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“Nickel-Catalyzed Cross-Redistribution between Hydrosilanes and Silacyclobutanes” Chen, S.; He, X.; Jin, C.; Zhang, W.; Yang, Y.; Liu, S.; Lan, Y.*; Houk, K. N.*; Shen, X.* Angew. Chem. Int. Ed. 2022, 61, e202213431. (DOI: 10.1002/anie.202213431)
“Enantioselective Synthesis of Spirosilabicyclohexenes by Asymmetric Dual Ring Expansion of Spirosilabicyclobutane with Alkynes” Chen, H.; Peng, J.; Pang, Q.; Du, H.; Huang, L.; Gao, L.; Lan, Y.*; Yang, C.*; Song, Z.* Angew. Chem. Int. Ed. 2022, 61, e202212889. (DOI: 10.1002/anie. 202212889)
“The in Vitro Biosynthesis of Chlorophyll b via Enzyme Catalysis” Niu, L.; Lan, Y.* ACS Cent. Sci. 2022, 8, 1373-1375. (DOI: 10.1021/acscentsci.2c00997)
“Catalytic Multicomponent Synthesis of C-Acyl Glycosides by Consecutive Cross-Electrophile Couplings” Jiang, Y.; Yang, K.; Wei, Y.; Wang, Q.*; Li, S.-J.*; Lan, Y.*; Koh, M. J.* Angew. Chem. Int. Ed. 2022, 61, e202211043. (DOI: 10.1002/anie.202211043)
“Structure, reactivity and catalytic properties of manganese-hydride amidate complexes” Wang, Y.; Liu, S.; Yang, H.; Li, H.; Lan, Y.*; Liu, Q.* Nat. Chem. 2022, 14, ASAP. (DOI: 10.1038/s41557-022-01036-6)
“What is the difference between mono- and biphosphine ligands? Revealing the chemoselectivity in Pd-catalysed carbenation of bromonaphthalene” Gong, W.; Fu, D.; Zhong, K.; Ni, H.; He, X.; Shan, C.*; Li, R.*; Lan, Y.* Org. Chem. Front. 2022, 9, 4916-4923. (DOI: 10.1039/d2qo00910b)
“How Strain-Release Determines Chemoselectivity: A Mechanistic Study of Rhodium-Catalyzed Bicyclo[1.1.0]butane Activation” Lai, W.; Zhong, K.*; Liu, S.; Liu, S.; Chen, H.; Ni, H.; Zeng, Z.; Zhao, Z.; Lan, Y.*; Bai, R.* J. Phys. Chem. Lett. 2022, 13, 7694-7701. (DOI: 10.1021/acs.jpclett.2c01528)
“Regio- and Stereoselective 1,2-Oxyhalogenation of Non-Conjugated Alkynes via Directed Nucleopalladation: Catalytic Access to Tetrasubstituted Alkenes” Liu, M.; Sun, J.; Zhang, T.; Ding, Y.; Han, Y.-Q.; Martín-Montero, R.; Lan, Y.*; Shi, B.-F.*; Engle, K. M.* Angew. Chem. Int. Ed. 2022, 61, e202209099. (DOI: 10.1002/anie.202209099)
“Perfluoroarene Interaction-Controlled Chiral Phosphoric Acid-Catalyzed Enantioselective Michael Addition of Difluoroenoxysilanes to Azadienes: a Combination of Experimental and Theoretical Studies” Li, J.; Chen, H.; Zhong, R.; Zhu, L.; Liu, S.; Ding, H.; Yang, J.; Wang, L.; Lan, Y.*; Wang, Z.* ACS Catal. 2022, 12, 9655-9663. (DOI: 10.1021/acscatal.2c01671)
“The chiral pyridoxal-catalyzed biomimetic Mannich reaction: the mechanism and origin of stereoselectivity” Han, L.-L.; Zhang, Q.-Y.; Li, X.; Qiao, Y.*; Lan, Y.*; Wei, D.* Org. Chem. Front. 2022, 9, 4401-4410. (DOI: 10.1039/d2qo00705c)
“Copper-catalyzed regio- and stereo-selective hydrosilylation of terminal allenes to access (E)-allylsilanes” Chen, S.; He, X.; Jin, Y.; Lan, Y.*; Shen, X.* Nat. Commun. 2022, 13, 3691. (DOI: 10.1038/s41467-022-31458-2)
“The regioselectivity of the sulfonylation of tetrazoles: a theoretical view” Liu, C.-C.; Qiao, B.; Qu, L.-B.; Zhang, T.*; Li, S.-J.*; Lan, Y.* Org. Chem. Front. 2022, 9, 4009-4015. (DOI: 10.1039/d2qo00797e)
“Iminyl radical-triggered relay annulation for the construction of bridged aza-tetracycles bearing four contiguous stereogenic centers” Jiang, K.; Li, S.-J.; Liu, Q.-P.; Yu, N.; Li, Y.-L.; Zhou, Y.-Q.; He, K.-C.; Lin, J.; Zheng, T.-Y.; Lang, J.; Lan, Y.*; Wei, Y.* Chem. Sci. 2022, 13, 7283-7288. (DOI: 10.1039/d2sc01548j)
