID:27484259) Douglas, F.J., MacLaren, D.A., Tuna, F., Holmes, W.H., Berry, C.C., and Murrie, M. (2014) Formation of octapod MnO nanoparticles with enhanced magnetic properties through kinetically-controlled thermal decomposition of polynuclear manganese complexes. Nanoscale, 6(1), p. 172. (doi:10.1039/C3NR04832B) Kettles, F. J., Milway, V. A., Tuna, F., Valiente, R., Thomas, L. H., Wernsdorfer, W., Ochsenbein, S. T., and Murrie, M. (2014) Exchange interactions at the origin of slow relaxation of the magnetization in {TbCu3} and {DyCu3} single-molecule magnets. Inorganic Chemistry, 53(17), pp. 8970-8978. (doi:10.1021/ic500885r)

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