Introduction

Water purification is a technique broadly used for wastewater treatment, industrial processing, residential applications, medical treatment, and radioactive wastewater treatment1. There are many types of water purification methods including simple submerged electrolysis to complex direct current regulated power supplies to electrode potential passivation, degasification, chemical filtration, active carbon, anode consumption, cell REDOX potentials, active chlorine, ultrasonic sound devices, ultraviolet light stimulation, peroxi-coagulation, adsorption methods2, filtration, reverse osmosis, advanced membrane systems, sedimentation and a wide range of gaseous matter vessel reactions. These different methods are used to target specific types of contaminants for varying applications and have inherently different energy and resource costs.

As global temperatures continue to rise due to increasing atmospheric CO2 levels and the world’s natural resources dwindle, it is becoming increasingly important to develop water purification technologies that require minimal energy and natural resource costs. As recently as 2020, scientists studying electron bifurcation in nature made a clarion call for the building of synthetic electron manipulating machines to answer the need for clean, sustainable energy technologies3.

This study aims to explore the utility of one such device—the Quantum Kinetic Fusor™ (QKF). The system uses voltage in a purely physical process, without re-sorting to passing current through an electrolyte in a chemical interaction. The tri-coil design resonant cavity transformer uses the dielectric properties of a material acting as part of a resonant closed-loop electrical (Resistor, Inductor, Capacitor) RLC tank circuit. The tri-coil transformer (or TCT) is tuned to resonance with the dielectric properties of a suitable material, which can be water, liquid metals, ambient air or even the vacuum of space. The TCT can be a tri-coil resonating cavity transformer employing either a Maxwell or Helmholtz tri-coil design. The physical approach to electrolysis is based on voltage and not amperage to dissociate a selected dielectric medium, an approach that is 180 degrees out of phase from traditional Faraday electrolysis.

As suggested in this research, the QKF™ is an energy-efficient device that removes an array of contaminants from water, including strontium, which has historically proved resistant to traditional purification methods (Fig. 1). The carbon footprint appears to be ~99.7% lower than prior electrolyte devices. Prior art dissociation of water occurs typically between 10 and 350 mA cm−2 depending on the methods employed4. The disclosed device successfully dissociates water between 0.146 and 0.366 mA cm−2 (1.9–4 watts). With such low power consumption, this device can be operated with a 20–50 watt solar panel/charge controller and a 12 V battery. The only substantial carbon footprint is associated with manufacturing the device (machining, lathe, source material, etc.).

Fig. 1: Quantum Kinetic Fusor design.
figure 1

Coil (C1) and (C2) are respectively Helmholtz coils. Secondary step-up coil (S) laid in conjunction with Primary (P) coil determines resonant voltage to cell. Increasing (S) turn count in reference to (P) turn count increases voltage levels. Transformer tape can be positioned between coils creating an electrical stopgap. (S) and (P) coils positioned between (C1) and (C2) establish a classical Maxwellian Coil arrangement. Modular device can be arranged in series or parallel configuration. Electron Extraction is established between electrodes (20), (12) and (11) respectfully. Transparent acrylic lens (14) allows 660 nm (deep red) photon excitation from LEDs to be passed into resonant cavity and stimulates liberated gaseous matter ions in their quantum orbiting electron jumps (K, L and M shells). (17), (18) and (19) are terminal connections for electrodes and LED photon cluster array. Modular design can be stacked in series or parallel arrangement. Polarized dielectric mediums flow direction is from 15 (enter) to (exit) 16 respectively during operations.

During operation of the QKF, the primary challenge is maintaining resonance with the dielectric medium during operations. This depends on several variables, including temperature, ohmic resistance, flow rate, precipitate accumulation, electrode spacing, electrode lengths and coil turn-count ratios. A phase-lock-loop-electronic (PLL) circuit aids in the maintenance of resonance during operations5,6,7.