“An alternative non-redox Ni(I) pathway in hydroaminomethylation: A theoretical perspective” Qiao, B.; Bai, R.; Zhang, T.*; Li, S.-J.*; Lan, Y.* Mol. Catal. 2022, 526, 112378. (DOI: 10.1016/j.mcat.2022.112378)
“Design and synthesis of stable four-coordinated benzotriazole-borane with tunable fluorescence emission” Tang, Q.; Li, S.-J.; Ye, X.; Yuan, T.; Zhao, K.; He, Y.; Shan, C.; Wojtas, L.; Richardson, D.; Lan, Y.*; Shi, X.* Chem. Sci. 2022, 13, 5982-5987. (DOI: 10.1039/d2sc01103d)
“Visible-light-induced cross-coupling of aryl iodides with hydrazones via an EDA-complex” Pan, P.; Liu, S.; Lan, Y.*; Zeng, H.*; Li, C.-J.* Chem. Sci. 2022, 13, 7165-7171. (DOI: 10.1039/d2sc01909d)
“NHC-Catalyzed Transformation Reactions of Imines: Electrophilic versus Nucleophilic Attack” Liu, C.; Han, P.; Zhang, X.; Qiao, Y.; Xu, Z.; Zhang, Y.; Li, D.; Wei, D.*; Lan, Y.* J. Org. Chem. 2022, 87, 7989-7994. (DOI: 10.1021/acs.joc.2c00621)
“Enantioselective Nickel-Catalyzed Si−C(sp2) Bond Activation and Migratory Insertion to Aldehydes: Reaction Scope and Mechanism” Wang, Q.; Zhong, K.-B.; Xu, H.; Li, S.-N.; Zhu, W.-K.; Ye, F.; Xu, Z.; Lan, Y.*; Xu, L.-W.* ACS Catal. 2022, 12, 4571-4580. (DOI: 10.1021/acscatal.2c00533)
“Palladium-Catalyzed Asymmetric [3 + 2] Annulation of Vinylethylene Carbonates with Alkenes Installed on Cyclic N‑Sulfonyl Imines: Highly Enantio- and Diastereoselective Construction of Chiral Tetrahydrofuran Scaffolds Bearing Three Vicinal and Quaternary Stereocenters” Ke, M.; Qiao, B.; Yu, Y.; Li, X.; Xiao, X.; Li, S.-J.; Lan, Y.*; Chen, F.* J. Org. Chem. 2022, 87, 5166-5177. (DOI: 10.1021/acs.joc.1c03157)
“Boryl Radical Activation of Benzylic C−OH Bond: Cross-Electrophile Coupling of Free Alcohols and CO2 via Photoredox Catalysis” Li, W.-D.; Wu, Y.; Li, S.-J.; Jiang, Y.-Q.; Li, Y.-L.; Lan, Y.*; Xia, J.-B.* J. Am. Chem. Soc. 2022, 144, 8551-8559. (DOI: 10.1021/jacs.1c12463)
“Theoretical study on mechanism of cycloaddition reaction between o-alkynylbenzaldoximes and hexynol catalyzed by silver(I)” Yang, X.; Hao, Q.; Li, S.*; Zhu, Y.*; Lan, Y.* Mol. Catal. 2022, 522, 112227. (DOI: 10.1016/j.mcat.2022.112227)
“Regioselectivity of Pd-catalyzed o-carborane arylation: a theoretical view” Liu, J.; Fu, D.; Chen, Z.; Li, T.; Qu, L.-B.; Li, S.-J.*; Zhang, W.*; Lan, Y.* Org. Chem. Front. 2022, 9, 1686-1695. (DOI: 10.1039/d2qo00046f)
“Regiospecific construction of m-alkenyl benzaldehyde from b-bromoenal and vinyl borate” Xin, X.; Liu, Y.; Zhong, L.; Li, Y.; Luo, H.; Liu, L.; Bai, R.; Lan, Y.*; Li, B.* Chem. Commun. 2022, 58, 4989-4992. (DOI: 10.1039/d2cc01441f)
“The Stannum–Ene Reactions of Benzyne and Cyclohexyne with Superb Chemoselectivity for Cyclohexyne” Li, L.; Shan, C.; Shi, J.; Li, W.; Lan, Y.*; Li, Y.* Angew. Chem. Int. Ed. 2022, 61, e202117351. (DOI: 10.1002/anie.202117351)
“Ligand-Controlled Site- and Enantioselective Carbene Insertion into Carbon-Silicon Bonds of Benzosilacyclobutanes” Huo, J.; Zhong, K.; Xue, Y.; Lyu, M.; Ping, Y.; Ouyang, W.; Liu, Z.; Lan, Y.*; Wang, J.* Chem. Eur. J. 2022, 28, e202200191. (DOI: 10.1002/chem.202200191)
“Diradical Generation via Relayed Proton-Coupled Electron Transfer” Shi, Q.; Pei, Z.; Song, J.; Li, S.-J.; Wei, D.*; Coote, M. L.*; Lan, Y.* J. Am. Chem. Soc. 2022, 144, 3137-3145. (DOI: 10.1021/jacs.1c12360)
“Mechanistic Investigation of Cu-Catalyzed Asymmetric Alkynylation of Cyclic N‑Sulfonyl Ketimines with Terminal Alkynes” Zeng, Z.; Yan, F.; Dai, M.; Yu, Z.; Liu, F.; Zhao, Z.; Bai, R.*; Lan, Y.* Organometallics 2022, 41, 270-277. (DOI: 10.1021/acs.organomet.1c00624)
