Skip to main content
SpringerLink
Log in

Synthesis and corrosion inhibition studies of modified polyacrylic acid bearing triazole moieties on aluminium in alkaline medium

  • ORIGINAL PAPER
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

Novel modified Polyacrylic acid (ACTP) bearing triazole pendant moieties prepared with polyacrylyl chloride and 3-amino-1,2,4-triazole-5-thiol through polycondensation reaction. The synthesized polymer was characterized using nuclear magnetic resonance (lH-NMR, 13C-NMR), fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive studies (EDAX) and thermogravimetric (TGA) studies. The ACTP polymer was tested as corrosion inhibitor with aluminium metal in alkaline medium and their results were compared with synthesized simple polyacrylic acid (PAA). Gravimetric, electrochemical impedance spectroscopy (EIS), potentiodynamic polarization techniques were used to test the efficiency of the corrosion inhibitor. Activation energy and free energy for inhibition reaction supports both chemical and physical adsorption mechanism, with better inhibition efficiency. Potentiodynamic polarization curves validated that the corrosion inhibitors behave an anodic type.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Zaromb S (1962) The use and behavior of aluminum anodes in alkaline primary batteries. J Electrochem Soc 109:1125–1130

    CAS  Google Scholar 

  2. Ashassi-Sorkhabi H, Shabani B, Aligholipour B, Seifzadeh D (2006) The effect of some Schiff bases on the corrosion of aluminium in hydrochloric acid solutions. Appl Surf Sci 252:4039–4047

    CAS  Google Scholar 

  3. Donatus U, Thompson GE, Omotoyinbo JA, Alaneme KK, Aribo S, Agbabiaka OG (2017) Corrosion pathways in aluminium alloys. Trans. Nonferrous Met Soc China 27:55–62

    CAS  Google Scholar 

  4. Fouda AS, Al-Sarawy AA, Ahmed FS, El-Abbasy HM (2009) Corrosion inhibition of aluminum 6063 using some pharmaceutical compounds. Corros Sci 51:485–492

    CAS  Google Scholar 

  5. Wang JM, Wang JB, Shao HB, Zeng XX, Zhang JQ, Cao CN (2011) Corrosion and electrochemical behaviours of pure aluminium in novel KOH-ionic liquid-water solutions. Mater Corros 60:977–981

    Google Scholar 

  6. Abiola OK, Otaigbe JOE (2008) Effect of common water contaminants on the corrosion of aluminium alloys in ethylene glycol–water solution. Corros Sci 50:242–247

    CAS  Google Scholar 

  7. Kuznetsov YI, Thomas JGN (1996) Organic inhibitors of corrosion of metals. Springer, Netherlands

    Google Scholar 

  8. Yildiz R (2015) An electrochemical and theoretical evaluation of 4, 6-diamino-2-pyrimidinethiol as a corrosion inhibitor for mild steel in HCl solutions. Corros Sci 90:544–553

    CAS  Google Scholar 

  9. Obot IB, Ebenso EE, Kabanda MM (2013) Metronidazole as environmentally safe corrosion inhibitor for mild steel in 0.5 M HCl: experimental and theoretical investigation. J Environ Chem Eng 1:431–439

    CAS  Google Scholar 

  10. Finsgar M, Jackson J (2014) Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: a review. Corros Sci 86:17–41

    CAS  Google Scholar 

  11. Aytac A, Ozmen U, Kabasakaloglu M (2005) Investigation of some Schiff bases as acidic corrosion of alloy AA3102. Mater Chem Phys 89:176–181

    CAS  Google Scholar 

  12. Li XH, Deng SD, Fu H, Xie XG (2014) Synergistic inhibition effects of bamboo leaf extract/major components and iodide ion on the corrosion of steel in H3PO4 solution. Corros Sci 78:29–42

    CAS  Google Scholar 

  13. Abdallah M (2004) Antibacterial drugs as corrosion inhibitors for corrosion of aluminium in hydrochloric solution. Corros Sci 46:1981–1996

