Skip to main content
SpringerLink
Log in

Effects of MTW Zeolite Crystallite Morphology on Product Formation in Isomerization of m-Xylene

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

Four samples of ZSM-12 zeolite (MTW structural type) synthesized using various template types were tested as catalysts in m-xylene isomerization. The functionality of the catalysts was examined using solid-state 27Al NMR spectroscopy, NH3–TPD, and IR spectroscopy of adsorbed pyridine. The effects of the crystallite size, acidity, and phase purity of the zeolites on the composition of the reaction products were investigated. The template used for the synthesis was found to affect the physicochemical properties and catalytic activity of the zeolites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Kostyniuk, A., Bajec, D., and Likozar, B., J. Ind. Eng. Chem., 2021, vol. 96, pp. 130–143. https://doi.org/10.1016/j.jiec.2021.01.010

    Article  CAS  Google Scholar 

  2. Wang, F., Xiao, W., Gao, L., and Xiao, G., RSC Adv., 2016, vol. 6, no. 49, pp. 42984–42993. https://doi.org/10.1039/c6ra03358j

    Article  CAS  Google Scholar 

  3. Popov, A.G., Fedosov, D.A., Ivanova, I.I., Vedernikov, O.S., Kleimenov, A.V., Kondrashev, D.O., Miroshkina, V.D., Abrashenkov, P.A., and Kuznetsov, S.E., Petrol. Chem., 2016, vol. 56, no. 3, pp. 237–243. https://doi.org/10.1134/S0965544116030117

    Article  CAS  Google Scholar 

  4. Vorobkalo, V.A., Knyazeva, E.E., and Ivanova, I.I., Petrol. Chem., 2021, vol. 61, no. 3, pp. 299–324. https://doi.org/10.1134/S0965544121030099

    Article  CAS  Google Scholar 

  5. Glotov, A.P., Roldugina, E.A., Artemova, M.I., Smirnova, E.M., Demikhova, N.R., Stytsenko, V.D., Egazar’yants, S.V., Maximov, A.L., and Vinokurov, V.A., Russ. J. Appl. Chem., 2018, vol. 91, no. 8, pp. 1353–1362. https://doi.org/10.1134/S1070427218080141

    Article  CAS  Google Scholar 

  6. Glotov, A.P., Artemova, M.I., Demikhova, N.R., Smirnova, E.M., Ivanov, E.V., Gushchin, P.A., Egazar’yants, S.V., and Vinokurov, V.A., Petrol. Chem., 2019, vol. 59, no. 11, pp. 1226–1234. https://doi.org/10.1134/S0965544119110033

    Article  CAS  Google Scholar 

  7. Pérez-Pariente, J., Sastre, E., Fornes, V., Martens, J.A., Jacobs, P.A., and Corma, A., Appl. Catal., 1991, vol. 69, no. 1, pp. 125–137. https://doi.org/10.1016/S0166-9834(00)83296-0

    Article  Google Scholar 

  8. Tsaplin, D.E., Makeeva, D.A., Kulikov, L.A., Maksimov, A.L., and Karakhanov, E.A., Russ. J. Appl. Chem., 2018, vol. 91, no. 12, pp. 1957–1962. https://doi.org/10.1134/S1070427218120066

    Article  CAS  Google Scholar 

  9. Tamura, M., Shimizu, K., and Satsuma, A., Appl. Catal. A: General, 2012, vol. 8, pp. 135-145. https://doi.org/10.1016/j.apcata.2012.05.008

    Article  CAS  Google Scholar 

  10. Wu, W., Wu, W., Kikhtyanin, O.V., Li, L., Toktarev, A.V., Khabibulin, J.F., Echevsky, G.V., and Huang, J., Appl. Catal. A: General , 2010, vol. 375, no. 2, pp. 279–288. https://doi.org/10.1016/j.apcata.2010.01.003

    Article  CAS  Google Scholar 

  11. Carvalho, K.T.G. and Urquieta-Gonzalez, E.A., Catal. Today, 2015, vol. 243, pp. 92–102. https://doi.org/10.1016/j.cattod.2014.09.025

    Article  CAS  Google Scholar 

  12. Chiche, B.H., Dutartre, R., Renzo, F.D., Fajula, F., Katovic, A., Regina, A., and Giordano, G., Catal. Lett., 1995, vol. 31, no. 4, pp. 359–366. https://doi.org/10.1007/BF00808600

    Article  CAS  Google Scholar 

  13. Xia, Q.-H., Shen, S.-C., Song, J., Kawi, S., and Hidajat, K., J. Catal., 2003, vol. 219, no. 1, pp. 74–84. https://doi.org/10.1016/S0021-9517(03)00154-4

    Article  CAS  Google Scholar 

  14. Shavaleev, D.A., Pavlov, M.L., Basimova, R.A., Sadovnikov, A.A., Sudin, V.V., Smirnova, E.M., Demikhova, N.R., Grigor’ev, Yu.V., Maksimov, A.L., and Naranov, E.R., Petrol. Chem., 2020, vol. 60, no. 9, pp. 1073–1079. https://doi.org/10.1134/S0965544120090182

    Article  CAS  Google Scholar 

  15. Wang, Z., Jiang, Y., Yi, X., Zhou, C., Rawal, A., Hook, J., Liu, Z., Deng, F., Zheng, A., Hunger, M., Baiker, A., and Huang, J., Sci. Bull., 2019, vol. 64, no. 8, pp. 516–523. https://doi.org/10.1016/j.scib.2019.04.002

    Article  CAS  Google Scholar 

  16. Gonçalves, J.C. and Rodrigues, A.E., J. Chem. Eng. Data, 2013, vol. 58, no. 6, pp. 1425–1428. https://doi.org/10.1021/je400318z

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

This work was performed using equipment of the Center for Collective Use “TIPS RAS Analytical center of deep oil processing and petrochemistry.”

Funding

This study was carried out with financial support from the Ministry of Science and Higher Education of the Russian Federation (grant no. 075-15-2021-1363).

Author information

Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, 119991, Moscow, Russia

    L. A. Kulikov, S. V. Egazar’yants, A. L. Maximov & E. A. Karakhanov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    V. A. Ostroumova, E. R. Naranov & A. L. Maximov

Authors
  1. L. A. Kulikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Ostroumova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. R. Naranov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. V. Egazar’yants
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. L. Maximov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. A. Karakhanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to L. A. Kulikov or V. A. Ostroumova.

Ethics declarations

A.L. Maximov, a co-author, is the Chief Editor at the Neftekhimiya (Petroleum Chemistry) Journal. The other co-authors declare no conflict of interest requiring disclosure in this article.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kulikov, L.A., Ostroumova, V.A., Naranov, E.R. et al. Effects of MTW Zeolite Crystallite Morphology on Product Formation in Isomerization of m-Xylene. Pet. Chem. 62, 914–923 (2022). https://doi.org/10.1134/S096554412207012X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S096554412207012X

Keywords:

Search

Navigation