Issue 9, 2020
From the journal:

Chemical Communications

Synthesis of 2-alkenylfurans via a Ag(i)-catalyzed tandem cyclization/cross-coupling reaction of enynones with iodonium ylides†

Haiyun Peng,ab   Yinbo Wan,ab   Yu Zhangab  and  Guisheng Deng ORCID logo *ab  

* Corresponding authors

a Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China), Hunan Normal University, Changsha 410081, China
E-mail: gsdeng@hunnu.edu.cn

b Key Laboratory of the Assembly and Application of Organic Functional Molecules of Hunan Province, Hunan Normal University, Changsha 410081, China

Abstract

A silver(I)-catalyzed tandem cyclization/cross-coupling reaction of enynones with iodonium ylides to construct carbon–carbon double bonds has been developed. The strategy provides a novel method for the synthesis of 2-alkenylfurans. This is the first cross-coupling reaction between metal–carbene complexes and iodonium ylides.

Graphical abstract: Synthesis of 2-alkenylfurans via a Ag(i)-catalyzed tandem cyclization/cross-coupling reaction of enynones with iodonium ylides

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Article information

DOI
https://doi.org/10.1039/C9CC08561K
Article type
Communication
Submitted
02 Nov 2019
Accepted
19 Dec 2019
First published
20 Dec 2019

Chem. Commun., 2020,56, 1417-1420

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Synthesis of 2-alkenylfurans via a Ag(I)-catalyzed tandem cyclization/cross-coupling reaction of enynones with iodonium ylides

H. Peng, Y. Wan, Y. Zhang and G. Deng, Chem. Commun., 2020, 56, 1417 DOI: 10.1039/C9CC08561K

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