    CAS  Google Scholar 

  14. El-Maksoud SAA, Fouda AS (2005) Some pyridine derivatives as corrosion inhibitors for carbon steel in acidic medium. Mater Chem Phys 93:84–90

    Google Scholar 

  15. Quraishi MA, Sharma HK (2003) 4-Amino-3-butyl-5-mercapto-1,2,4-triazole: a new corrosion inhibitor for mild steel in sulphuric acid. Mater Chem Phys 78:18–21

    Google Scholar 

  16. Asan A, Kabasakalog lu M, Isiklan M, Kilic Z (2005) Corrosion inhibition of brass in presence of terdentate ligands in chloride solution. Corros Sci 47:1534–1544

    CAS  Google Scholar 

  17. Kirupha SD, Murugesan A, Vidhyadevi T, Baskaralingam P, Sivanesan S, Ravikumar L (2012) Novel polymeric adsorbents bearing amide, pyridyl, azomethine and thiourea binding sites for the removal of cu(II) and Pb(II) ions from aqueous solution. Sep Sci Technol 48:254–262

    CAS  Google Scholar 

  18. Vidhyadevi T, Murugesan A, Kirupha SD, Baskaralingam P, Ravikumar L, Sivanesan S (2013) Adsorption of Congo red dye over pendent chlorobenzylidine rings present on polythioamide resin: kinetic and equilibrium studies. Sep Sci Technol 48:1450–1458

    CAS  Google Scholar 

  19. Ravikumar L, Kalaivani S, Vidhyadevi T, Murugesan A, Kirupha SD, Sivanesan S (2014) Synthesis, characterization and metal ion adsorption studies on novel aromatic poly (azomethine amide)s containing thiourea groups. Open J Org Polym Mater 4:1–7

    CAS  Google Scholar 

  20. Kirupha SD, Kalaivani S, Vidhyadevi T, Premkumar P, Baskaralingam P, Sivanesan S, Ravikumar L (2015) Effective removal of heavy metal ions from aqueous solutions using a new chelating resin poly[2,5-(1,3,4-thiadiazole)-benzalimine]: kinetic and thermodynamic study. J Water Reuse Desal 6:310–324

    Google Scholar 

  21. Kirupha SD, Narayanasamy R, Sornalatha M, Sivanesan S, Ravikumar L (2017) Synthesis and metal ion uptake studies of chelating polyurethane resin containing donor atoms: experimental optimization and temperature studies. Can J Chem Eng 95:944–953

    CAS  Google Scholar 

  22. Mahalakshmi R, Kirupha SD, Rathina K, Ravikumar L (2018) Removal and recovery of thorium from aqueous solution using new polyurethane bearing azomethine and urethane chelators: kinetics, thermodynamics, and isotherm analysis. Desal Water Treat 121:92–103

    CAS  Google Scholar 

  23. Prabhu D, Rao P (2017) Corrosion behaviour of 6063 aluminium alloy in acidic and in alkaline media. Arab J Chem 10:S2234–S2244

    Google Scholar 

  24. Chalal S, Haddadine N, Bouslah N, Benaboura A (2012) Preparation of poly(acrylic acid)/silver nanocomposite by simultaneous polymerization-reduction approach for antimicrobial application. J Polym Res 19:24

    Google Scholar 

  25. Wei Q-B, Fu F, Zhang Y-Q, Tang L (2015) Synthesis and characterization of pH-responsive carboxymethyl chitosan-g-polyacrylic acid hydrogels. J Polym Res 22:15

    Google Scholar 

  26. Wei S, Zhang Y, Xu J (2011) Preparation and properties of poly(acrylic acid-co-styrene)/Fe3O4 nanocomposites. J Polym Res 18(1):125–130

