Abstract
This article considers the thermodynamic aspects, thermo- and rheokinetics of endo-dicyclopentadiene polymerization in the presence of the original metathesis second Hoveyda-Grubbs catalyst with an N-chelating ligand. The activation energy of endo-dicyclopentadiene polymerization was determined as 88.9–89.2 kJ/mol. The thermal effect of the ring-opening metathesis endo-dicyclopentadiene polymerization reaction reaches 52.7 kJ/mol. This is lower than the values for molybdenum- and tungsten-containing catalysts reported in the literature, which can be explained by a different microstructure of the polymer produced in the presence of ruthenium-based metathesis catalysts.
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The authors acknowledge the support from the Russian Foundation for Basic Research (no. 18-29-04047) and Tomsk Polytechnic University Competitiveness Enhancement Program grant (VIU-195/2018).
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Lyapkov, A.A., Soroka, L.S., Ashirov, R.V. et al. Kinetics of Dicyclopentadiene Polymerization in the Presence of the Second Generation Hoveyda-Grubbs Catalyst with N-Chelating Ligand. Polym. Sci. Ser. C 61, 41–48 (2019). https://doi.org/10.1134/S1811238219010107
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DOI: https://doi.org/10.1134/S1811238219010107