Abstract
Classical hydrometallurgy methods such as chemical precipitation, ion exchange, solvent extraction and adsorption have been used to recover vanadium from aqueous solutions, but the last step of these methods involves precipitation with ammonium salts, which are harmful to the environment at high concentration. Therefore, here we tested urea as a new precipitant to replace ammonium salts. We studied the effect of various parameters on the precipitation efficiency of vanadium. Results showed that urea is hydrolyzed to form NH4+ in acidic medium at 90 °C. Then, NH4+ reacts with V6O162− and precipitates as (NH4)2V6O16. Nearly 95% of the vanadium was precipitated within 120 min in the system containing 2.8 g/L vanadium and n(CON2H4)/n(V) of 0.6. The Avrami model was used to describe crystallization kinetics and analysis of the dimensions of crystal growth. Model results show that the crystalline growth was one-dimensional and that the crystals were shaped in columns. Overall, this study introduced a new way for urea utilization as a new precipitant to recover vanadium.
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References
Anjass MH, Kastner K, Nagele F, Ringenberg M, Boas JF, Zhang J, Bond AM, Jacob T, Streb C (2017) Stabilization of low-valent iron(I) in a high-valent vanadium(V) oxide cluster. Angew Chem Int Ed Engl 56(46):14749–14752. https://doi.org/10.1002/anie.201706828
Avrami M (1939) Kinetics of phase change I: general theory. J Chem Phys 7:1103–1112
Avrami M (1940) Kinetics of phase change II: transformation time relations for random distribution of nuclei. J Chem Phys 8:212–224
Bao S, Duan J, Zhang Y (2018) Recovery of V(V) from complex vanadium solution using capacitive deionization (CDI) with resin/carbon composite electrode. Chemosphere 208:14–20. https://doi.org/10.1016/j.chemosphere.2018.05.149
Bashir A, Malik LA, Ahad S, Manzoor T, Bhat MA, Dar GN, Pandith AH (2019) Removal of heavy metal ions from aqueous system by ion-exchange and biosorption methods. Environ Chem Lett 17(2):729–754. https://doi.org/10.1007/s10311-018-00828-y
Celik FA, Kazanc S (2013) Crystallization analysis and determination of Avrami exponents of CuAlNi alloy by molecular dynamics simulation. Phys B 409:63–70. https://doi.org/10.1016/j.physb.2012.10.015
Celik FA, Kazanc S, Ozgen S, Yildiz AK (2011) Investigating the crystallization process of a ternary alloy system with a new nano-cluster analysis by using molecular dynamics method. Solid State Sci 13(5):959–965. https://doi.org/10.1016/j.solidstatesciences.2011.02.009
Efremenko V, Shimizu K, Chabak Y (2013) Effect of destabilizing heat treatment on solid-state phase transformation in high-chromium cast irons. Metall Mater Trans A 44(12):5434–5446. https://doi.org/10.1007/s11661-013-1890-9
El Hage R, Chauvet F, Biscans B, Cassayre L, Maurice L, Tzedakis T (2019) Kinetic study of the dissolution of vanadyl sulfate and vanadium pentoxide in sulfuric acid aqueous solution. Chem Eng Sci 199:123–136. https://doi.org/10.1016/j.ces.2019.01.024
Hermida L, Agustian J (2019) Slow release urea fertilizer synthesized through recrystallization of urea incorporating natural bentonite using various binders. Environ Technol Innov 13:113–121. https://doi.org/10.1016/j.eti.2018.11.005
Hu W, Wang L, Wu L, Zhang B, Guan H (1994) The activation energy and the Avrami exponent for crystallization in amorphous Fe70.45W1.55Si3B25. Phys B 203(1):147–150. https://doi.org/10.1016/0921-4526(94)90288-7
Hubbes S-S, Danzl W, Foerst P (2018) Crystallization kinetics of palm oil of different geographic origins and blends thereof by the application of the Avrami model. LWT 93:189–196. https://doi.org/10.1016/j.lwt.2018.03.022
Kang Q, Zhang Y, Bao S (2019) An environmentally friendly hydrothermal method of vanadium precipitation with the application of oxalic acid. Hydrometallurgy 185:125–132. https://doi.org/10.1016/j.hydromet.2019.01.011
