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Multi-dimensional Crystal Structuring of Complex Metal Oxide Catalysts of Group V and VI Elements by Unit-Assembling

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Abstract

Four new porous crystalline complex metal oxide families based on group V and VI elements, all of which are synthesized through unit-assembling, are introduced along with crystal structure formation mechanism. Polyoxometalates (POMs) are utilized as building units and assembled for constructing microporous complex metal oxides. Assembling of MoVO-POMs having pentagonal units of [Mo6O21] with {VO} linkers under hydrothermal conditions forms microporous orthorhombic (NH4)4[Mo30V4O106] {VO}6 oxide and trigonal (NH4)3[Mo19.5V1.5O69] {VO}6 oxide. Assembling of ε-Keggin Mo-POMs with bismuth ions as a linker under a hydrothermal condition produces a cubic (NH4)4[Mo9.4V3.6O40] {Bi}2 crystal with cages and channels with the diameter sizes of 0.77 and 0.34 nm, respectively. One dimensional anionic tungstosellenate molecular wire building block, [SeW6O21]2−n, is first formed by linear connection of hexagonal tungstosellenate POM units [SeW6O27] and then linked with the CoII ion to form a crystalline microporous materials, (NH4)0.4 [SeW6O21] {Co(OH)}1.3. [W4O16] building blocks are orderly connected with {VO} linkers to form a microporous framework (K1.5(NH4)0.2H0.3[W4O16]{VO}3) with a pore diameter of 0.43 nm which is fully opened and is accessible to small molecules. These new porous crystalline complex metal oxides showed high catalytic performance for alkane oxidation, aldehyde oxidation, alcohol oxidation, H2O2 oxidation, NH3-SCR, and so on.

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Authors and Affiliations

  1. Department of Material and Life Chemistry, Kanagawa University, Rokkakubashi, 3-27-1, Kanagawa-ku, Yokohama, 221-8686, Japan

    Satoshi Ishikawa & Wataru Ueda

  2. Laboratory for Materials and Structures, Institute of Innovative Research, Tokyo Institute of Technology, Nagatsuta-cho, 4259, Midori-ku, Yokohama, 226-8503, Japan

    Zhenxin Zhang

  3. Research Center for Gold Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo, 192-0397, Japan

    Toru Murayama

  4. Research Institute for Chemical Process Technology, National Institute of Advanced Industrial Science and Technology, 4-2-1 Nigatake, Miyagino, Sendai, 983-8551, Japan

    Norihito Hiyoshi

  5. Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi Hiroshima, 739-8527, Japan

    Masahiro Sadakane

Authors
  1. Satoshi Ishikawa
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  2. Zhenxin Zhang
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  3. Toru Murayama
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  4. Norihito Hiyoshi
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  5. Masahiro Sadakane
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  6. Wataru Ueda
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Correspondence to Wataru Ueda.

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Ishikawa, S., Zhang, Z., Murayama, T. et al. Multi-dimensional Crystal Structuring of Complex Metal Oxide Catalysts of Group V and VI Elements by Unit-Assembling. Top Catal 62, 1157–1168 (2019). https://doi.org/10.1007/s11244-018-1077-0

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  • DOI: https://doi.org/10.1007/s11244-018-1077-0

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