Skip to main content
Log in

Effect of Nitride Nuclear Fuel Structure and Phase Composition on Fuel-Rod Life

  • Published:
Atomic Energy Aims and scope

The behavior of mixed uranium-plutonium nitride fuel and uranium nitride was studied by means of thermogravimetry at high temperatures (to 2173 K) in a helium flow. The mass loss of the nitride samples was found in the low temperature range (<1773 K), which is not associated with decomposition of uranium or plutonium mononitrides. The mass loss occurs in two stages and is accompanied by the release of nitrogen. It is shown that nitride fuel can contain up to several percent of uranium sesquinitride U2N3, which decomposes in the indicated temperature range and can strongly affect pellet integrity and fuel-rod life during operation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. V. M. Troyanov, A. F. Grachev, L. M. Zabudko, and M. V. Skupov, “Prospects for the use of nitride fuel in fast closed-cycle reactors,” At. Energ., 117, No. 2, 69–74 (2014).

    Google Scholar 

  2. S. V. Alekseev and V. A. Zaitsev, Nitride Fuel for Nuclear Power, Tekhnosphera, Moscow (2013).

    Google Scholar 

  3. X. Wang, Z. Long, R. Bin, et al., “Study of the decomposition and phase transition of uranium nitride under UHV conditions via TDS, XRD, SEM, and XPS,” Inorg. Chem., 55, No. 21, 10835–10838 (2016).

    Article  Google Scholar 

  4. T. Hiroaki, “Phase relations and thermodynamic properties of the uranium-nitrogen system,” J. Nucl. Mater., 51, 78–89 (1974).

    Article  ADS  Google Scholar 

  5. Y. Arai and K. Nakajima, “Preparation and characterization of PuN pellets containing ZrN and TiN,” J. Nucl. Mater., 281, No. 2–3, 244–247 (2000).

    Article  ADS  Google Scholar 

  6. C. Ganguly, P. Hegde, and A. Sengupta, “Preparation, characterisation and out-of-pile property evaluation of (U, Pu)N fuel pellets,” J. Nucl. Mater., 178, No. 2–3, 234–241 (1991).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. P. Krivov.

Additional information

Translated from Atomnaya Énergiya, Vol. 127, No. 1, pp. 25–29, July, 2019.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Krivov, M.P., Kireev, G.A. & Tenishev, A.V. Effect of Nitride Nuclear Fuel Structure and Phase Composition on Fuel-Rod Life. At Energy 127, 28–32 (2019). https://doi.org/10.1007/s10512-019-00579-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10512-019-00579-1

Navigation