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Pseudohalide-directed assemblies of Cu(II) coordination polymers with diverse structures and dye adsorption behaviors

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Abstract

Assembly of 3,4-bis(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole (L334) and CuBr2 without or with the presence of thiocyanate (SCN−)/dicyanamide [dca, N(CN)−2] anion produces three Cu(II) coordination polymers, {[Cu(L334)(H2O)2](Br)2(CH3OH)}n (1), {[Cu(L334)(SCN)2(H2O)](H2O)(EA)}n (2) (EA = ethyl acetate), and [Cu(L334)(dca)2]n (3). The crystal structures for 1 and 3 show different 2D layered coordination networks, whereas that for 2 represents a distinct 1D coordination pattern. The above results demonstrate that the addition of pseudohalide anions plays an important role in structural construction of coordination architectures. Moreover, 1 exhibits the best adsorption capacity toward methyl orange (MO) dye.

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Acknowledgments

This work is supported by the Program for Innovative Research Team in University of Tianjin (TD13-5074) and Tianjin Natural Science Foundation (17JCYBJC22800).

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Authors and Affiliations

  1. Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic–Organic Hybrid Functional Material Chemistry, College of Chemistry, Tianjin Normal University, Tianjin, 300387, People’s Republic of China

    Cai-Ying Tian, Yan Bi & Jing Chen

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  1. Cai-Ying Tian
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  2. Yan Bi
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  3. Jing Chen
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Correspondence to Jing Chen.

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Tian, CY., Bi, Y. & Chen, J. Pseudohalide-directed assemblies of Cu(II) coordination polymers with diverse structures and dye adsorption behaviors. Transit Met Chem 45, 91–97 (2020). https://doi.org/10.1007/s11243-019-00361-z

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