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Rich nitrogen-doped ordered mesoporous carbon synthesized by copolymerization of PMDA and ODA with SBA-15 as a template for high-performance supercapacitors

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Abstract

Polyimide-based nitrogen-doped ordered mesoporous carbon was successfully synthesised utilising SBA-15 as a hard template. By controlling the molar ratio of 4,4′-oxydianiline to pyromellitic dianhydride during copolymerising and carbonisation, nitrogen-doped ordered mesoporous carbon (NOMCx) with various nitrogen content and pore distribution were obtained. When the molar ratio of 4,4′-oxydianiline to pyromellitic dianhydride was 6, NOMC6 presented the highest content of nitrogen (7.94 wt%) and moderate specific surface area (890 m2 g−1). Accordingly, NOMC6 showed a high specific capacitance of 282 F g−1 at 0.1 A g−1, and excellent cycle stability (no capacitance loss over 10,000 cycles) in 1 M H2SO4. The synthesised ordered mesoporous carbons do not show a significant decrease of capacitive performance in the current density range of 2 to 20 A g−1. Furthermore, a symmetrical supercapacitor consisting of two NOMC6 electrodes exhibited an energy density of 4.77 Wh kg−1 at power density of 500 W kg−1 (1 A g−1).

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Project Code 21776051); the Scientific Research Foundation for Yangcheng Scholars (Project Code 1201541563); Applied Science and Technology Planning Project of Guangdong Province (Project Code 2017B090917002).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou, China

    Tingting Ma, Zongjian Wu, Kangzhou Lei, Jingzhou Lin & Shengzhou Chen

  2. Guangzhou Key Laboratory for New Energy and Green Catalysis, Guangzhou University, Guangzhou, China

    Wei Yang & Hanbo Zou

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  1. Tingting Ma
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  2. Wei Yang
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  3. Zongjian Wu
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Correspondence to Wei Yang or Shengzhou Chen.

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Ma, T., Yang, W., Wu, Z. et al. Rich nitrogen-doped ordered mesoporous carbon synthesized by copolymerization of PMDA and ODA with SBA-15 as a template for high-performance supercapacitors. J Porous Mater 27, 525–535 (2020). https://doi.org/10.1007/s10934-019-00832-9

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