    CAS  Google Scholar 

  27. Karppi J, Akerman S, Akerman K, Sundell A, Penttila I (2010) Adsorption of metal cations from aqueous solution onto the pH responsive poly(vinylidene fluoride) grafted poly(acrylic acid) (PVDF-PAA) membrane. J Polym Res 17:71

    CAS  Google Scholar 

  28. Kohestanian M, Bouhendi H, Ghiass M (2017) Synthesis and characterization of PAA microgels using multifunctional epoxy cross-linkers with a new cross-linking mechanism via a precipitation polymerization method. J Polym Res 24:194

    Google Scholar 

  29. Chen P, Wu R, Wang J, Liu Y, Ding C, Xu S (2012) One-pot preparation of ultrastrong double network hydrogels. J Polym Res 19:9825

    Google Scholar 

  30. Pourjavadi A, Farhadpour B, Seidi F (2009) Synthesis and investigation of swelling behaviour of new agar based superadsorbent hydrogel as a candidate for agrochemical delivery. J Polym Res 16:655

    CAS  Google Scholar 

  31. Yuan R, Liu H, Yu P, Wang H, Liu J (2018) Enhancement of adhesion, mechanical strength and anti-corrosion by multilayer superhydrophobic coating embedded electroactive PANI/CNF nanocomposite. J Polym Res 25:151

    Google Scholar 

  32. Aly KI, Hussein MA (2010) New polymer syntheses, part 45: corrosion inhibition behaviour of novel polyurea derivatives based on diarylidenecycloalkanone mioties in the polymer backbone. J Polym Res 17(5):607–620

    CAS  Google Scholar 

  33. Pruna A, Branzoi F (2012) Electrochemical activity and microscopy of electrosynthesised poly(o-phenylenediamine) nanotubes. J Polym Res 19:9879

    Google Scholar 

  34. Bereket G, Pinarbasi A (2004) Electrochemical thermodynamic and kinetic studies of the behaviour of aluminium in hydrochloric acid containing various benzotriazole derivatives. Corros Eng sci Techn 39:308–312

    CAS  Google Scholar 

  35. Fragoza-Mar L, Olivares-Xometl O, Dominguez-Aguilar MA, Flores EU, Arellanes-Lozada P, Jimenez-Cruz F (2012) Corrosion inhibitor activity of 1,3-diketone malonates for mild steel in aqueous hydrochloric acid solution. Corros Sci 61:171–184

    CAS  Google Scholar 

  36. Vasanthi BJ, Ravikumar L, Selvaraj A (2008) Corrosion control of phenylthiourea polymers on aluminium in alkaline medium. Mater Corros 59:14–20

    CAS  Google Scholar 

  37. Li S, Clen S, lei S, Ma H, Yu R, Liu D (1999) Investigation on some Schiff bases as HCl corrosion. Corros Sci 41:1273–1287

  38. Behpour M, Ghoreishi SM, Soltani N, Salavati-Niasari M, Hamadanian M, Gandomi A (2008) Electrochemical and theoretical investigation on the corrosion inhibition of mild steel by thiosalicylaldehyde derivatives in hydrochloric acid solution. Corros Sci 50:2172–2181

    CAS  Google Scholar 

  39. Tang L, Mu G, Liu G (2003) The effect of neutral red on the corrosion inhibition of cold rolled steel in 1.0 M hydrochloric acid. Corros Sci 45:2251–2262

    CAS  Google Scholar 

  40. Arsian T, Kandemirli F, Ebenso EE, Love I, Alemu H (2009) Quantum chemical studies on the corrosion inhibition of some sulphonamides on mild steel in acidic medium. Corros Sci 51:35–47

    Google Scholar 

  41. Larabi L, Harek Y, Traisnel M, Mansri A (2014) Inhibition behavior of mild steel in 1 M HCl in the presence of poly(4-vinylpyridine) (P4VP) and potassium iodide. J Appl Electrochem 34:833–839

    Google Scholar 

  42. Trabanelli G (1987) Corrosion Inhibitors. In: Mansfeld F (ed) Chemical industries: corrosion mechanism, chapter 3. Marcel Dekker, New York, pp 28–120

