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Oligomerization of C5 Olefins on Amorphous Mesoporous Aluminosilicates

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Abstract

Catalytic properties of ASM amorphous mesoporous aluminosilicates with different SiO2/Al2O3 molar ratios (20, 40, 80) in oligomerization of 1-pentene and isoamylene fraction were studied. The yield of pentene oligomers is maximal on ASM-20 aluminosilicate and decreases with an increase in the SiO2/Al2O3 molar ratio. The optimum conditions for preparing 1-pentene oligomers in the maximal yield (92–94%) were determined: 150–180°C, 10% catalyst. The yields of the oligomers obtained from the isoamylene fraction on ASM-20 and ASM-40 aluminosilicates are 76 and 74%, respectively (110°C, 10% catalyst), with dimers prevailing. Comparison of the catalytic properties of ASM-20 and 40 mesoporous aluminosilicates and H-Beta zeolite in oligomerization of these monomers shows that their activity is close, but the mesoporous materials exhibit higher stability in oligomerization. In addition, ASM aluminosilicates allow preparation of oligomers with broader molecular-mass distribution.

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Funding

The study was performed within the framework of the government assignment for the Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences (theme no. FMRS-2022-0080). Studies on synthesis of pentene oligomers were performed within the framework of a Bashkortostan Republic grant for young scientists in accordance with the Order of the Head of Bashkortostan Republic no. UG-377 of July 23, 2021. Structural studies were performed at the Agidel’ Regional Center for Shared Use, Ufa Federal Research Center, Russian Academy of Sciences within the framework of the government assignment for the Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences (theme no. FMRS-2022-0081).

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  1. Institute of Petroleum Chemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, 450075, Ufa, Russia

    D. V. Serebrennikov, N. G. Grigor’eva, M. R. Agliullin & B. I. Kutepov

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  1. D. V. Serebrennikov
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  2. N. G. Grigor’eva
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  3. M. R. Agliullin
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  4. B. I. Kutepov
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Correspondence to D. V. Serebrennikov or N. G. Grigor’eva.

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Serebrennikov, D.V., Grigor’eva, N.G., Agliullin, M.R. et al. Oligomerization of C5 Olefins on Amorphous Mesoporous Aluminosilicates. Pet. Chem. 62, 896–905 (2022). https://doi.org/10.1134/S0965544122070118

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