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Methane oxidation catalysts based on the perovskite-like complex oxides of cobalt and nickel

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Abstract

The results of the last 20 year research on the development of rare earth cobaltate- and nickelate-based catalysts of the partial oxidation of methane (POM) are summarized. New way of synthesis of these catalysts based on the decomposition of complex oxide precursors in the reducing environment is discussed. It was found that the high mobility of oxygen in LaSrCoO4 is accompanied by a significant catalytic activity of this complex oxide in methane oxidation. High catalytic performance of NdCaCoO4 in POM might be caused by the reductive decomposition of this complex oxide at a temperature above 900 °C and the formation of closely packed agglomerates of nanoparticles of metallic cobalt, Nd2O3, and CaO. The studies focused on decreasing POM temperature via substitution of cobalt by nickel in complex oxide precursors as well as the works considering decomposition processes in order to obtain metal-oxide nanocomposites with the optimum catalytic performance are discussed. This work shows that the reductive decomposition of Nd2−xCax(Co1−yNiy)O4−d and of the related complex oxides opens up new possibilities for the development of metal-oxide catalysts of the partial oxidation of methane and other catalytic oxidation processes.

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Authors and Affiliations

  1. Chemistry Department, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    G. N. Mazo & O. A. Shlyakhtin

  2. National Research University Higher School of Economics, 20 Myasnitskaya ul., 101000, Moscow, Russian Federation

    G. N. Mazo

  3. Gubkin State University of Oil and Gas (National Research University), 65 Leninsky prosp., 119991, Moscow, Russian Federation

    A. S. Loktev & A. G. Dedov

  4. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    A. S. Loktev & A. G. Dedov

  5. A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Build. 2, 29 Leninsky prosp., 119991, Moscow, Russian Federation

    A. S. Loktev & A. G. Dedov

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  1. G. N. Mazo
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  2. O. A. Shlyakhtin
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  3. A. S. Loktev
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  4. A. G. Dedov
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Correspondence to G. N. Mazo.

Additional information

Based on the materials of the Russian National Conference “Interplay between Ionic and Covalent Interactions in Design of Molecular and Nano Chemical Systems” (ChemSci-2019) (May 13–17, 2019, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 1949–1953, November, 2019.

This work was financially supported by the Ministry of Education and Science of the Russian Federation (governmental assignment “Leading researches on continuing basis”, Project No. 4.6718.2017/6.7) and Presidium of Russian Academy of Sciences (programme No. 33, “Carbon power engineering: chemical aspects”).

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Mazo, G.N., Shlyakhtin, O.A., Loktev, A.S. et al. Methane oxidation catalysts based on the perovskite-like complex oxides of cobalt and nickel. Russ Chem Bull 68, 1949–1953 (2019). https://doi.org/10.1007/s11172-019-2653-6

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  • DOI: https://doi.org/10.1007/s11172-019-2653-6

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