Abstract
Semicarbazide (OC(NH2)(N2H3)) and thiosemicarbazide (SC(NH2)(N2H3)) are well-known for their coordination complex formation ability. They contain nonbonding electrons in the form of heteroatoms (N, O and S) and π-electrons in the form of >C=O and >C=S through they strongly coordinate with the metal atoms and ions. Because of their association with this property, the Semicarbazide (SC), thiosemicarbazide (TSC) and their derivatives are widely used for different applications. They serve as building blocks for synthesis of various industrially and biologically useful chemicals. The SC, TSC and they derivatives are also serve as strong aqueous phase corrosion inhibitors. In the present reports, the coordination ability and corrosion protection tendency of Semicarbazide (SC), thiosemicarbazide (TSC) and their derivatives is surveyed and described. These compounds are widely used as inhibitors for different metals and alloys. Through their electron rich sites they adsorb on the metal surface and build corrosion protective film. Their adsorption mostly followed the Langmuir adsorption isotherm. Through their adsorption they increase the value of charge transfer resistance and decrease the value of corrosion current density. Computational studies adopted in the literature indicate that SC, TSC and their derivatives adsorb flatly and spontaneously using charge transfer mechanism.
About the authors
Chandrabhan Verma works at the IRC for Advanced Materials, KFUPM, Dhahran, Saudi Arabia. He is a member of the American Chemical Society (ACS). His research is mainly focused on the synthesis and designing of environmental friendly corrosion inhibitors useful for several industrial applications. Dr. Verma is the author of several research and review articles and has edited many books. He has a total citation of more than 7400. Dr. Verma has received many awards.
Mumtaz A. Quraishi is a chair professor at IRC for Advanced Materials, KFUPM, Saudi Arabia. Before joining KFUPM, he was an institute professor at IIT-BHU, Varanasi, India. He also served as head (chairman) of Department of Chemistry IIT BHU. He has a teaching experience of more than 35 years. Dr Quraishi is a fellow of RSC and ACS. He has published more than 400 papers having a total citation of more than 28000. He has also authored and edited many books.
Dr. Kyong Yop Rhee is a professor of mechanical engineering at Kyung Hee University (South Korea) since 1999. His main research interests are nanocomposites, surface treatment, fracture, and composite materials. He has published more than 451 scientific papers and has led 67 R&D projects. His current h-index is 63. He earned his BS and MS degrees in mechanical engineering from Seoul National University (South Korea) and his PhD in mechanical engineering from Georgia Institute of Technology.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: None declared.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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