张兆国 - 上海交通大学 - 化学化工学院

研究领域

1、金属有机化学与不对称催化 2、精细有机合成 3、可见光条件下的催化反应

近期论文

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Zhang, L.; Xie, X.; Fu, L.; Zhang, Z. “[RuCl2(p-cymene)]2-Catalyzed Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Ketones under Ligand-Free and Neutral Conditions” J. Org. Chem. 2013, 78, 3434-3437. Ren, K.; Zhang, L.; Hu, B.; Zhao, M.; Tu, Y.; Xie, X.; Zhang, T. Y.; Zhang, Z. “Cationic-Rhodium-Catalyzed Kinetic Resolution of Allylic Alcohols through a Redox Isomerization Reaction in a Noncoordinating Solvent” ChemCatChem 2013, 5, 1317-1320. Tao, X.; Li, W.; Li, X.; Xie, X.; Zhang, Z. “Diastereo- and Enantioselective Asymmetric Hydrogenation of α-Amido-β-keto Phosphonates via Dynamic Kinetic Resolution” Org. Lett. 2013, 15, 72-75. Li, W.; Tao, X.; Ma, X.; Fan, W.; Li, X.; Zhao, M; Xie, X.; Zhang, Z. “Ru-Catalyzed Asymmetric Hydrogenation of 3-Oxoglutaric Acids Derivatives: Study on the Unconventional Solvent and Substituent Effects” Chem. Eur. J. 2012, 18, 16531-16539. Tao, X.; Li, W.; Ma, X.; Li, X.; Fan, W.; Zhu, L.; Xie, X.; Zhang, Z. “Enantioselective Hydrogenation of β Ketophosphonates with Chiral Ru(II) Catalysts” J. Org. Chem. 2012, 77, 8401-8409. Ma, F.; Xie, X.; Zhang, L.; Peng, Z.; Ding, L.; Fu, L.; Zhang, Z. “Palladium-Catalyzed Amidation of Aryl Halides Using 2-Dialkylphosphino- 2′-alkoxyl-1,1′-binaphthyl as Ligands”, J. Org. Chem., 2012, 77, 5279–5285. Jackowski, O.; Wang, J.; Xie,X.; Ayad, T.; Zhang, Z.; Ratovelomanana-Vidal, V. Enantioselective Rhodium-Catalyzed Synthesis of α-Chloromethylene-γ- Butyrolactams from N-Allylic Alkynamides, Enantioselective Synthesis of 1-Aryl-tetrahydroisoquinolines through Iridium Catalyzed Asymmetric Hydrogenation, Org. Lett. 2012, 14, 3308. Berhal, F.; Wu, Z.; Zhang, Z.; Ayad, T.; Ratovelomanana-Vidal V. “Enantioselective Synthesis of 1-Aryl-tetrahydroisoquinolines through Iridium Catalyzed Asymmetric Hydrogenation” Org. Lett. 2012, 14, 4006. Li, W.; Fan, W.; Ma, X.; Tao, X.; Li, X.; Xie, X.; Zhang, Z. “Ru-catalyzed hydrogenation of 3,5-diketo amides: simultaneous control of chemo- and enantioselectivity” Chem. Commun. 2012, 48, 8976. Ma, X.; Li, W.; Li, X.; Tao, X.; Fan, W.; Xie, X.; Ayad, T.; Vidal, V.; Zhang, Z. “Ru-catalyzed highly chemo- and enantioselective hydrogenation of -halo- -unsaturated--keto esters under neutral conditions” Chem. Commun. 2012, 48, 5352. Fan, W.; Li, W.; Ma, X.; Tao, X.; Li, X.; Yao, Y.; Xie, X.; Zhang, Z. “Acid-labile -ketal--hydroxy esters by asymmetric hydrogenation of corresponding -ketal--keto esters in the presence of CaCO3” Chem. Commun. 2012, 48, 4247. Li, W.; Xie, X.; Tao, X.; Ma, X.; Fan, W.; Li, X.; Zhang, Z. “RuCl2(PPh3)3-catalyzed chemoselective hydrogenation of -diketo acid derivatives at the -carbonyls” RSC Adv.. 2012, 2, 3214. Tao, X.; Li, W.; Ma, X.; Li, X.; Fan, W.; Xie, X.; Ratovelomanana-Vidal, V.; Ayad, T.; Zhang, Z. J. Org. Chem. 2012, 77, 612. Yang, Y.; Chen, L.; Zhang, Z.; Zhang Y. “Palladium-Catalyzed Oxidative C−H Bond and C═C Double Bond Cleavage: C-3 Acylation of Indolizines with α,β-Unsaturated Carboxylic Acids” Org. Lett. 2011, 13, 1342. Fan, W.; Li, W.; Ma, X.;Tao, X.; Li, X.; Yao, Y.; Xie, X.; Zhang, Z. “Ru-Catalyzed Asymmetric Hydrogenation of γ-HeteroatomSubstituted β-Keto Esters ” J. Org. Chem. 2011, 76, 9445. Li, W.; Ma, X.; Fan, W.; Tao, X.; Li, X.; Xie, X.; Zhang, Z. “Ru-Catalyzed Asymmetric Hydrogenation of 3-Oxoglutaric Acid Derivatives via Solvent-Assisted Pinpoint Recognition of Carbonyls in Close Chemical Propinquity” Org. Lett. 2011, 13, 3876. Yao, Y.; Fan, W.; Li, X.; Ma, X.; Zhu, L.; Xie, X. “Synthesis of (S)-7-Amino-5-azaspiro[2.4]heptane via Highly Enantioselective Hydrogenation of Protected Ethyl1-(2-Aminoaceto)cyclopropanecarboxylates” J. Org. Chem. 2011, 76, 2807.