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Syntheses, Crystal Structures and Properties of Zinc(II), Cadmium(II) and Cobalt(II) Coordination Complexes Based on 2,4-Dichlorophenoxyacetic Acid and Different Imidazole-Containing Ligands

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Abstract

A series of Zn(II), Cd(II), and Co(II) mixed-ligand coordination complexes, namely, [Cd2(2,4-D)4(PBIX)2] (1), [Cd(2,4-D)2(OBIX)]n (2), [Zn(2,4-D)2(OBIX)]n (3), [Co(2,4-D)2(BIM)(H2O)2]n (4), and [Cd(2,4-D)(NBI)]n (5) (2,4-DH = 2,4-dichlorophenoxyacetic acid, PBIX = 1,4-bis(imidazole-1-ylmethyl)benzene, OBIX = 1,2-bis(imidazole-1-ylmethyl)benzene, BIM = 1,1′-(1,4-butanediyl)bis(benzimidazole), and NBIH = 6-nitrobenzimidazole) have been prepared and fully characterized by elemental analysis, IR spectra, and single crystal X-ray diffraction. X-ray analysis reveals that the bimetallic Cd(II) subunits in complex 1 are bridged by PBIX to form a 0D structure with 26-membered metallomacrocycle. In complexes 2, 3 and 4, the metal centers are linked by OBIX or BIM molecules to generate 1D chains. In complex 5, the Cd(II) ions are bridged by NBI ligands to form a 2D network, which is further extended to a 3D framework through π–π stacking interaction. The structural diversification of complexes 1–5 illustrates the great influence of the metal centers and imidazole-containing ligands on the self-assembly of coordination architectures. In addition, solid fluorescence properties and thermal stability for these crystalline materials are also studied.

Graphic Abstract

A series of Cd(II)/Zn(II)/Co(II) coordination compounds based on 2,4-dichlorophenoxyacetic acid and different imidazole-containing ligands have been synthesized under hydrothermal conditions and structurally characterized. Photoluminescent properties have been discussed.

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Acknowledgements

This work was financially supported by Scientific Research Foundation of Anhui Provincial Education Department (KJ2019A0597) and Teaching Quality and Teaching Reform Project of Huaibei Normal University (JY18022).

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  1. School of Chemistry and Material Science, Huaibei Normal University, Huaibei, 235000, People’s Republic of China

    Yong-Hong Zhou, Yun Xu, Qian-Lan Tao, Tian Tian, Xian-Hui Wei, Qiao Chu & Biao Shi

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Zhou, YH., Xu, Y., Tao, QL. et al. Syntheses, Crystal Structures and Properties of Zinc(II), Cadmium(II) and Cobalt(II) Coordination Complexes Based on 2,4-Dichlorophenoxyacetic Acid and Different Imidazole-Containing Ligands. J Inorg Organomet Polym 30, 2376–2385 (2020). https://doi.org/10.1007/s10904-019-01426-3

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