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Mass Transfer between Liquid and Solid Phases in the Synthesis of High-Crystallinity Granular ZSM-5 with Hierarchical Porous Structure

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Abstract

The paper investigates the mass transfer between the liquid and solid phases during the crystallization of granules that contained 60 wt % of powdered ZSM-5 and 40 wt % of amorphous aluminosilicate in a sodium silicate solution. The chemical and phase compositions and the porous properties of the resultant zeolite-containing products were identified. Based on the findings obtained, a stepwise mechanism was suggested for the synthesis of high-crystallinity granular ZSM-5 zeolite with a hierarchical porous structure.

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Funding

The study was carried out within the state assignment for IPC UFRC RAS (project no. FMRS-2022-0080). The physicochemical properties of high-crystallinity granular ZSM-5 zeolites with a hierarchical porous structure were investigated within RFBR project no. 19-33-60009. The structural investigation was carried out at the Agidel Regional Center for Collective Use of UFRC RAS within the state assignment for IPC UFRC RAS (project no. FMRS-2022-0081).

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, 450075, Ufa, Russia

    O. S. Travkina, R. Z. Kuvatova, A. Kh. Ishkildina, I. N. Pavlova & D. Sh. Sabirov

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  1. O. S. Travkina
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  2. R. Z. Kuvatova
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  3. A. Kh. Ishkildina
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  4. I. N. Pavlova
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  5. D. Sh. Sabirov
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Correspondence to O. S. Travkina.

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Travkina, O.S., Kuvatova, R.Z., Ishkildina, A.K. et al. Mass Transfer between Liquid and Solid Phases in the Synthesis of High-Crystallinity Granular ZSM-5 with Hierarchical Porous Structure. Pet. Chem. 62, 813–819 (2022). https://doi.org/10.1134/S0965544122070064

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