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Role of Mn: Promotion of Fast-SCR for Cu-SAPO-34 in Low-Temperature Selective Catalytic Reduction with Ammonia

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Abstract

There is a required need for improving low-temperature selective catalytic reduction with ammonia (NH3-SCR) activities of catalysts. In this paper, Cu-SAPO-34 and Mn/Cu-SAPO-34 catalysts were prepared by a one-pot hydrothermal synthesis method. ICP-OES, N2 adsorption/desorption, XRD, FT-IR, SEM, H2-TPR, XPS, NH3/NO-TPD were performed to study the properties of the catalysts. Mn promoted Cu-SAPO-34 shows considerably improvement in low-temperature NH3-SCR activity with almost 100% NOx conversion between 220–300 °C. It is suggested that the excellent catalytic activity of Mn/Cu-SAPO-34 is ascribed to MnO2 which can promote “fast-SCR”. H2O/SO2 resistance tests were also investigated and the results show that the catalysts both exhibit strong resistance to H2O but the introduction of Mn doesn’t improve the SO2 resistance of Cu-SAPO-34.

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Authors and Affiliations

  1. Key Laboratory for Green Chemical Technology of Ministry of Education, R&D Center for Petrochemical Technology, Tianjin University, Tianjin, 300072, People’s Republic of China

    Minhua Zhang, Haibo Cao, Yifei Chen & Haoxi Jiang

  2. Collaborative Innovation Center of Chemical Science and Engineering, Tianjin, 300072, People’s Republic of China

    Minhua Zhang, Haibo Cao, Yifei Chen & Haoxi Jiang

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  1. Minhua Zhang
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  2. Haibo Cao
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  3. Yifei Chen
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  4. Haoxi Jiang
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Correspondence to Haoxi Jiang.

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Zhang, M., Cao, H., Chen, Y. et al. Role of Mn: Promotion of Fast-SCR for Cu-SAPO-34 in Low-Temperature Selective Catalytic Reduction with Ammonia. Catal Surv Asia 23, 245–255 (2019). https://doi.org/10.1007/s10563-019-09277-1

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  • DOI: https://doi.org/10.1007/s10563-019-09277-1

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