“Mechanistic investigation of zwitterionic MOF-catalyzed enyne annulation using UNLPF-14-MnIII as catalyst” Liu, T.; Duan, R.; Wang, Y.; Li, S.; Qu, L.; Song, J.*; Liu, Q.*; Lan, Y.* Chin. Chem. Lett. 2022, 33, 4281-4286. (DOI: 10.1016/j.cclet.2022.01.041)
“Chemo-, regio- and enantioselective dearomative (3+2) reaction of non-functionalized 1-naphthols” Mei, G.-J.*; Luo, Y.; Koay W. L.; Li, R.; Lan, Y.*; Lu, Y.* Chem Catal. 2022, 2, 386-399. (DOI: 10.1016/j.checat.2021.12.012)
“Deoxygenative Cross-Coupling of Aromatic Amides with Polyfluoroarenes” He, Y.; Wang, Y.; Li, S.-J.; Lan, Y.*; Wang, X.* Angew. Chem. Int. Ed. 2022, 61, e202115497. (DOI: 10.1002/anie.202115497)
“Experimental and Computational Studies on the Directing Ability of Chalcogenoethers in Palladium-Catalyzed Atroposelective C-H Olefination and Allylation” Liao, G.; Zhang, T.; Jin, L.; Wang, B.-J.; Xu, C.-K.; Lan, Y.*; Zhao, Y.*; Shi, B.-F.* Angew. Chem. Int. Ed. 2022, 61, e202115221. (DOI: 10.1002/anie.202115221)
“Carbene-Enabled Ether Activation Through the Formation of Oxonium: A Theoretical View” Wang, Y.-N.; Wang, X.; Li, S.-J.*; Lan, Y.* Org. Chem. Front. 2022, 9, 1247-1253. (DOI: 10.1039/D1QO01730F)
“Chiral Phosphoric Acid Catalyzed Conversion of Epoxides into Thiiranes: Mechanism, Stereochemical Model, and New Catalyst Design” Duan, M.; Díaz-Oviedo, C. D.; Zhou, Y.; Chen, X.; Yu, P.; List, B.*; Houk, K. N.*; Lan, Y.* Angew. Chem. Int. Ed. 2022, 61, e202113204. (DOI: 10.1002/anie.2020113204)
“Is the metal involved or not? A computational study of Cu(I)-catalyzed [4 + 1] annulation of vinyl indole and carbene precursor” He, X.; Zhong, K.; Heng, D.; Zeng, Z.; Ni, H.; Bai, R.*; Lan, Y.* Chin. Chem. Lett. 2022, 33, 2031-2035. (DOI: 10.1016/j.cclet.2021.10.010)
“Insights into Organoamine-Catalyzed Asymmetric Synthesis of Axially Chiral Allenoates Using Morita−Baylis−Hillman Carbonates and Trisubstituted Allenoates: Mechanism and Origin of Stereoselectivity” Zhang, J.; Luo, J.; Li, X.; Zhang, Q.; Wu, Z.; Lan, Y.*; Wei, D.* J. Org. Chem. 2021, 86, 15276-15283. (DOI: 10.1021/acs.joc.1c01871)
“Asymmetric Construction of Tertiary/Secondary Carbon-Phosphorus Bonds via Bifunctional Phosphonium Salt Catalyzed 1,6-Addition” Chen, Y.; Yu, Z.; Jiang, Z.; Tan, J.-P.; Wu, J.-H.; Lan, Y.*; Ren, X.; Wang, T.* ACS Catal. 2021, 11, 14168-14180. (DOI: 10.1021/acscatal.1c03149)
“Hydrogen radical-shuttle (HRS)-enabled photoredox synthesis of indanones via decarboxylative annulation” Yang, B.; Li, S.-J.; Wang, Y.*; Lan, Y.*; Zhu, S.* Nat. Commun. 2021, 12, 5257. (DOI: 10.1038/s41467-021-25594-4)
“On the Me chanism of Cu Catalyzed Hydroboraethylation of Isocyanates” Huang, L.; Wang, Y.; Liu, J.; Li, S.*; Zang, W.*; Lan, Y.* Chin. J. Org. Chem. 2021, 41, 4347-4352. (DOI: 10.6023/cjoc202107031)
“Visible-light photoredox-catalyzed selective carboxylation of C(sp3)-F bonds with CO2” Yan, S.-S.; Liu, S.-H.; Chen, L.; Bo, Z.-Y.; Jing, K.; Gao, T.-G.; Yu, B.; Lan, Y.*; Luo, S.-P.; Yu, D.-G.* Chem 2021, 7, 3099-3113. (DOI: 10.1016/j.chempr.2021.08.004)
“Practical DMSO-promoted selective hydrolysis–oxidation of lignocellulosic biomass to formic acid attributed to hydrogen bonds” Guo, Y.-J.; Li, S.-J.; Sun, Y.-L.; Wang, L.; Zhang, W.-M.; Zhang, P.; Lan, Y.*; Li, Y.* Green Chem. 2021, 23, 7041-7052. (DOI: 10.1039/D1GC02265B)
