Issue 13, 2023

Cobalt-catalysed [1,2]-Wittig rearrangement of ethers to secondary alcohols

Abstract

Stable ethers are successfully transformed into secondary alcohols via C–O bond activation using a simple cobalt pincer catalyst. Mechanistic studies indicate the involvement of radical pairs, and their sequential recombination and the subsequent hydrolysis results in the formation of secondary alcohols.

Graphical abstract: Cobalt-catalysed [1,2]-Wittig rearrangement of ethers to secondary alcohols

Supplementary files

Article information

Article type
Communication
Submitted
21 Dec 2022
Accepted
18 Jan 2023
First published
26 Jan 2023

Chem. Commun., 2023,59, 1853-1856

Cobalt-catalysed [1,2]-Wittig rearrangement of ethers to secondary alcohols

S. Pattanaik, A. Kumar and C. Gunanathan, Chem. Commun., 2023, 59, 1853 DOI: 10.1039/D2CC06937G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements