5,6-Fused bicyclic tetrazolo-pyridazine energetic materials

Sitong Chen; Yuji Liu; Yongan Feng; Xianjin Yang; Qinghua Zhang

doi:10.1039/C9CC08782F

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5,6-Fused bicyclic tetrazolo-pyridazine energetic materials†

Sitong Chen,

^a Yuji Liu,^a Yongan Feng,^a Xianjin Yang^b and Qinghua Zhang

*^a

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* Corresponding authors

^a Institute of Chemical Materials, China Academy of Engineering Physics (CAEP), Mianyang, P. R. China
E-mail: qinghuazhang@caep.cn

^b School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, P. R. China

Abstract

This study presents the synthesis of 5,6-fused bicyclic conjugated energetic compounds through a combined strategy of anchoring the catenated nitrogen-atom chain and introducing vicinal C-amino and C-nitro groups into a tetrazolo-pyridazine ring. Their crystal structures were confirmed by single crystal X-ray diffraction. Both compounds display good thermal stability, high energetic properties and low sensitivities as energetic materials.

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DOI: https://doi.org/10.1039/C9CC08782F
Article type: Communication
Submitted: 11 Nov 2019
Accepted: 31 Dec 2019
First published: 02 Jan 2020

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Chem. Commun., 2020,56, 1493-1496

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5,6-Fused bicyclic tetrazolo-pyridazine energetic materials

S. Chen, Y. Liu, Y. Feng, X. Yang and Q. Zhang, Chem. Commun., 2020, 56, 1493 DOI: 10.1039/C9CC08782F

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Chemical Communications

5,6-Fused bicyclic tetrazolo-pyridazine energetic materials†

Abstract

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5,6-Fused bicyclic tetrazolo-pyridazine energetic materials

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