“Palladium-Catalyzed Enantioselective Carbene Insertion into Carbon−Silicon Bonds of Silacyclobutanes” Huo, J.; Zhong, K.; Xue, Y.; Lyu, M.; Ping, Y.; Liu, Z.; Lan, Y.*; Wang, J.* J. Am. Chem. Soc. 2021, 143, 12968-12973. (DOI: 10.1021/jacs.1c05879)
“Oxymetalation or oxidative cyclization? mechanism of Pd-catalyzed annulation of enynones” Ni, H.; He, X.; Zhong, K.; Chen, H.; Lai, W.; Zhao, Z.; Zeng, Z.; Bai, R.*; Lan, Y.* Chem. Commun. 2021, 57, 8316-8319. (DOI: 10.1039/d1cc02744a)
“Dehydrogenative 6π heterocyclization under visible light irradiation and mechanistic insights” Zhang, Z.; Chen, H.; Keller, N.; Xiong, Q.; Liu, L.; Lan, Y.*; Bein, T.*; Li, J.* Org. Chem. Front. 2021, 8, 3788-3795. (DOI: 10.1039/d1qo00356a)
“Benzyne 1,2,4-Trisubstitution and Dearomative 1,2,4-Trifunctionalization” Shi, J.; Li, L.; Shan, C.; Chen, Z.; Dai, L.; Tan, M.; Lan, Y.*; Li, Y.* J. Am. Chem. Soc. 2021, 143, 10530-10536. (DOI: 10.1021/jacs.1c04389)
“Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations” Qi, X.*; Lan, Y.* Acc. Chem. Res. 2021, 54, 2905-2915. (DOI: 10.1021/acs.accounts.1c00075)
“Rhodium(II)-Catalyzed Regioselective Remote C−H Alkylation of Protic Indoles” Kong, L.; Han, X.; Chen, H.; Sun, H.; Lan, Y.*; Li, X.* ACS Catal. 2021, 11, 4929-4935. (DOI: 10.1021/acscatal.1c01052)
“C(sp2)−X (X = Cl, Br, and I) Reductive Eliminations from Well-Defined Gold(III) Complexes: Concerted or Dissociation Pathways?” Kang, K.; Liu, S.; Xu, C.; Lu, Z.; Liu, S.; Leng, X.; Lan, Y.*; Shen ,Q.* Organometallics 2021, 40, 2231-2239. (DOI: 10.1021/acs.organomet.0c00784)
“C(sp2)‑CF3 Reductive Elimination from Well-Defined Argentate(III) Complexes [nBu4N][Ag(Ar)(CF3)3]” Lu, Z.; Liu, S.; Lan, Y.*; Leng, X.; Shen, Q.* Organometallics 2021, 40, 1713-1718. (DOI: 10.1021/acs.organomet.1c00195)
“Photoredox Catalysis Unlocks the Nickel-Catalyzed Cyanation of Aryl Halides under Benign Conditions” Jia, Y.; Liu, Y.-Y.; Lu, L.-Q.; Liu, S.-H.; Zhou, H.-B.; Lan, Y.*; Xiao, W.-J.* CCS Chem. 2021, 3, 2032-2041. (DOI: 10.31635/ccschem.021.202100934)
“Atom Recombination of Difluorocarbene Enables 3-Fluorinated Oxindoles from 2-Aminoarylketones” Zhang, G.; Shi, Q.; Hou, M.; Yang, K.; Wang, S.; Wang, S.; Li, W.; Li, C.; Qiu, J.; Xu, H.; Zhou, L.; Wang, C.; Li, S.-J.; Lan, Y.*; Song, Q.* CCS Chem. 2021, 3, 1613-1621. (DOI: 10.31635/ccschem.021.202100979)
“Mechanistic studies on nickel-catalyzed enantioselective [3 + 2] annulation for γ-butenolide synthesis via C-C activation of diarylcyclopropenones” Bai, D.*; Liu, S.; Chen, J.; Yu, Y.; Wang, M.; Chang, J.; Lan, Y.*; Li, X.* Org. Chem. Front. 2021, 8, 3023-3031. (DOI: 10.1039/D1QO00322D)
“Tuning the reactivity of alkoxyl radicals from 1,5-hydrogen atom transfer to 1,2-silyl transfer” Yang, Z.; Niu, Y.; He, X.; Chen, S.; Liu, S.; Li, Z.; Chen, X.; Zhang, Y.; Lan, Y.*; Shen, X.* Nat. Commun. 2021, 12, 2131. (DOI: 10.1038/s41467-021-22382-y)
“Biomimetic Carbene Cascades Enabled Imine Derivative Migration from Carbene-Bearing Thiocarbamates” Li, X.; Chen, H.; Xuan, Q.; Ma, S.; Lan, Y.*; Song, Q.* Org. Lett. 2021, 23, 3518-3523. (DOI: 10.1021/acs.orglett.1c00930)
“Oxidation of Pd(II) with disilane in a palladium-catalyzed disilylation of aryl halides: a theoretical view” Zhang, J.; Liu, S.; Zhang, T.; Liu, T.*; Lan, Y.* Dalton Trans. 2021, 49, 7656-7666. (DOI: 10.1039/d1dt00399b)
“Metal-free C(sp3)–H functionalization of sulfonamides via strain-release rearrangement” Hu, J.*; Yang, X.; Shi, S.; Cheng, B.; Luo, X.*; Lan, Y.*; Loh, T.-P.* Chem. Sci. 2021, 12, 4034-4340. (DOI: 10.1039/d0sc06603f)
