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Effects of Fe doping on perovskite development and dielectric properties of Pb([Zn,Mg]1/2W1/2)O3 ceramics

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Abstract

The stabilization of a perovskite structure in yet-unreported Pb(Zn1/2W1/2)O3 (PZW) was attempted through compositional modification by multiple species of Mg and Fe for Zn. The attempt was accomplished through the substitutions by ≥20 mol% Pb(Mg1/2W1/2)O3 (PMW) at the presence of additional 20 mol% Pb(Fe2/3W1/3)O3 (PFW). The perovskite formation yields were 0% (0.8PZW-0.2PFW), 88.3% (0.6PZW-0.2PMW-0.2PFW), and ≥ 99.7% (virtually completed state) at higher levels of substituent PMW. Lattice parameters of the perovskite structure decreased nearly linearly with increasing fractions of Mg. Developed microstructures of the sintered ceramics mostly revealed well-developed perovskite grains with a multi-faceted polyhedral morphology. Their fracture modes were virtually intergranular. Frequency-dependent dielectric dispersion behaviors, with diffuse modes in the phase transition, were observed at the modified composition range. Values of the maximum dielectric constant increased sharply at an intermediate composition range, whereas corresponding temperatures were comparatively insensitive to the compositional change.

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Acknowledgments

This study was supported by the Kyungpook National University Research Fund, 2018-21.

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  1. School of Materials Science and Engineering, Kyungpook National University, Daegu, 41566, Republic of Korea

    Woo-Joon Lee & Nam-Kyoung Kim

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  1. Woo-Joon Lee
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  2. Nam-Kyoung Kim
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Correspondence to Nam-Kyoung Kim.

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Lee, WJ., Kim, NK. Effects of Fe doping on perovskite development and dielectric properties of Pb([Zn,Mg]1/2W1/2)O3 ceramics. J Electroceram 43, 20–25 (2019). https://doi.org/10.1007/s10832-019-00177-4

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  • DOI: https://doi.org/10.1007/s10832-019-00177-4

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