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The reagent Et2AlX/CH2N2 in cyclopropanation of sterically hindered olefins, as well as oxygen- and nitrogen-containing unsaturated compounds

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Abstract

A transition-metal-free method of cyclopropanation of sterically hindered olefins, substituted allylic alcohols, allylamines, and vinyl silyl ethers was developed using diazomethane in the presence of organic aluminum halides.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    I. R. Ramazanov, A. V. Yaroslavova, N. R. Yaubasarov, E. N. Gil’manova & U. M. Dzhemilev

Authors
  1. I. R. Ramazanov
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  2. A. V. Yaroslavova
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  3. N. R. Yaubasarov
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  4. E. N. Gil’manova
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  5. U. M. Dzhemilev
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Correspondence to I. R. Ramazanov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1869–1873, October, 2019.

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Ramazanov, I.R., Yaroslavova, A.V., Yaubasarov, N.R. et al. The reagent Et2AlX/CH2N2 in cyclopropanation of sterically hindered olefins, as well as oxygen- and nitrogen-containing unsaturated compounds. Russ Chem Bull 68, 1869–1873 (2019). https://doi.org/10.1007/s11172-019-2638-5

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  • DOI: https://doi.org/10.1007/s11172-019-2638-5

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