    Google Scholar 

  43. Frumkin AN (1964) Influence of adsorption of neutral molecules and organic cations on the kinetics of electrode processes. Electrochim Acta 9:465–476

    CAS  Google Scholar 

  44. Antrapov LI (1967) A correlation between kinetics of corrosion and the mechanism of inhibition by organic compounds. Corros Sci 7:607–620

    Google Scholar 

  45. Ashassi-Sorkhabi H, Majidi MR, Seyyedi K (2004) Investigation of inhibition effect of some amino acids against steel corrosion in HCl solution. Appl Surf Sci 225:176–185

    CAS  Google Scholar 

  46. Amin MA, Khaled KF (2010) Monitoring corrosion and corrosion control of iron in HCl by non-ionic surfactants of the TRITON-X series–part I. Tafel polarisation, ICP-AES and EFM studies. Corros Sci 52:1762–1770

    CAS  Google Scholar 

  47. Lebrini M, Lagrenee M, Vezin H, Traisnel M, Bentiss F (2007) Experimental and theoretical study for corrosion inhibition of mild steel in normal hydrochloric acid solution by some new macrocyclic polyether compounds. Corros Sci 49:2254–2269

    CAS  Google Scholar 

  48. Ghareba S, Omanovic S (2011) 12-Aminododecanoic acid as a corrosion inhibitor for carbon steel. Electrochim Acta 56:3890–3898

    CAS  Google Scholar 

  49. El-Haddad MN, Fouda AS (2015) Electro-analytical, quantum and surface characterization studies on imidazole derivatives as corrosion inhibitors for aluminum in acidic media. J Mol Liq 209:480–486

    CAS  Google Scholar 

  50. Deyab MA (2015) Corrosion inhibition of aluminum in biodiesel by ethanol extracts of rosemary leaves. J Tai Inst Chem Eng 58:536–541

    Google Scholar 

  51. Eddy NO, Momoh-Yahaya H, Oguzie EE (2015) Theoretical and experimental studies on the corrosion inhibition potentials of some purines for aluminum in 0.1 M HCl. J Adv Res 6:203–217

    CAS  PubMed  Google Scholar 

  52. El-Maghraby AA (2009) Corrosion inhibition of aluminum in hydrochloric acid solution using potassium iodate inhibitor. Open Corrosion J 2:189–196

    CAS  Google Scholar 

  53. El-Sherbini EEF, Abd-El-Wahab SM, Deyab MA (2003) Studies on corrosion inhibition of aluminum in 1.0 M HCl and 1.0 M H2SO4 solutions by ethoxylated fatty acids. Mater Chem Phys 82:631–637

    Google Scholar 

  54. Obot IB, Obi-Egbedi NO (2008) Fluconazole as an inhibitor for aluminium corrosion in 0.1 M HCl. Colloids Surf A Physicochem Eng Asp 330:207–212

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, SVS College of Engineering, JP NAGAR, Coimbatore, Tamil Nadu, 642109, India

    Ranganathan Punitha

  2. Centre of Excellence for Medical Textiles, The South India Textile Research Association (SITRA), Coimbatore, 641014, India

    Selvaraj Dinesh Kirupha

  3. Department of Chemistry, CBM College, Coimbatore, 641042, India

    Selvaraj Vivek & Lingam Ravikumar

Authors
  1. Ranganathan Punitha
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Selvaraj Dinesh Kirupha
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Selvaraj Vivek
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Lingam Ravikumar
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ranganathan Punitha.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Punitha, R., Kirupha, S.D., Vivek, S. et al. Synthesis and corrosion inhibition studies of modified polyacrylic acid bearing triazole moieties on aluminium in alkaline medium. J Polym Res 26, 287 (2019). https://doi.org/10.1007/s10965-019-1921-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-019-1921-3

Keywords

Search

Navigation