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Insight into molecular packing effects on transesterification catalysis of zinc(II) coordination polymers

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Abstract

Self-assembly of ZnX2 (X− = ClO4− and CF3SO3−) with naphthalene-2,6-diyl-diisonicotinate (L) gives rise to the 2D sheet structures with composition of [ZnL2(H2O)2](ClO4)2·H2O and [ZnL2(CF3SO3)2], respectively. [ZnL2(H2O)2](ClO4)2·H2O is packed in an interpenetration mode, whereas [ZnL2(CF3SO3)2] exists as a simple 2D network in the crystalline solid state. These two crystals have been employed as hetero-catalysts for transesterification reactions of phenylacetate with alcohol. The catalytic effect on the transesterification reaction shows the order of [ZnL2(H2O)2](ClO4)2·H2O > Zn(CF3SO3)2 > [ZnL2(OTf)2] > Zn(ClO4)2, which indicate that molecular packing is an important factor in the catalysis.

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Acknowledgements

This work was supported by National Research Foundation of Korea (NRF) grants funded by the Korean Government [MEST] (2016R1A2B3009532 [OSJ], 2016R1A5A1009405 [OSJ] and 2017R1D1A3B03035719) (YAL).

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Authors and Affiliations

  1. Department of Chemistry and Research Institute of Functional Materials Chemistry, Pusan National University, Pusan, 609-735, Korea

    Lingling Yang, Dongwon Kim, Soomin Hyun & Ok-Sang Jung

  2. Department of Chemistry, Chonbuk National University, Jeonju, 54896, Korea

    Young-A Lee

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  1. Lingling Yang
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  2. Dongwon Kim
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  3. Soomin Hyun
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Correspondence to Ok-Sang Jung.

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Yang, L., Kim, D., Hyun, S. et al. Insight into molecular packing effects on transesterification catalysis of zinc(II) coordination polymers. Transit Met Chem 45, 139–145 (2020). https://doi.org/10.1007/s11243-019-00366-8

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  • DOI: https://doi.org/10.1007/s11243-019-00366-8

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