Mountford, P. - University of Oxford - Department of Chemistry

研究领域

The Mountford Group is an international mixture of postdoctoral researchers, PhD and Oxford Masters (Part II) students, and visiting academic fellows. We are working on the synthesis and stoichiometric and catalytic chemistry of organometallic compounds of the transition and lanthanide metals. Please browse the outline information below and then visit the Mountford Group web site for full details, including the latest news from the group, who we are and what we do, along with details of how to join the group. Selected references are given in the next section. Click here for a printable version of this site.

近期论文

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"Group 4 metal complexes for homogeneous olefin polymerisation: a short tutorial review". R. A. Collins, A. F. Russell and P. Mountford, Appl. Petrochem. Res., 2015, accepted for publication. "s-Block Metal-Metal Bonds". C. Jones, P. Mountford, A. Stasch and M. P. Blake, in Molecular Metal-Metal Bonds: Compounds, Synthesis, Properties, Ed. S. T. Liddle, Wiley, 2015, in the press. "Synthesis, molecular and electronic structure, and reactions of a Zn–Hg–Zn bonded complex". M. P. Blake, N. Kaltsoyannis and P. Mountford, Chem. Commun., 2015, 51, in the press. [link to journal]. Highlighted in the RSC magazine Chemistry World "Reactivity of boryl- and silyl-substituted carbenoids towards alkynes: insertion and cycloaddition chemistry". A. V. Protchenko, M. P. Blake, A. D. Schwarz, C. Jones, P. Mountford and S. Aldridge, Organometallics, 2015, 34, in the press. [link to journal] "The influence of Michael Lappert on the chemistry landscape". J. Arnold, P. J. Brothers, P. Mountford, W. E. Piers, C. M. Thomas and T. D. Tilley, Dalton Trans., 2014, 43, 16553–16556. [link to journal] "Oxidative bond formation and reductive bond cleavage at Main Group metal centers: reactivity of five valence electron MX2 radicals". A. V. Protchenko, D. Dange, M. P. Blake, A. D. Schwarz, C. Jones, P. Mountford and S. Aldridge, J. Am. Chem. Soc., 2014, 136, 10902–10905. [link to journal]. "Heavy metal boryl chemistry: complexes of cadmium, mercury and lead". A. V. Protchenko, D. Dange, A. D. Schwarz, C. Y. Tang, N. Phillips, P. Mountford, C. Jones and S. Aldridge, Chem. Commun., 2014, 50, 3841-3844. [link to journal] "Chiral Lanthanide Complexes bearing amido-bisoxazoline Ligands: Coordination Chemistry, Spectroscopy, and Catalysis". S. D. Bennett, B. A. Core, M. P. Blake, S. J. A. Pope, Philip Mountford and B. D. Ward, Dalton Trans., 2014, 43, 5871-5885. [link to journal] "Stable MX2 radicals (M = Ga, In, Tl)". A. V. Protchenko, D. Dange, J. R. Harmer, C. Y. Tang, A. D. Schwarz, M. J. Kelly, N. Phillips, R. Tirfoin, K. H. Birjkumar, C. Jones, N. Kaltsoyannis, P. Mountford and S. Aldridge, Nature Chem., 2014, 6, 515-319. [link to journal] "Reactions of a cyclopentadienyl-amidinate titanium benzimidamido complex". L. R. Groom, A. F. Russell, A. D. Schwarz and P. Mountford, Organometallics, 2014, 33,1002-1019. [link to journal] "Group 5 hydride and borohydride complexes supported by cyclopentadienyl-imido ligand sets". N. McLeod, L. G. Kuzmina, A. V. Churakov, P. Mountford and G. I. Nikonov, Dalton Trans., 2014, 43, 188-195. [link to journal] "Synthesis and reactions of a cyclopentadienyl-amidinate titanium tert-butoxyimido compound". L. R. Groom, A. D. Schwarz, A. Nova, E. Clot and P. Mountford, Organometallics, 2013, 32, 7520–7539. [link to journal]. Forward to "Advances in metal-catalysed polymerisation and related transformations". P. Mountford as Guest Editor for a Themed Issue, Dalton Trans., 2013, 42, 8977-8978. [link to journal] "Synthesis and reactivity of titanium hydrazido complexes supported by diamido-ether ligands." J. Unruangsri, H. Morgan, A. D. Schwarz, A. D. Schofield and P. Mountford, Organometallics, 2013, 32, 3091–3107. [link to journal] "Synthesis and reactions of beta-diketiminate-supported complexes with Mg Fe or Yb-Fe bonds." M. P. Blake, N. Kaltsoyannis and, P. Mountford, Chem. Commun., 2013, 49, 3315-3317. [link to journal] "Potassium, zinc, and magnesium complexes of a bulky OOO-tridentate bis(phenolate) ligand: synthesis, structures, and studies of cyclic ester polymerisation." Y. Huang, W. Wang, C.-C. Lin, M. P. Blake, L. Clark, A. D. Schwarz and P. Mountford, Dalton Trans., 2013, 42, 9313-9324. Invited contribution for a Special Issue on metal-catalysed polymerisation. [link to journal] "Synthesis and structures of calcium and strontium 2,4-di-tert-butylphenolates and their reactivity towards the amine co-initiated ring-opening polymerisation of rac-lactide." L. Clark, G. B. Deacon, C. M. Forsyth, P. C. Junk, P. Mountford, J. P. Townley, and J. Wang, Dalton Trans., 2013, 42, 9294-9312. Invited contribution for a Special Issue on metal-catalysed polymerisation. [link to journal] "Synthesis, Bonding and Reactivity of a Terminal Titanium Alkylidene Hydrazido Compound." P. J. Tiong, L. R. Groom, E. Clot and P. Mountford, Chem. Eur. J., 2013, 19, 4198-4216. [link to journal]. "A generic one-pot route to acyclic two-coordinate silylenes from Si(IV) precursors: synthesis and structural characterization of a silylsilylene." A. V. Protchenko, A. D. Schwarz, M. P. Blake, C. Jones, N. Kaltsoyannis, P. Mountford and S. Aldridge, Angew. Chem. Int. Ed., 2013, 52, 568–571. [link to journal] "Synthesis and rac-lactide ring-opening polymerisation studies of new alkaline earth tetrahydroborate complexes." R. A. Collins, J. Unruangsri and P. Mountford, Dalton Trans., 2013, 42, 759-769. Invited contribution for a Special Issue on metal borane and borohydride chemistry. [link to journal]