Issue 2, 2020

Sustainable innovations in steam cracking: CO2 neutral olefin production

Abstract

Steam cracking of hydrocarbons is and will continue to be the main industrial process to produce light olefins in the coming decades. In state of the art steam cracking plants more than 90% of the CO2 emissions can be directly related to the high energy consumption of the endothermic conversion in the cracking furnaces. Steam cracking accounts for a global emission of more than to 300 million tonnes of CO2per annum. Enhancing heat transfer in the radiation section, using green energy and reducing coke formation are key to substantially reduce CO2 emissions. Heat transfer can be increased by implementing three-dimensional (3D) coil technologies such as swirled and dimpled tubes. These reactor technologies also reduces coke formation because of the lower wall temperatures that are consequently obtained. Advanced manufacturing techniques and better computational abilities have opened the door to novel and improved 3D reactor technologies that are designed to increase the heat transfer while minimizing the pressure drop penalty. At the same time applying high emissivity coatings on the furnace refractory and reactor tubes can further reduce CO2 emissions. Substantial fuel savings can also be obtained by a novel furnace design, where the heat recovery scheme is substantially modified. Combining all these technologies could result in reducing emissions by 30%. Shifting completely to green electricity, which is practically infeasible today, is another alternative but the technologies that would potentially allow this are still in their infancy. These new technologies, combined with advanced process innovations and CO2 capture, will help the industry to meet future emissions targets.

Graphical abstract: Sustainable innovations in steam cracking: CO2 neutral olefin production

Article information

Article type
Review Article
Submitted
15 Oct 2019
Accepted
18 Dec 2019
First published
19 Dec 2019

React. Chem. Eng., 2020,5, 239-257

Sustainable innovations in steam cracking: CO2 neutral olefin production

I. Amghizar, J. N. Dedeyne, D. J. Brown, G. B. Marin and K. M. Van Geem, React. Chem. Eng., 2020, 5, 239 DOI: 10.1039/C9RE00398C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements