Intercalating potassium-aqua complex cation into α-MoO3 layer without reducing molybdenum: a potential storage system

Abstract

We have demonstarted a green aqueous synthesis of rod-shaped MoO3 material, [MoVI3O9{K(H2O)4}(CH3COO)]∙H2O (2) intercalating potassium-aqua-complex acetate into its lamellar space, simply by ion-exchange of Co(II)-aqua-complex in compound [MoVI4O12(CH3COO)2{CoII(H2O)6}]∙2H2O (1) by {K(H2O)4}+ in an aqueous solution of 1 and KCl. Compound 2 acts as potential storage system of alkali metal ions.

Supplementary files

Article information

Article type
Communication
Submitted
27 Mar 2024
Accepted
15 Apr 2024
First published
15 Apr 2024

Chem. Commun., 2024, Accepted Manuscript

Intercalating potassium-aqua complex cation into α-MoO3 layer without reducing molybdenum: a potential storage system

D. Jana, S. S. Mishra and S. K. Das, Chem. Commun., 2024, Accepted Manuscript , DOI: 10.1039/D4CC01400F

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