Design strategy for optimising weight and ballistic performance of soft body armour reinforced with shear thickening fluid

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Abstract

This study presents some soft armour panel design strategies using shear thickening fluid (STF) reinforced Kevlar® fabric. The effect of size of silica nano and sub-micron particles on the ballistic performance of soft body armour panels against the small arms ammunition (velocity ~ 430 ± 15 m/s) has been analysed. Two STFs, namely STF-500 and STF-100, were prepared by dispersing silica particles of 500 nm and 100 nm diameter, respectively, in polyethylene glycol (PEG) 200. Kevlar® fabrics were impregnated with both the STFs. Multiple layers (20–24) of fabrics were stitched to prepare 13 soft armour panels which were evaluated for back face signature (BFS) against 9 × 19 mm lead core bullet. Soft armour panels comprising of fabrics impregnated with STF-500 yielded lower BFS than the respective panels comprising of fabrics impregnated with STF-100. This study also revealed that STF impregnation of Kevlar® fabrics can reduce the BFS by 2.5 mm–2.8 mm while keeping the areal density of the panel same (5 kg/m2). The areal density of soft armour panel can be reduced further by 10% (4.5 kg/m2), while keeping the BFS comparable to or lower than that of an STF impregnated homogenous panel, by judiciously placing the STF impregnated fabrics at the rear side while neat fabrics are placed at the strike face of the panel. STF impregnated panels were found to stop the impacting bullet earlier than neat panel.

Introduction

Body armours are of two types, namely hard and soft. Either combination of hard and soft body armours or standalone version of the former can give protection against the threats from rifle ammunitions (e.g. SLR, AK, etc.). Hard body armours are composite or hybrid structures comprising of metals, ceramics (boron carbide, silicon carbide) and/or textile reinforced composites. On the other hand, soft body armours are made of various high-performance fibres like p-aramid (Kevlar®, Twaron®, etc.) and ultra-high molecular weight polyethylene (Spectra®, Dyneema®, etc.) used in the form of woven fabrics, multiaxial fabrics, uni/multi-directional laminates, etc. In the past two decades, scientists and researchers have explored shear thickening fluid (STF) which has the capability to reduce behind armour blunt trauma (BABT) or back face signature (BFS) and stop a bullet from penetrating the soft armour [[1], [2], [3], [4], [5], [6], [7]]. STF is a concentrated colloidal suspension whose viscosity increases drastically when the applied shear rate exceeds the critical value. This non-Newtonian behaviour of STF makes it ideal for energy absorption applications. Shear thickening behaviour is exhibited by various concentrated suspensions such as corn-starch–water suspension, iron particles in carbon tetrachloride and silica nanoparticles in polyethylene glycol, etc. [[8], [9], [10], [11], [12]] In normal conditions, the solid particles remain suspended in the medium and hence the fabric maintains its flexibility. Upon bullet impact, the particles form hydroclusters which helps in energy absorption by providing better structural integrity and by ensuring increased participation of secondary yarns of fabric [[13], [14], [15]]. One of the most important particle parameters which influences the rheological behaviour of STF is size of particle in dispersed phase. In general, it has been observed that higher the particle size, lower the critical shear rate and higher the peak viscosity [[16], [17], [18]]. Therefore, choice of particle size remains crucial for the design of STF reinforced soft armour panel.

