王新平 - 中国科学院上海有机化学研究所 - 金属有机化学国家重点实验室

个人简介

Biography 1993/9-1997/6, Sichuan University, Chemistry, Bachelor degree, Tutor: Professor Chen Yaoqiang 1997/9-2000/6, Lanzhou University, Chemistry, Master, Tutor: Professor Zeng Zhengzhi 2001/9-2007/6, University of New Brunswick, Canada, Chemistry, PhD, Supervisor: Professor Jack Passmore 2007/11-2010/10, University of California, Davis, Chemistry, Postdoctoral, supervisor: Professor Philip P. Power 2010/11-2012/3, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Associate Professor 2012/4-2023/2, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Professor 2022/7-present, State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Professor Awards and Honors Class A of the High-level Talent Initiative of the Chinese Academy of Sciences (2022) National Talent Program Leading Talent (2019) Young and middle-aged Leading Talents in Science and Technology Innovation of the Ministry of Science and Technology (2016) Cheung Kong Scholars Program Distinguished Professor of Ministry of Education (2015) National Science Foundation for Outstanding Young People (2015) Science Foundation for Outstanding Youth of Jiangsu Province (2014) Entrepreneurship and Innovation Plan of Jiangsu Province (2013) New Century Excellent Talents Support Program of Ministry of Education (2012) National Overseas Young Talents Program (2011) Outstanding Young Key Teachers Program of Nanjing University (2011) National Scholarship for Outstanding Self-Funded Foreign Students of Ministry of Education (2006)

研究领域

课题组根据空间位阻效应和电子性质，设计配体，合成自由基化合物，结合光(波)谱表征技术和量子化学计算, 对生成的自由基化合物的结构、化学健本质和反应机理进行深层次的研究，并挖掘自由基化合物可能具有的功能特性如催化、发光、导电和磁性等，来发现和解决基础化学领域中的重要问题。主要从事以下几方面的研究：新型自由基化合物的合成基于自由基的活化与催化自由基光电功能自由基分子磁体自由基超导材料

近期论文

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1.X. Dong, Q. Luo, Y. Zhao, T. Wang, Q. Sun, R. Pei, Y. Zhao, Y. Zheng* and X. Wang*. A Dynamic Triradical：Synthesis, Crystal Structure and Spin Frustration. J. Am. Chem. Soc. 2023, DOI:10.1021/jacs.3c04692. 2.M. Liu, X. Yang, Q. Sun, T. Wang, R. Pei, X. Yang, Y. Zhao, L. Zhao,* G. Frenking,* X. Wang,* Lewis Acid-Mediated Radical Stabilization and Dynamic Covalent Bonding: Tunable, Reversible and Photocontrollable. Angew. Chem. Int. Ed. 2023, published online, DOI:10.1002/anie.202300068. 3.W. Wang, X. Ma, M. Liu, S. Tang, X. Ding, Y. Zhao, Y. Tan,* M. Kertesz,* X. Wang,* A Triply Negatively Charged Nanographene Bilayer with Spin Frustration.Angew. Chem. Int. Ed. 2023, published online,DOI:10.1002/anie.202217788. 4.J. Wang, H. Cui, H. Ruan, Y. Zhao, Y. Zhao, L. Zhang,* X. Wang,* The Lewis Acid-Induced Formation of a Stable Diradical with an Intra Molecular Ion Pairing State. J. Am. Chem. Soc. 2022, 144, 18, 7978-7982. 5.Z. Feng, S. Tang, Y. Su, X. Wang,* Recent Advances in Stable Main Group Element Radicals: Preparation and Characterization. Chem. Soc. Rev. 2022, 51, 5930-5973. 6.W. Yang, L. Zhang, D. Xiao, R. Feng, W. Wang, Y. Zhao, L. Zhao,* G. Frenking,* X. Wang,* A Diradical Based on Odd-Electron σ-Bonds. Nat. Commun. 2020, 11:1-8. DOI: 10.1038/s41467-020-17303-4. Highlighted in Nat. Rev. Chem. (Bonding Electrons Happy with Single Life. Nat. Rev. Chem. 2020, 4, 438). 7.D. Tuo, C. Chen, H. Ruan, Q. Wang, Y. Ao, X. Wang,* D. Wang,* Magnetic Multistability in an Anion Radical Pimer. Angew. Chem. Int. Ed. 2020, 59, 14040-14043. 8.S. Tang, L. Zhang, H. Ruan, Y. Zhao, X. Wang,* A Magnetically Robust Triplet Ground State Sulfur- Hydrocarbon Diradical Dication. J. Am. Chem. Soc. 2020, 142, 7340-7344. 9.C. Chen, H. Ruan, Z. Feng, Y. Fang, Y. Zhao, Y. Su,* X. Wang,* Crystalline Diradical Dianions of Azaacenes. Angew. Chem. Int. Ed. 2020, 59, 11794-11799. 10.Z. Feng, Y. Fang, H. Ruan, Y. Zhao, G. Tan,* X. Wang,* Stable Radical Cation and Dication of an N-Heterocyclic Carbene Stabilized Digallene: Synthesis, Characterization and Reactivity，Angew. Chem. Int. Ed. 2020, 59, 6769-6774. 11.S. Tang, H. Ruan, R. Feng, Y. Zhao, G. Tan, L. Zhang,* X. Wang*, Tunable Reduction of 2,4,6-Tri(4-pyridyl)-1,3,5-Triazine: from Radical Anion to Diradical Dianion to Radical-Contained Metal-Organic Framework,Angew. Chem. Int. Ed. 2019, 58, 18224-18229. 12.M. Mondal, L. Zhang, Z. Feng, S. Tang, R. Feng, Y. Zhao, G. Tan,* H. Ruan,* X. Wang*, Tricoordinate Nontrigonal Pnictogen-Centered Radical Anions: Isolation, Characterization and Reactivity，Angew. Chem. Int. Ed. 2019, 58, 15829-15833. 13.R. Feng, L. Zhang, H. Ruan, Y. Zhao, G. Tan* and X. Wang*, A Main-Group Element Radical Based One-Dimensional Magnetic Chain, Angew. Chem. Int. Ed. 2019, 58, 6084-6088. 14.W. Wang, C. Chen, C. Shu, S. Rajca, X. Wang,* A. Rajca,* S = 1 Tetraazacyclophane Diradical Dication with Robust Stability: A Case of Low-Temperature One-Dimensional Antiferromagnetic Chain, J. Am. Chem. Soc. 2018, 140, 7820-7826. 15.W. Wang, C. Xu, Y. Fang, Y. Zhao, J. Li,* X. Wang,* An Isolable Diphosphene Radical Cation Stabilized by Three-Center Three-Electron π-Bonding with Chromium: End-On versus Side-On Coordination, Angew .Chem. Int. Ed. 2018, 57, 9563–9568. 16.T. Li, H. Wei, Y. Fang, L. Wang, S. Chen, Z. Zhang, Y. Zhao, G. Tan,* X. Wang,* Elusive Antimony-Centered Radical Cations: Isolation, Characterization, Crystal Structures, and Reactivity Studies, Angew. Chem. Int. Ed.2017, 56, 632. 17.L. Wang, L. Zhang, Y. Fang, J. Li, C. Chen, Y. Zhao, Y. Song, L. Deng, G. Tan,* X. Wang,* P. P. Power,* Isolable Borane-Based Diradical and Triradical Fused by a Diamagnetic Transition Metal Ion, J. Am. Chem. Soc. 2017, 139, 17723. 18.G. Tan, X. Wang,* Isolable Bis(triarylamine) Dications: Analogues of Thiele’s, Chichibabin’s, and Müller’s Hydrocarbons, Acc. Chem. Res. 2017, 50, 1997. 19. W. Wang, J. Li, L. Yin, Y. Zhao, Z. Ouyang, X. Wang,* Z. Wang,* Y. Song,* P. P. Power,* Half-Sandwich Metal Carbonyl Complexes as Precursors to Functional Materials: From a Near-Infrared Absorbing Dye to a Single-Molecule Magnet, J. Am. Chem. Soc. 2017, 139, 12069. 20.G. Tan, J. Li, Li Zhang, C. Chen, Y. Zhao, X. Wang,* Y. Song,* Y. Zhang,* M. Driess,* The Charge Transfer Approach to Heavier Main-Group Element Radicals in Transition Metal Complexes, Angew. Chem. Int. Ed. 2017, 56, 12741. 21.T. Li, G. Tan, D. Shao, J. Li, Z. Zhang, Y. Song, Y. Sui, S. Chen, Y. Fang, X. Wang,* Magnetic Bistability in a Discrete Organic Radical, J. Am. Chem. Soc. 2016, 138, 10092-10095. 22.G. Tan, S. Li, S. Chen, Y. Sui, Y. Zhao, X. Wang,* Isolable Diphosphorus-Centered Radical Anion and Diradical Dianion. J. Am. Chem. Soc. 2016, 138, 6735-6738. 23.X. Zheng, X. Wang, Z. Zhang, Y. Sui, X. Wang,* P. P. Power,* Access to Stable Metalloradicals with Unsupported and Isomeric Metal-Metal Hemi-Bonds, Angew. Chem. Int. Ed. 2015, 54, 9084–9087 (VIP Paper). 24. Y. Su, X. Wang, Y. Li, Y. Song, Y. Sui, X. Wang,* Nitrogen Analogues of Thiele’s Hydrocarbon：Closed-Shell vs Open-Shell in the Ground State, Angew. Chem. Int. Ed. 2015, 54, 1634–1637. 25.S. Zhang, X. Wang, Y. Sui,* X. Wang,* Odd-Electron Bonded Sulfur Radical Cations: X-ray Structural Evidence of a Sulfur-Sulfur Three-Electron σ–Bond, J. Am. Chem. Soc. 2014, 136, 14666–14669. Highlighted by C&E News (“When Three Electrons Are Not a Crowd”, Oct. 27, 2014) 26.X. Pan, X. Wang, Y. Zhao, Y. Sui, and X. Wang,* A Crystalline Phosphaalkene Radical Anion, J. Am. Chem. Soc. 2014, 136, 9834–9837. 27.S. Zhang, X. Wang, Y. Su, Y. Qiu, Z. Zhang, and X. Wang,* Isolation and Reversible Dimerization of a Selenium–Selenium Three–Electron σ–Bond, Nat. Commun. 2014, 5, 4127. 28.Y. Su, X. Zheng, X. Wang, X. Zhang, Y. Sui, and X. Wang,* Two Stable Phosphorus-Containing Four-Membered Ring Radical Cations with Inverse Spin Density Distributions, J. Am. Chem. Soc. 2014, 136, 6251–6254. 29.Y. Su, X. Wang, X. Zheng, Z. Zhang, Y. Song, Y. Sui, Y. Li, and X. Wang,* Tuning Ground States of Bis(triphenylamine)benzidine Dications by Substituent Effect: From a Closed-Shell Singlet to a Diradicaloid with an Excited Triplet State, Angew. Chem. Int. Ed. 2014, 53, 2857–2861. 30.X. Zheng, X. Wang, Y. Qiu, Y. Li, C. Zhou, Y. Sui, Y. Li, J. Ma, and X. Wang*, One-Electron Oxidation of an Organic Molecule by B(C6F5)3; Isolation and Structures of Stable Non-para-substituted Triarylamine Cation Radical and Bis(triarylamine) Dication Diradicaloid, J. Am. Chem. Soc. 2013, 135, 14912–14915. 