“Theoretical Model for N‑Heterocyclic Carbene-Catalyzed Desymmetrizing [4 + 1] and [4 + 2] Annulations of an Enal and Aryldialdehyde with 1,3-Cyclopentenedione” Wang, X.; Li, S.-J.; Wang, Y.-N.; Wei, D.*; Lan, Y.* Org. Lett. 2021, 23, 2421-2425. (DOI: 10.1021/acs.orglett.1c00270)
“Insights into the chiral sulfide/selenide-catalyzed electrophilic carbothiolation of alkynes: mechanism and origin of axial chirality” Zhang, Q.-Y.; Li, S.-J.; Wang, Y.; Song, J.; Lan, Y.*; Wei, D.* Org. Chem. Front. 2021, 8, 1983-1990. (DOI: 10.1039/d1qo00036e)
“Ligand coordination- and dissociation induced divergent allylic alkylations using alkynes” Huang, Y.; Ma, C.; Liu, S.; Yang, L.-C.; Lan, Y.*; Zhao, Y.* Chem 2021, 7, 812-826. (DOI: 10.1016/j.chempr.2021.02.018)
“On the mechanism of homogeneous Pt-catalysis: A theoretical view” Chen, H.; Li, Y.*; Liu, S.*; Xiong, Q.; Bai, R.; Wei, D.*; Lan, Y.* Coor. Chem. Rev. 2021, 437, 213863. (DOI: 10.1016/j.ccr.2021.213863)
“Synergistic Dinuclear Rhodium Induced Rhodium-Walking Enabling Alkene Terminal Arylation: A Theoretical Study” Heng, D.; Chen, H.; He, X.; Liu, S.; Zhu, L.; Zhong, K.; Zhang, T.; Bai, R.*; Lan, Y.* ACS Catal. 2021, 11, 3975-3987. (DOI: 10.1021/acscatal.0c05554)
“Desymmetrization of 1,3-Diones by Catalytic Enantioselective Condensation with Hydrazine” Yang, B.; Dai, J.; Luo, Y.; Lau, K. K.; Lan, Y.*; Shao, Z.*; Zhao, Y.* J. Am. Chem. Soc. 2021, 143, 4179-4186. (DOI: 10.1021/jacs.1c01366)
“Multiple Functional Organocatalyst-Promoted Inert C–C Activation: Mechanism and Origin of Selectivities” Zhang, M.; Wang, Y.; Li, S.-J.; Wang, X.; Shi, Q.; Li, X.; Qu, L.-B.; Wei, D.*; Lan, Y.* ACS Catal. 2021, 11, 3443-3454. (DOI: 10.1021/acscatal.0c05511)
“How Solvents Control the Chemoselectivity in Rh-Catalyzed Defluorinated [4 + 1] Annulation” Liu, S.; Zhu, L.; Zhang, T.; Zhong, K.; Li, S.-J.; Bai, R.*; Lan, Y.* Org. Lett. 2021, 23, 1489-1494. (DOI: 10.1021/acs.orglett.1c00223)
“Catalytic Atroposelective Catellani Reaction Enables to Construct Axially Chiral Biaryl Monophosphine Oxides” Feng, Q.; Ma, X.; Bao, W.; Li, S.-J.; Lan, Y.*; Song, Q.* CCS Chem. 2021, 3, 377-387. (DOI: 10.31635/ccschem.021.202000725)
“Aryne 1,2,3,5-Tetrasubstitution Enabled by 3‑Silylaryne and Allyl Sulfoxide via an Aromatic 1,3-Silyl Migration” Shi, J.; Li, L.; Shan, C.; Wang, J.; Chen, Z.; Gu, R.; He, J.; Tan, M.; Lan, Y.*; Li, Y.* J. Am. Chem. Soc. 2021, 143, 2178-2184. (DOI: 10.1021/jacs.0c11119)
“Lewis acid–catalyzed domino generation/[2,3]-sigmatropic rearrangement of ammonium ylidesto access chiral azabicycles” Xi, S.; Dong, J.; Chen, H.; Dong, Q.; Yang, J.; Tan, Q.; Zhang, C.; Lan, Y.*; Zhang, M.* Sci. Adv. 2021, 7, eabd5290. (DOI: 10.1126/sciadv.abd5290)
“Rhodium-Catalyzed Atroposelective Construction of Indoles via C-H Bond Activation” Sun, L.; Chen, H.; Liu, B.; Chang, J.; Kong, L.; Wang, F.*; Lan, Y.*; Li, X.* Angew. Chem. Int. Ed. 2021, 60, 8391-8395. (DOI: 10.1002/anie.202012932)
“Predicting the origin of selectivity in NHCcatalyzed ring opening of formylcyclopropane: a theoretical investigation” Wang, Y.; Qiao, Y.; Lan, Y.*; Wei, D.* Catal. Sci. Tech. 2021, 11, 332-337. (DOI: 10.1039/d0cy01768j)
“Is the reaction sequence in phosphine-catalyzed [8+2] cycloaddition controlled by electrophilicity?” Lin, W.-X.; Pei, Z.; Gong, C.; Mo, H.; Yang, K.; Qu, L.-B.; Wei, D.; Song, J.-S.*; Li, S.-J.*; Lan, Y.* Chem. Commun. 2021, 57, 761-764. (DOI: 10.1039/d0cc07370a)
