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Physicochemical Properties and Spectral Studies for Binary Systems of 2-Ethoxyethanol (1) + Water (2) and + Dimethyl Sulfoxide (2)

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Abstract

In the development of CO2 capture and utilization, the physical and transport properties of the binary systems are significant, because these can affect the gas absorption and desorption processes. Thus, we report the densities and viscosities of two binary systems: 2-ethoxyethanol (ECS) + water (H2O) and ECS + dimethyl sulfoxide (DMSO), with various compositions at temperatures from (298.15 to 318.15) K. On the basis of these data, excess molar volumes (\(V_{\text{m}}^{\text{E}}\)) and viscosity deviations (Δη) were calculated. The \(V_{\text{m}}^{\text{E}}\) values of the two binary mixtures are negative and decrease with increasing temperatures; Δη values are positive at all compositions and decrease with increasing temperatures. The \(V_{\text{m}}^{\text{E}}\) and Δη values were fitted with the Redlich–Kister equation. The physico-chemical properties of the two binary systems, including activation enthalpy and entropy, were calculated from the kinematic viscosity. In addition, various spectral results offer evidence for the formation of weak interactions between ECS and DMSO or H2O.

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Funding

This work was supported by Key Laboratory of Coal-based CO2 Capture and Geological Storage (Jiangsu Province, China University of Mining and Technology, 2016A06), the Program for Grassland Excellent Talents of Inner Mongolia Autonomous Region, the Natural Science Foundation of Inner Mongolia Autonomous Region (2016JQ02), the Inner Mongolia Science and Technology Key Projects, and training plan of academic backbone in youth of Inner Mongolia University of Technology.

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Authors and Affiliations

  1. Key Laboratory of Coal-based CO2 Capture and Geological Storage, China University of Mining and Technology, Xuzhou, 221008, China

    Xianshu Qiao & Jianbin Zhang

  2. Inner Mongolia Engineering Research Center for CO2 Capture and Utilization, Hohhot, 010051, China

    Xianshu Qiao, Fang Han, Long Zhao, Huipeng Li & Jianbin Zhang

  3. Petroleum Engineering Research Institute of PetroChina Dagang Oilfield Company, Tianjin, 300280, China

    Fang Han

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  1. Xianshu Qiao
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Correspondence to Jianbin Zhang.

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Qiao, X., Han, F., Zhao, L. et al. Physicochemical Properties and Spectral Studies for Binary Systems of 2-Ethoxyethanol (1) + Water (2) and + Dimethyl Sulfoxide (2). J Solution Chem 48, 1244–1265 (2019). https://doi.org/10.1007/s10953-019-00908-9

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