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A Comparative Study on the Pollutant Removal Efficiency of CoFe2O4@HKUST-1 MOF and CoFe2O4 Nanoparticles

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Abstract

In this work, CoFe2O4 nanoparticles were fabricated by the Pechini sol–gel technique. Then, Cu3(BTC)2 or HKUST-1 metal–organic framework was used to prepare Co-ferrite@HKUST-1 composite. The as-synthesized composite powder and Co-ferrite nanoparticles were compared by their performance for methyl orange (MO) and methylene blue (MB) degradation. X-ray diffractometry (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and vibrating sample magnetometer (VSM) were utilized to evaluate the as-prepared samples. Results showed that the average grain size was about 20–30 nm. The magnetic saturation value for Co-ferrite nanoparticles and Co-ferrite@HKUST-1 composite were 65 and 20 emu/g, respectively. Results of the removal efficiency of the Co-ferrite samples approved that just the cation dyes concentrations decreased, whereas in the case of the Co-ferrite@HKUST-1 composite samples both anionic and cationic organic dyes were degraded efficiently.

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Authors and Affiliations

  1. Department of Nanomaterials and Nanocoatings, Institute for Color Science and Technology, PO. Box 1668814811, Tehran, Iran

    Tahoura Saemian & Mehrnaz Gharagozlou

  2. Department of Chemistry, Faculty of Science, Azarbaijan Shahid Madani University, Tabriz, Iran

    Tahoura Saemian & Moayad Hossaini Sadr

  3. Ascotec Holding GMBH, Tersteegenstrasse 10, 40474, Dusseldorf, Germany

    Moayad Hossaini Sadr

  4. Department of Metallurgy and Materials Engineering, Shahreza Branch, Islamic Azad University, PO. Box 311–86145, Shahreza, Iran

    Sanaz Naghibi

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  1. Tahoura Saemian
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  2. Mehrnaz Gharagozlou
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  4. Sanaz Naghibi
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Correspondence to Mehrnaz Gharagozlou.

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Saemian, T., Gharagozlou, M., Hossaini Sadr, M. et al. A Comparative Study on the Pollutant Removal Efficiency of CoFe2O4@HKUST-1 MOF and CoFe2O4 Nanoparticles. J Inorg Organomet Polym 30, 2347–2355 (2020). https://doi.org/10.1007/s10904-019-01406-7

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  • DOI: https://doi.org/10.1007/s10904-019-01406-7

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