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First Example of an Octahedral Rhenium Telluride Cluster Complex with an Organic N-Donor Ligand

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Abstract

The [{Re6Te8}(imzH)6]2+ cationic cluster complex prepared by the interaction of [{Re6Te8} (TeI2)6]I2·[{Re6Te8}(TeI2)4(TeI3)2]·I2 with imidazole (imzH) in a sealed glass ampoule at 200 °C for 48 h. The composition of the obtained compound is confirmed by 1H NMR spectroscopy and high-resolution mass spectrometry. The single crystals suitable for SC-XRD are prepared by slow diffusion of diethyl ether vapors into a solution of the complex in DMF. According to the SC-XRD data, the resulting complex has the composition [{Re6Te8}(imzH)6]I2·2/3DMF. The compound crystallizes in the monoclinic crystal system, P21/c space group, with the following unit cell parameters: a = 18.0379(4) Å, b = 17.9945(5) Å, c = 33.1318(7) Å, β = 115.1829(10)°, V = 9732.0(4) Å3, Z = 6. It is also shown that this compound exhibits solid-state luminescence with an emission maximum at 730 nm characteristic of octahedral rhenium cluster complexes.

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Funding

This work was funded by the Russian Science Foundation (project No. 22-23-20110) and by the Novosibirsk region Government (project No. p-30).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E. D. Novikova, D. I. Konovalov, A. A. Ivanov, N. V. Kuratieva, A. S. Berezin & M. A. Shestopalov

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  1. E. D. Novikova
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  2. D. I. Konovalov
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  3. A. A. Ivanov
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Correspondence to D. I. Konovalov.

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Russian Text © The Author(s), 2024, published in Zhurnal Strukturnoi Khimii, 2024, Vol. 65, No. 2, 122359.https://doi.org/10.26902/JSC_id122359

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Novikova, E.D., Konovalov, D.I., Ivanov, A.A. et al. First Example of an Octahedral Rhenium Telluride Cluster Complex with an Organic N-Donor Ligand. J Struct Chem 65, 323–330 (2024). https://doi.org/10.1134/S0022476624020100

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