Numerous research works have been reported on the polyethylene glycol or PEG (dispersion medium) and silica nanoparticle (dispersed phase) based STF impregnated Kevlar® fabrics. STF impregnated Kevlar® fabrics show improvement in impact resistance. There exist two different schools of thought about the role of STF in enhancing the impact resistance of fabrics. One group of researchers believe that the improvement is due to increase in inter-yarn friction [6,19,20]. In contrast, the other group of researchers attribute the enhanced performance to shear thickening mechanism [10,16]. However, STF impregnated fabrics have mostly been explored at lower impact velocity range in which an impactor in dropped or a projectile is fired at a velocity lower than Mach 1 [4,5,7,12,[21], [22], [23], [24], [25]]. Xu et al. [26] investigated the effect of silica particle size and loading on the stab resistance of body armour. They found that as the particle size and STF loading increase, energy absorption also increases. Majumdar and Laha [13] showed that the shear thickening effect is critical for achieving enhanced performance via an increase in the yarn pull-out force upon transition of STF to its solid-state. Seshagiri et al. [27] found that when Kevlar® was used with Oobleck and silica-PEG STF, the deformation produced on a glass plate reduced considerably as compared to that of neat Kevlar® sample. Khodadadi et al. [15,24] reported numerical and experimental results of STF impregnated panels for a range of impact velocity from 40 m/s to 60 m/s. They found improvement in performance over neat panels and ascribed it to frictional interaction between yarns and silica in impregnated fabrics. Park et al. [3,5,6] found that the impregnation of aramid fabric with STF increased the frictional force of a single yarn in the fabric, which consequently increased the modulus of the yarn. The layering sequence was found to be very important in improving the protective performance of STF impregnated hybrid multilayer panels, which influenced not only the BFS value but also the perforation ratio and bullet expansion. Some recent research papers have reported that the effectiveness of STF, in improving the impact resistance, depends upon the fabric structure [28,29]. Arora et al. [29] found that the beneficial role of STF ceases to exist if the fabric is very tightly woven. The impregnation of STF increased the effective mass of the fabric by 10% to 46% [10,12,22,23]. Therefore, to keep the mass of the soft armour panel within the prescribed limit, either the number of fabric layers should be reduced after STF treatment so that the overall areal density of panel remains the same or few layers of soft armour panels should be impregnated with the STF. If the latter is followed, then the STF impregnated fabric layers should be judiciously placed so that they perform effectively.

This research work presents the effect of silica particle size on the ballistic performance of STF impregnated soft armour panels under two scenarios, namely keeping the number of fabric layers same and keeping the areal density of the panel same. The comparison of ballistic performance of soft armour panels when the STF impregnated fabric layers are placed at the strike face and at the rear side has also been made.

Section snippets

Materials

Kevlar® 363 2S (scoured) square plain woven fabric, having 28 ends (warp) per inch and 28 picks (weft) per inch and areal density of 200 g/m2 was sourced from DuPont, USA. It was made of multifilament Kevlar 129 yarn having linear density of 840 denier, tensile strength of 3.4 GPa, tensile modulus of 78 GPa and breaking strain of 3.3%. Polyethylene glycol of molecular weight 200 (PEG 200) and ethanol were sourced from Merck Life Science Pvt. Ltd. (India) and Changshu Hongsheng Fine Chemical Co.

Rheological analysis of STF

Steady state rheological properties of prepared STFs were evaluated using Anton Paar Physica MCR 51 stress-controlled rheometer. The tests were performed using a parallel plate geometry having two plates separated by a gap of 0.3 mm. Diameter of upper and lower plates was 25 mm and 50 mm, respectively. Rheological tests were conducted at three different temperatures, i.e. 15 °C, 25 °C and 35 °C, and shear rate was varied from 1 s−1 to 1000 s−1.

Scanning electron microscopy (SEM)

Surface morphology of neat and STF impregnated

Rheological behaviour of STFs

Flow curves of STF-100 and STF-500, at three different temperatures, are shown in Fig. 7(a) and 7(b), respectively. The flow curves confirmed the non-Newtonian behaviour of both the STFs at all three temperatures. Further, it can be seen from the Fig. 7 and Table 3 that with the increase in temperature, the critical shear rate and shear rate at maximum viscosity increase and peak viscosity decreases for both the STFs. This change in critical shear rate and viscosity is due to increased Brownian

Conclusions

Effective strategies have been developed for designing of soft body armour by using STF impregnated Kevlar fabrics. Fabrics impregnated with STF prepared by using 500 nm silica (STF-500) show higher impact energy absorption as compared to fabrics impregnated with STF prepared by using 100 nm silica (STF-100). The soft armour panels made from the former also yield lower BFS than the panel made from the latter when the number of fabric layers is equal. Use of hybrid panels comprising of neat and

CRediT authorship contribution statement

Mukesh Bajya: Conceptualization, Methodology, Writing - original draft. Abhijit Majumdar: Visualization, Supervision, Writing - review & editing. Bhupendra Singh Butola: Visualization, Supervision, Writing - review & editing. Sanjeev Kumar Verma: Formal analysis. Debarati Bhattacharjee: Formal analysis.

Declaration of competing interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgement

The authors are grateful to Terminal Ballistic Research Laboratory (TBRL), Chandigarh, India, for the financial and technical assistance in this research work (Grant no: TBRL/CARS/61/2014). The support of Science and Engineering Research Board (SERB), Reliance Industries and FICCI are also greatly acknowledged.

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