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Influence of Cooperative Interactions on the Spin Crossover Phenomenon in Iron(II) Complexes: A Review

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Theoretical and Experimental Chemistry Aims and scope

The theoretical principles of a spin transition phenomenon in pseudo-octahedral iron(II) complexes are summarized. The intrinsic transfer of electrons between d-orbitals of a central ion under the action of external factors and the corresponding changes in the structural, spectral, and magnetic characteristics of matter are considered. Cooperative interactions that lead to the appearance of hysteresis of physical properties have been studied in detail. Perspective areas of practical applications of compounds with spin transitions have been provided.

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  1. Taras Shevchenko National University of Kyiv, Kyiv, Ukraine

    M. L. Seredyuk, K. O. Znovjyak & I. O. Fritsky

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Seredyuk, M.L., Znovjyak, K.O. & Fritsky, I.O. Influence of Cooperative Interactions on the Spin Crossover Phenomenon in Iron(II) Complexes: A Review. Theor Exp Chem 58, 75–89 (2022). https://doi.org/10.1007/s11237-022-09725-6

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