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Minireview of pentatomic cations in sodalite cavities

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Abstract

Centered-tetrahedral cationic clusters are frequently found in the sodalite cavities of zeolites and in the cavities of analogues of the mineral sodalite. Examples are Mn4S6+, Fe4Te6+, Zn4Se6+, Cd4S6+, Cu4Cl7+, Na4Cl3+, Na4I3+, Na54+, In57+, Ga57+, and Sn512+.

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Notes

  1. R1 = Σ|Fo-|Fc||/ΣFo; wR2 = [Σw(Fo2-Fc2)2/Σw(Fo2)2]1/2.

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Acknowledgements

This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2017R1D1A1B03029558).

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  1. Department of Applied Chemistry, Andong National University, Andong, 36729, South Korea

    Dae Jun Moon & Woo Taik Lim

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  1. Dae Jun Moon
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Correspondence to Woo Taik Lim.

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Moon, D.J., Lim, W.T. Minireview of pentatomic cations in sodalite cavities. J Porous Mater 27, 563–564 (2020). https://doi.org/10.1007/s10934-019-00818-7

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