“Mechanistic insights into the rhodium-copper cascade catalyzed dual C-H annulation of indoles” He, X.; Zhu, L.; Heng, D.; Liu, F.; Liu, S.; Zhong, K.; Shan, C.*; Bai, R.*; Lan, Y.* Org. Chem. Front. 2020, 7, 1739-1746. (DOI: 10.1039/D0QO01332C)
“Elemental sulfur enabled divergent synthesis of disulfides, diselenides and polythiophenes from β-CF3-1,3-enynes” Jin, S.; Li, S.-J.; Ma, X.; Su, J.; Chen, H.; Lan, Y.*; Song, Q.* Angew. Chem. Int. Ed. 2021, 60, 881-888. (DOI: 10.1002/anie.202009194)
“Possible Mechanisms and Origin of Selectivities for Phosphine-Catalyzed [2+n] (n=3, 4) Annulations of Saturated Amines and δ-Acetoxy Allenoates” Yang, T.-T.; Wang, C.; Li, S.-J.; Zhang, M.; Wei, D.*; Lan, Y.* Asian J. Org. Chem. 2021, 10, 619-625. (DOI: 10.1002/ajoc.202000679)
“How to inverse the chemoselectivity of nucleophilic addition by using a Lewis acid/Brønsted base pair catalyst: A theoretical view” Liu, C.; Li, S.-J.; Han, P.; Qu, L.-B.*; Lan, Y.* J.Mol. Catal. A, Chemical 2021, 499, 111318. (DOI: 10.1016/j.mcat.2020.111318)
“Manganese-Catalyzed Asymmetric Hydrogenation of Quinolines Enabled by π-π Interaction” Liu, C.; Wang, M.; Liu, S.; Wang, Y.; Peng, Y.; Lan, Y.*; Liu, Q.* Angew. Chem. Int. Ed. 2021, 60, 5108-5113. (DOI: 10.1002/anie.202013540)
“Insight into Organocatalytic Arylation of Azonaphthalenes with α-Chloroaldehydes: General Mechanism and Origin of Selectivities” Wang, X.; Wang, Y.; Wei, D.*; Lan, Y.* Chem. Commun. 2021, 57, 219-222. (DOI: 10.1039/D0CC07260E)
“N-Heterocyclic carbene-catalyzed enantioselective hetero-[10 +2] annulation” Peng, Q.; Li, S.-J.; Zhang, B.; Guo, D.; Lan, Y.*; Wang, J.* Commun. Chem. 2020, 3, 177. (DOI: 10.1038/s42004-020-00425-7)
“Quadruple C-H activation coupled to hydrofunctionalization and C-H silylation/borylation enabled by weakly coordinated palladium catalyst” Tang, B.-C.; Lin, W.-X.; Chen, X.-L.; He, C.; Ma, J.-T.; Wu, Y.-D.; Lan, Y.*; Wu, A.-X.* Nat. Commun. 2020, 11, 5662. (DOI: 10.1038/s41467-020-19508-z)
“Iron-Catalyzed Radical Relay Enabling the Modular Synthesis of Fused Pyridines from Alkyne-Tethered Oximes and Alkenes” Du, F.; Li, S.-J.; Jiang, K.; Zeng, R.; Pan, X.-C.*; Lan, Y.*; Chen, Y.-C.*; Wei, Y.* Angew. Chem. Int. Ed. 2020, 59, 23755-23762. (DOI: 10.1002/anie.202010752)
“Chemoselective Union of Olefins, Organohalides, and Redox-Active Esters Enables Regioselective Alkene Dialkylation” Yang, T.; Jiang, Y.; Luo, Y.; Li, J. J. H.; Lan, Y.*; Koh, M. J.* J. Am. Chem. Soc. 2020, 142, 21410-21419. (DOI: 10.1021/jacs.0c09922)
“Nickel-Catalyzed C-F/N-H Annulation of Aromatic Amides with Alkynes: Activation of C-F Bonds under Mild Reaction Conditions” Nohira, I.; Liu, S.; Bai, R.; Lan, Y.*; Chatani, N.* J. Am. Chem. Soc. 2020, 142, 17306-17311. (DOI: 10.1021/jacs.0c08512)
“Palladium-Catalyzed Intermolecular trans-Selective Carbofunctionalization of Internal Alkynes to Highly Functionalized Alkenes” Lv, W.; Liu, S.; Chen, Y.; Wen, S.; Lan, Y.*; Cheng, G.* ACS Catal. 2020, 10, 10516-10522. (DOI: 10.1021/acscatal.0c02522)
“Hydrogen-Bonding-Promoted Cascade Rearrangement Involving the Enlargement of Two Rings: Efficient Access to Polycyclic Quinoline Derivatives” Cao, W.-B.; Li, S.; Xu, M.-M.; Li, H.; Xu, X.-P.*; Lan, Y.*; Ji, S.-J.* Angew. Chem. Int. Ed. 2020, 59, 21425-21430. (DOI: 10.1002/anie.202008110)
“Visible Light-Driven Anti-Markovnikov Hydrocarboxylation of Acrylates and Styrenes with CO2” Huang, H.; Ye, J.-H.; Zhu, L.; Ran, C.-K.; Miao, M.; Wang, W.; Chen, H.; Zhou, W.-J.; Lan, Y.*, Yu, B.; Yu, D.-G.* CCS Chem. 2020, 2, 1746-1759. (DOI: 10.31635/ccschem.020.202000374)
“Visible-Light Photoredox-Catalyzed Remote Difunctionalizing Carboxylation of Unactivated Alkenes with CO2” Song, L.; Fu, D.-M.; Chen, L.; Jiang, Y.-X.; Ye, J.-H.; Zhu, L.; Lan, Y.*; Fu, Q.; Yu, D.-G.* Angew. Chem. Int. Ed. 2020, 59, 21121-21128. (DOI: 10.1002/anie.202008630)
“Utilizing Vinylcyclopropane Reactivity: Palladium-Catalyzed Asymmetric [5+2] Dipolar Cycloadditions” Li, M.-M.; Xiong, Q.; Qu, B.-L.; Xiao, Y.-Q.; Lan, Y.*; Lu, L.-Q.; Xiao, W.-J. Angew. Chem. Int. Ed. 2020, 59, 17429-17434. (DOI: 10.1002/anie.202006366)
“Dynamic Kinetic Asymmetric Amination of Alcohols Assisted by Microwave: Stereo-convergent Access to Tetralin- and Indane-Derived Chiral Amines” Rong, Z.-Q.; Yu, Z.; Weng, C.; Yang, L.-C.; Lu, S.; Lan, Y.*; Zhao, Y.* ACS Catal. 2020, 10, 9464-9475. (DOI: 10.1021/acscatal.0c02468)
“Cu-Catalyzed Regio- and Stereodivergent Chemoselective sp2/sp3 1,3- and 1,4-Diborylations of CF3-Containing 1,3-Enynes” Kuang, Z.; Chen, H.; Qiu, J.; Ou, Z.; Lan, Y.*; Song, Q.* Chem 2020, 6, 2347-2363. (DOI: 10.1016/j.chempr.2020.06.034)
“Insights into Lewis base-catalyzed chemoselective [3 + 2] and [3 + 4] annulation reactions of MBH carbonates” Deng, Q.; Li, S.-J.; Wei, D.*; Lan, Y.* Org. Chem. Front. 2020, 7, 1828-1836. (DOI: 10.1039/d0qo00457j)
“Mechanism and Regioselectivity of 1,3-Dipolar Cycloaddition of Nitrile Oxides to 3-Methylene Oxindole: A Density Functional Theory Study” Luo, X.; Liu, S.; Lan, Y.* ChemistrySelect 2020, 5, 8421-8428. (DOI: 10.1002/slct.202002672)
“σ-Bond Migration Assisted Decarboxylative Activation of Vinylene Carbonate in Rh-Catalyzed 4+2 Annulation: A Theoretical Study” Shen, B.; Liu, S.; Zhu, L.; Zhong, K.; Liu, F.; Chen, H.; Bai, R.*; Lan, Y.* Organometallics 2020, 39, 2813-2819. (DOI: 10.1021/acs.organomet.0c00248)
“Prediction of NHC-catalyzed chemoselective functionalizations of carbonyl compounds: A general mechanistic map” Li, X.; Xu, J.; Li, S.-J.; Qu, L.-B.; Li, Z.; Chi, Y. R.; Wei, D.*; Lan, Y.* Chem. Sci. 2020, 11, 7214-7225. (DOI: 10.1039/D0SC01793K)
“Regio- and Enantioselective Palladium-Catalyzed Asymmetric Allylation of N-Fluorenyl Trifluoromethyl Imine” Wang, W.; Xiong, Q.; Gong, L.; Wang, Y.; Liu, J.*; Lan, Y.*; Zhang, X.* Org. Lett. 2020, 22, 5479-5485. (DOI: 10.1021/acs.orglett.0c01836)
“Palladium-Catalyzed Asymmetric [8+2] Dipolar Cycloadditions of Vinyl Carbamates and Photogenerated Ketenes” Zhang, Q.-L.; Xiong, Q.; Li, M.-M.; Xiong, W.; Shi, B.; Lan, Y.*; Lu, L.-Q.*; Xiao, W.-J. Angew. Chem. Int. Ed. 2020, 59, 14096-14100. (DOI: 10.1002/anie.202005313)
“Stereoselective Access to [5.5.0] and [4.4.1] Bicyclic Compounds through Pd-Catalysed Divergent Higher-Order Cycloadditions” Yang, L.-C.; Wang, Y.-N.; Liu, R.; Luo, Y.; Ng, X. Q.; Yang, B.; Rong, Z.-Q.; Lan Y.*; Shao, Z.; Zhao, Y.* Nat. Chem. 2020, 12, 860-868. (DOI: 10.1038/s41557-020-0503-7)
“Mechanism of Palladium-Catalyzed Spiroannulation of Naphthols with Alkynes: A Density Functional Theory Study” Luo, X.; Zhong, K.; Lan, Y.* ChemCatChem 2020, 12, 3863-3869. (DOI: 10.1002/cctc.202000613)
“C(sp3)-CF3 Reductive Elimination from a Five-Coordinate Neutral Copper(III) Complex” Liu, S.; Liu, H.; Liu, S.; Lu, Z.; Lu, C.; Leng, X.; Lan, Y.*; Shen, Q.* J. Am. Chem. Soc. 2020, 142, 9785–9791. (DOI: 10.1021/jacs.0c03304)