31.X. Pan, Y. Su, X. Chen, Y. Zhao, Y. Li, J. Zuo, and X. Wang,* Stable Tetraaryldiphosphine Radical Cation and Dication, J. Am. Chem. Soc. 2013, 135, 5561–5564. 32.X. Pan, X. Chen, T. Li, Y. Li, and X. Wang,* Isolation and X-ray Crystal Structures of Triarylphosphine Radical Cations, J. Am. Chem. Soc. 2013, 135, 3414–3417. 33.X. Chen, X. Wang, Z. Zhou, Y. Li, Y. Sui, J. Ma, X. Wang,* P. P. Power,* Reversible σ-Dimerizations of Persistent Organic Radical Cations, Angew. Chem. Int. Ed. 2013, 52, 589–592. 34.X. Chen, X. Wang, Y. Sui,Y. Li, J. Ma,* J. Zuo and X. Wang,* Synthesis,Characterization and Structures of a Persistent Aniline Radical Cation, Angew. Chem. Int. Ed. 2012, 51,11878–11881. 35.X. Wang,* P. P. Power,* Structural Characterization, Infrared Spectroscopy and Theoretical Calculations for B(C6F5)3 Stabilized Benzene-Ammonia and Benzene-Water Complexes, Angew. Chem. Int. Ed. 2011, 50, 10965–10968. 独立工作前： 36.X. Wang, Y. Peng, M. M. Olmstaead, H. Hope, P. P. Power*, A ditetrylyne as a π-Electron Donor: Synthesis and Characterization of [AgAr'GeGeAr']+SbF6？ and [Ag2Ar'GeGe(F)Ar']+SbF6- (Ar'=C6H3-2,6(C6H3-2,6-Pri2)2), J. Am. Chem. Soc. 2010, 132, 13150 - 13151. 37.X. Wang, Y. Peng, Z. Zhu, J. C. Fettinger, P. P. Power*, J. Guo, S. Nagase. Synthesis and characterization of two of the three isomer models of a germanium substituted bicyclo[2.2.0]hexane diradicaloid: stretching the Ge-Ge bond, Angew. Chem. Int. Ed. 2010, 49, 4593 - 4597. 38.X. Wang, Y. Peng, J. C. Fettinger, M. Olmstead, P. P. Power*, An unsymmetric oxo/imido bridged germanium-centered singlet diradicaloid, J. Am. Chem. Soc. 2009, 131, 14164 – 14165. 39.X. Wang, Z. Zhu, Y. Peng, H. Lei, J. C. Fettinger, P. P. Power*. Room-temperature reaction of carbon monoxide with a stable diarylgermylene, J. Am. Chem. Soc., 2009, 131, 6912 - 6913. 40.T. S. Cameron (X-ray), J. Passmore* (Supervisor), X. Wang. The Preparation and X-ray Crystal Structure of [(AgI2)n]MF6 (M=Sb, As): Diiodine Acting as a Donor in the Planar Polymeric [(AgI2)n]n+, Angew Chem. Int. Ed. 2004, 43, 1995 – 1998. (作者按姓氏第一个英文字母顺序排列). Selected as a textbook example：Housecroft & Sharpe，Inorg. Chem. 3rd ed，Pearson，2006，p542. 41.A. Decken (X-ray), J. Passmore* (Supervisor), X. Wang. Cyclic dimethylsiloxanes as pseudo crown ethers: Syntheses and characterization of Li(Me2SiO)5[Al{OC(CF3)3}4], Li(Me2SiO)6[Al{OC(CF3)3}4], and Li(Me2SiO)6[Al{OC(CF3)3Ph}4], Angew. Chem. Int. Ed. 2006, 45, 2773 - 2777. (作者按姓氏第一个英文字母顺序排列). Highlighted in C&E News (April 10, 2006, P54) and Angew Chem. Int. Ed. ( 2007, 46, 4610 - 4613).