Abstract
In the crystal structure of 2-methylanilinium hydrogen DL-malate hydrate (I), an additional water molecule is present in asymmetric unit. In the crystal structures of 4-methoxyanilinium hydrogen DL-malate (II) and 4-methylanilinium hydrogen DL-malate (III), the hydrogen malate anions exhibit configurational disorder with major component occupy S-configuration and minor component occupy R-configuration provided both (II) and (III) are prepared from a racemic mixture of DL-malic acid. In crystal structures of compounds (I)–(III), the hydrogen malate anions and anilinium cations from O-H…O and N-H…O hydrogen bonds which exhibit interesting supramolecular frameworks. In compound (I), the N-H…O and O-H…O hydrogen-bonded anionic-cationic framework form two-dimensional hydrophilic and hydrophobic layers in which the lattice water molecules are embedded in hydrophilic layers. However, in crystal structures of (II) and (III), the hydrogen DL-malate anions form two-dimensional anionic substructure through O-H…O hydrogen bond, in which the anilinium cations are anchored through N-H…O hydrogen bonds.
Similar content being viewed by others
References
André V, Martins I, Quaresma S, Martins M, Duarte MT (2014). Struct Chem 25:707–714
Arunkumar A, Ramasamy P (2014). J Cryst Growth 388:124–131
Singh UP, Tomar K, Kashyap S (2016). Struct Chem 27:1027–1040
Maniukiewicz W, Bojarska J, Sieroń L (2018). Struct Chem 29:1525–1531
Aakeröy CB, Salmon DJ (2005). Cryst Eng Comm 7:439–448
Jin S, Wang D, Xu Y (2012). J Coord Chem 65:1953–1969
Dutkiewicz G, Dutkiewicz E, Kubicki M (2018). Struct Chem 29:1525–1531
Singh UP, Maurya RR, Kashyap S (2015). J Mol Struct 1081:128–135
Jagan R, Sathya D, Sivakumar K (2015). Acta Crystallogr C71:374–380
Kavitha SJ, Panchanatheswaran K, Low JN (2006). Acta Crystallogr C62:o165–o169
Farrell DMM, Ferguson G, Lough AJ, Glidewell C (2002). Acta Crystallogr B58:272–288
Perpétuo GJ, Janczak J (2003). Acta Crystallogr C59:o709–o711
Farrell DMM, Ferguson G, Lough AJ, Glidewell C (2002). Acta Crystallogr B58:530–544
Aakeroy CB, Nieuwenhuyzen M (1996). Chem Mater 8:1229–1235
Padmavathy R, Karthikeyan N, Sathya D, Jagan R, Sivakumar K (2016). RSC Adv 6:68468–68484
Bruker, APEX2, SAINT-Plus and SADABS (2012). Bruker AXS Inc., Madison, Wisconsin, USA
Spek AL (2003). J Appl Crystallogr 36:7–13
Sheldrick GM (2015). Acta Crystallogr C71:3–8
Farrugia LJ (1997). J Appl Crystallogr 30:565
Macrae CF, Bruno IJ, Chisholm JA, Edgington PR, McCabe P, Pidcock E, Rodriguez-Monge L, Taylor R, van de Streek J, Wood PA (2008). J Appl Crystallogr 41:466–470
Turkington DE, Ferguson G, Lough AJ, Glidewell C (2004). Acta Crystallogr C60:o617–o622
Bowes KF, Ferguson G, Lough AJ, Glidewell C (2003). Acta Crystallogr C59:o329–o331
Peeters OM, Blaton NM, De Ranter CJ (1995). Acta Crystallogr C51:1435–1438
van der Sluis P, Kroon J (1985). Acta Crystallogr C41:956–959
Amor FB, Soumhi EH, Abdellahi MO, Jouini T (1995). Acta Crystallogr C51:933–935
Abdul Rahman MB, Jumbri K, Sirat K, Kia R, Fun HK (2009). Acta Crystallogr E65:o49
Janczak J, Perpétuo GJ (2003). Acta Crystallogr C59:o349–o352
Anandha babu G, Bhagavannarayana G, Ramasamy P (2008). J cryst growth 310:1228–1238
Kalaiyarasi S, Devi SR, Akilan R, Kumar RM, Chakkaravarthi G (2016). IUCr Data 1(9):x161525
Wang KW, Jin ZM, Pan YJ (2005). J Chem Cryst 35:413–417
Aakeroey CB, Nieuwenhuyzen M (1994). J Am Chem Soc 116:10983–10991
Acknowledgments
The authors thank the Sophisticated Analytical Instruments Facility, Indian Institute of Technology Madras, for the single-crystal data collection.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Rajamoni, J., Kandasamy, S. Structural features and N-H…O and O-H…O hydrogen-bonded supramolecular frameworks in 2-methylanilinium hydrogen DL-malate hydrate, 4-methoxyanilinium and 4-methylanilinium hydrogen DL-malate salts. Struct Chem 31, 917–925 (2020). https://doi.org/10.1007/s11224-019-01441-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11224-019-01441-7