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Electronic Polarizability, Optical Basicity, Thermal, Mechanical and Optical Investigations of (65B2O3–30Li2O–5Al2O3) Glasses Doped with Titanate

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Abstract

Titanium-doped and titanium-free lithium borate glasses were prepared using a quenching method and high-purity-grade chemical substances. Structural analysis was carried out by Fourier transform infrared (FT-IR) spectroscopy and mechanical measurement. The states of the produced glasses were examined by x-ray diffraction, and the density (ρ) and molar volume (Vm) were determined. The Makishima–Mackenzie model was applied for the prepared glasses. FT-IR confirmed that the concentration of [BO4] was greater than that of [BO3] structural units. These variations confirmed that the compactness of the lithium borate network increased as the concentration of (TiO2/B2O3) increased. The longitudinal (vL) and shear (vT) velocities of the samples with varying concentrations of (TiO2/B2O3) were found to increase, along with the elastic moduli. The thermal stability, energy gap, and refractive index of the prepared glasses increased as the concentration of (TiO2/B2O3) was increased.

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Acknowledgments

The authors are grateful to Al-Azhar University for support with the experimental measurements. In addition, the authors thank the Deanship of Scientific Research at King Khalid University (KKU) for funding this research project (No. R.G.P2./22/40) under the Research Center for Advanced Materials Science.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Al-Azhar University, P.O. 71524, Assiut, Egypt

    Kh. S. Shaaban

  2. Physics Department, Faculty of Science, Al-Azhar University, P.O. 71452, Assiut, Egypt

    E. A. Abdel Wahab, E. R. Shaaban & El Sayed Yousef

  3. Physics Department, Faculty of Science, King Khalid University, P.O. Box 9004, Abha, Saudi Arabia

    El Sayed Yousef

  4. Research Center for Advanced Materials Science (RCAMS), King Khalid University, P.O. Box 9004, Abha, 61413, Saudi Arabia

    El Sayed Yousef

  5. Physics Department, Faculty of Science, Northern Border University, Arar, 91431, Saudi Arabia

    Safwat A. Mahmoud

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  1. Kh. S. Shaaban
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  2. E. A. Abdel Wahab
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  3. E. R. Shaaban
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Correspondence to Kh. S. Shaaban.

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Shaaban, K.S., Wahab, E.A.A., Shaaban, E.R. et al. Electronic Polarizability, Optical Basicity, Thermal, Mechanical and Optical Investigations of (65B2O3–30Li2O–5Al2O3) Glasses Doped with Titanate. J. Electron. Mater. 49, 2040–2049 (2020). https://doi.org/10.1007/s11664-019-07889-x

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