Lübke M, Ding N, Powell MJ, Brett DJL, Shearing PR, Liu Z, Darr JA (2016) VO2 nano-sheet negative electrodes for lithium-ion batteries. Electrochem Commun 64:56–60. https://doi.org/10.1016/j.elecom.2016.01.013
Peng H, Liu Z, Tao C (2017a) Adsorption kinetics and isotherm of vanadium with melamine. Water Sci Technol 75(10):2316–2321. https://doi.org/10.2166/wst.2017.094
Peng H, Liu Z, Tao C (2017b) Adsorption process of vanadium(V) with melamine. Water Air Soil Pollut 228(8):272. https://doi.org/10.1007/s11270-017-3452-z
Prathap K, Namasivayam C (2009) Adsorption of vanadate(V) on Fe(III)/Cr(III) hydroxide waste. Environ Chem Lett 8(4):363–371. https://doi.org/10.1007/s10311-009-0234-x
Shu J, Wu H, Chen M, Peng H, Li B, Liu R, Liu Z, Wang B, Huang T, Hu Z (2019) Fractional removal of manganese and ammonia nitrogen from electrolytic metal manganese residue leachate using carbonate and struvite precipitation. Water Res 153:229–238. https://doi.org/10.1016/j.watres.2018.12.044
Smirnov MB, Kazimirov VY, Baddour-Hadjean R, Smirnov KS, Pereira-Ramos J-P (2014) Atomistic mechanism of phase transition in vanadium pentoxide. J Phys Chem Solids 75(1):115–122. https://doi.org/10.1016/j.jpcs.2013.09.007
Wei Z, Liu D, Hsu C, Liu F (2014) All-vanadium redox photoelectrochemical cell: an approach to store solar energy. Electrochem Commun 45:79–82. https://doi.org/10.1016/j.elecom.2014.05.018
Wen J, Jiang T, Xu Y, Cao J, Xue X (2018) Efficient extraction and separation of vanadium and chromium in high chromium vanadium slag by sodium salt roasting-(NH4)2SO4 leaching. J Ind Eng Chem 71:325–327. https://doi.org/10.1016/j.jiec.2018.11.043
Wen J, Jiang T, Zhou W, Gao H, Xue X (2019) A cleaner and efficient process for extraction of vanadium from high chromium vanadium slag: leaching in (NH4)2SO4-H2SO4 synergistic system and NH4 + recycle. Sep Purif Technol 216:126–135. https://doi.org/10.1016/j.seppur.2019.01.078
Xiang J, Huang Q, Lv X, Bai C (2018) Extraction of vanadium from converter slag by two-step sulfuric acid leaching process. J Clean Prod 170:1089–1101. https://doi.org/10.1016/j.jclepro.2017.09.255
Yang X, Zhang Y, Bao S, Shen C (2016) Separation and recovery of vanadium from a sulfuric-acid leaching solution of stone coal by solvent extraction using trialkylamine. Sep Purif Technol 164:49–55. https://doi.org/10.1016/j.seppur.2016.03.021
Ye G, Hu Y, Tong X, Lu L (2018) Extraction of vanadium from direct acid leaching solution of clay vanadium ore using solvent extraction with N235. Hydrometallurgy 177:27–33. https://doi.org/10.1016/j.hydromet.2018.02.004
Zadorozhnyy VY, Klyamkin SN, Zadorozhnyy MY, Bermesheva OV, Kaloshkin SD (2014) Mechanical alloying of nanocrystalline intermetallic compound TiFe doped by aluminum and chromium. J Alloy Compd 586:S56–S60. https://doi.org/10.1016/j.jallcom.2013.01.138
Zhang X, Fang D, Song S, Cheng G, Xue X (2019a) Selective leaching of vanadium over iron from vanadium slag. J Hazard Mater 368:300–307. https://doi.org/10.1016/j.jhazmat.2019.01.060
Zhang Y, Zhang TA, Dreisinger D, Lv C, Lv G, Zhang W (2019b) Recovery of vanadium from calcification roasted-acid leaching tailing by enhanced acid leaching. J Hazard Mater 369:632–641. https://doi.org/10.1016/j.jhazmat.2019.02.081
Zhu X, Li W, Zhang Q, Zhang C, Chen L (2018) Separation characteristics of vanadium from leach liquor of red mud by ion exchange with different resins. Hydrometallurgy 176:42–48. https://doi.org/10.1016/j.hydromet.2018.01.009
Acknowledgements
This work was supported by the Science and Technology Project of Chongqing, China (No. cstc2018jcyjAX0018), National Natural Science Foundation of China (No. 51804062) and Talent Introduction Project of Yangtze Normal University (No. 2017KYQD117).
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Peng, H., Yang, L., Wang, L. et al. Recovery of vanadium with urea in acidic medium. Environ Chem Lett 17, 1867–1871 (2019). https://doi.org/10.1007/s10311-019-00902-z
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DOI: https://doi.org/10.1007/s10311-019-00902-z