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Synthesis, Characterization and Catalytic Application of Starch Supported Cuprous Iodide Nanoparticles

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Abstract

The starch supported cuprous iodide nanoparticles (CuI-NPs@Starch) were synthesized in aqueous medium and characterized by transmission electron microscopy, scanning electron microscopy, X-ray powder diffraction, energy-dispersive X-ray spectroscopy and atomic absorption spectra analysis. The newly synthesized CuI NPs on starch have been demonstrated first time as an efficient catalyst for the regioselective 3-allylation reaction of N-substituted indoles as well as ring-substituted indoles using various allyl alcohols under moisture and air insensitive conditions.

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Notes

  1. Environmental friendly polysaccharides, such as chitosan, cellulose and agarose are currently being explored as support materials for catalyst systems. Please see the Refs. [20,21,22,23,24].

  2. The non-reusability of catalyst may also be caused by the degradation of the starch polymer. We thank one of the reviewers for this insightful suggestion.

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Acknowledgements

D.D. acknowledges the financial support (project ref. No. YSS/2015/001425) from Science & Engineering Research Board (SERB), New Delhi. Also, D.D. is highly grateful to Dr. Asish Kumar Dey (Principal, TDB College, Raniganj) for support and encouragement.

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Authors and Affiliations

  1. Department of Chemistry, Indira Gandhi National Tribal University, Amarkantak, India

    Sadhucharan Mallick

  2. School of Basic Sciences, Indian Institute of Technology, Bhubaneswar, India

    Priyabrata Mukhi

  3. Centre for Applied Chemistry, Central University of Jharkhand, Ranchi, India

    Poonam Kumari, Kumari Reshmi Mahato & Suryadev Kumar Verma

  4. Department of Chemistry, Triveni Devi Bhalotia College, Raniganj, India

    Debjit Das

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  1. Sadhucharan Mallick
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  2. Priyabrata Mukhi
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Correspondence to Debjit Das.

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Mallick, S., Mukhi, P., Kumari, P. et al. Synthesis, Characterization and Catalytic Application of Starch Supported Cuprous Iodide Nanoparticles. Catal Lett 149, 3501–3507 (2019). https://doi.org/10.1007/s10562-019-02909-1

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  • DOI: https://doi.org/10.1007/s10562-019-02909-1

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