“Unveiling the Chemo- and Stereoselectivities of NHC-Catalyzed Reactions of Aliphatic Ester with Aminochalcone” Wang, Y.; Qu, L.-B.; Wei, D.*; Lan, Y.* J. Org. Chem. 2020, 85, 8437-8446. (DOI: 10.1021/acs.joc.0c00769)
“Is Cu(III) a necessary intermediate in Cu-mediated coupling reactions? A mechanistic point of view” Li, S.-J.; Lan, Y.* Chem. Commun. 2020, 56, 6609-6619. (DOI: 10.1039/d0cc01946a)
“Reagent addition sequence and equivalent in N-heterocyclic carbene-catalyzed nonpolar inversion enable conversion from aldimine to benzoxazole” Li, X.; Liu, J.; Zhang, Q.-C.; Zhang, W.*; Lan, Y.* Int. J. Quantum Chem. 2020, e26249. (DOI: 10.1002/qua.26249)
“Highly Regio- and Enantioselective Hydrogenation of Conjugated α-Substituted Dienoic Acids” Liu, X.; Liu, S.; Wang, Q.; Zhou, G.; Yao, L.; Ouyang, Q.; Jiang, R.*; Lan, Y.*; Chen, W.* Org. Lett. 2020, 22, 3149-3154. (DOI: 10.1021/acs.orglett.0c00915)
“With metal or not? a computationally predicted rule for a dirhodium catalyst in [3+3] cycloadditions of triazole with thiirane” Li, S.-J.; Li, X.; Mo, H.; Qu, L.-B.; Wei, D.*; Lan, Y.* Chem. Commun. 2020, 56, 4732-4735. (DOI: 10.1039/d0cc01293a)
“Kinetically Controlled Radical Addition/Elimination Cascade: From Alkynyl Aziridine to Fluorinated Allenes” Song, T.; Zhu, L.; Li, H.; Tung, C.-H.; Lan, Y.*; Xu, Z.* Org. Lett. 2020, 22, 2419-2424. (DOI: 10.1021/acs.orglett.0c00622)
“Protecting-Group-Free Total Syntheses of (±)-Norascyronones A and B” Cao, T.; Zhu, L.; Lan, Y.*; Huang, J.*; Yang, Z.* Org. Lett. 2020, 22, 2517-2521 (DOI: 10.1021/acs.orglett.0c00212)
“Mechanism of Ir-catalyzed hydrogenation: A theoretical view” Cui, C.-X.; Chen, H.; Li, S.-J.; Zhang, T.; Qu, L.-B.; Lan, Y.* Coor. Chem. Rev. 2020, 412, 213251. (DOI: 10.1016/j.ccr.2020.213251)
“A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group” Zhan, M.; Ding, Z.; Du, S.; Chen, H.; Feng, C.; Xu, M.; Liu, Z.; Zhang, M.; Wu, C.; Lan, Y.*; Li, P.* Nat. Commun. 2020, 11, 792. (DOI: 10.1038/s41467-020-14592-7)
“Layered Chirality Relay Model in Rh(I)-Mediated Enantioselective C−Si Bond Activation: A Theoretical Study” Liu, S.; Zhang, T.; Zhu, L.; Liu, F.; Bai, R.*; Lan, Y.* Org. Lett. 2020, 22, 2124-2128. (DOI: 10.1021/acs.orglett.9b04636)
“Origin of Regio- and Stereoselectivity in the NHC-catalyzed Reaction of Alkyl Pyridinium with Aliphatic Enal” Wang, Y.; Qu, L.-B.; Lan, Y.*; Wei, D.* ChemCatChem 2020, 12, 1068-1074. (DOI: 10.1002/cctc.201901965)
“Nucleophilicity versus Brønsted basicity controlled chemoselectivity: mechanistic insight into silver- or scandium-catalyzed diazo functionalization” Liu, F.; Zhu, L.; Zhang, T.; Zhong, K.; Xiong, Q.; Shen, B.; Liu, S.; Lan, Y.*; Bai, R.* ACS Catal. 2020, 10, 1256-1263. (DOI: 10.1021/acscatal.9b02040)
“Reaction Scope and Mechanistic Insights of Nickel-Catalyzed Migratory Suzuki-Miyaura Cross-Coupling” Li, Y.; Luo, Y.; Peng, L.; Li, Y.; Zhao, B.; Wang, W.; Pang, H.; Deng, Y.; Bai, R.; Lan, Y.*; Yin, G.* Nat. Commun. 2020, 11, 147. (DOI: 10.1038/s41467-019-14016-1)
“Mechanism and origin of diastereoselectivity of N-heterocyclic carbene-catalyzed cross-benzoin reaction: A DFT study” Wang, Y.; Lan, Y.* Chin. Chem. Lett. 2020, 31, 736-738. (DOI: 10.1016/j.cclet.2019.08.010)
“Visible-Light-Induced Alkoxyl Radicals Enable α-C(sp3)-H Bond Allylation” Zhang, J.; Liu, D.; Liu, S.; Ge, Y.; Lan, Y.*; Chen, Y.* iScience, 2020, 23, 100755. (DOI: 10.1016/j.isci.2019.100755)
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