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Silica gel modified with tetraalkylammonium halides as an available and efficient catalyst for the synthesis of cyclic organic carbonates from epoxides and CO2

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Abstract

Silica gel with the additives of tetraalkylammonium halides serves as an efficient catalyst for the solvent-free insertion of carbon dioxide into epoxides (10–56 atm of CO2, 105–100 °C), leading to cyclic carbonates with quantitative conversion.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, M. V. Sokolovskaya, A. V. Arzumanyan, R. S. Tukhvatshin, L. F. Ibragimova, A. A. Tyutyunov, V. A. Davankov & A. M. Muzafarov

  2. Department of Applied Chemistry, Indian Institute of Technology (Indian School of Mines), Dhanbad, 826004, India

    B. Chowdhury

Authors
  1. S. E. Lyubimov
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  2. M. V. Sokolovskaya
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  3. B. Chowdhury
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  4. A. V. Arzumanyan
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  5. R. S. Tukhvatshin
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  6. L. F. Ibragimova
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  7. A. A. Tyutyunov
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  8. V. A. Davankov
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  9. A. M. Muzafarov
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Corresponding author

Correspondence to S. E. Lyubimov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1866–1868, October, 2019.

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Lyubimov, S.E., Sokolovskaya, M.V., Chowdhury, B. et al. Silica gel modified with tetraalkylammonium halides as an available and efficient catalyst for the synthesis of cyclic organic carbonates from epoxides and CO2. Russ Chem Bull 68, 1866–1868 (2019). https://doi.org/10.1007/s11172-019-2637-6

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  • DOI: https://doi.org/10.1007/s11172-019-2637-6

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