Three replicate resonant cavities were constructed and used to test how this electrolysis technique altered water chemistry and removed metal contaminants. Our goal was to test the behavior of two different dielectric mediums, freshwater (FW) and seawater (SW). The FW samples were sourced from a residential well to test the ability of the QKF to remove trace levels of contaminants in drinking water to evaluate if this technology would be applicable to more contaminated FW systems. Similarly, the SW was sourced from a relatively pristine coastal setting to assess trace level changes in contaminant levels to evaluate if the technology shows promise for deploying in more contaminated settings. Each resonant cavity vessel had two different sets of constructed electrodes: S/S304 (SS) electrode set, and an Aluminum 6061 (Al6061) electrode set to evaluate how electrode composition altered water purification performance and/or added dissolved metals sourced from the electrode to the treated sample. For each dielectric or electrode sets we analyzed triplicate source water blanks (SB; i.e., the source water), chamber blanks (CB; i.e., water added to the chambers without voltage applied) and treated samples (T; i.e., voltage applied). Electrolysis parameters are described in Table 1.

Table 1 The experiment input characteristics per electrode and dielectric set (bold).

A variety of water chemistry measurements were made to evaluate changes in bulk geochemistry, dissolved metals, carbonate speciation, and the stable isotopic composition of the water.

Results

Exotic photon emissions during experiments (Amptek - SiPIN - XR-100CR)

First, we describe photon signatures during the experiments to provide context on the distinct conditions occurring during water treatment. Photon signatures ranging from 1 to 20 KeV were successfully detected during all experiments (Fig. 2). Photon values were taken throughout the experiment at 1 min, 2 min, 6 h, and 8 h. This allowed photon excitation spectrum BLUE shifts to be evaluated if any. Static background radiation values were also taken between each interval to establish if radiation leaked into the dielectric and/or out of device. Background radiation values were consistent with non-radioactive contamination during off states. Radiation signatures did not linger post de-energizing of the device. Radiation signatures were only detected during unipolar pulse train input at resonance.

Fig. 2: Blue spectrum is photon emissions during operations.
figure 2

Red spectrum is radioactive 55Fe calibration sample in reference to device. a At 1 min shows strong 1 KeV emission lines at start-up with a gradual envelope falloff towards 7.5 KeV8. Spectrum b after 2 min of operations shows substantial envelope growth in photonic values at 3.5 KeV, 5.7 KeV, 6.1 KeV, 10.2 KeV and 12.5 KeV. Spectrum c after 6-h shows an even further widening of the photon emissions with distinct peaks at 1 KeV, 6.6 KeV and 14 KeV shown as dominant. It appears that maximum tapered out emissions were detected approximately between 14 and 17 KeV. Spectrum d after eight hours shows the highest maximum emission value at 18.93 KeV (RED vertical line) with strong peaks between 3.55 KeV, 6.3 Kev, 15 Kev and ~18 KeV. RED spectrum on the graphs shows the radioactive 55Fe calibration sample. Note: BLUE Spectrum values (ad) are from FW experiments and the S/ST304 electrodes. See Supplemental Fig. 3 for SW experiments.

The (B2) experiment is a radioactive 55Fe calibration sample while (1B), (3B), (4B), (5B) and (6B) are ambient lab background radiation levels while device is OFF (Fig. 3b). It appears that the radioactive 55Fe calibration sample has similar overall total emissions as the device while ON (2000–2500 counts). The raw photon data indicates both positive (+) and negative (−) photonic excitation regions. An interesting observation is the resonant ringing that occurs between ON/OFF subsequent 360 hz Gate Unipolar pulse bursts. Detected photon data seems to have characteristics associated with inner atomic electron-capture events and potentially neutron-capture events8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23, (micro-atomic cavitation). We believe that the photon emissions extend down into the UV A, B and C ranges. However, due to the beryllium lens on Amptek, the effectively attenuated detectable ranges are from 1 to 20 keV.

Fig. 3: Photonic energy values throughout the experiment.
figure 3

a The measured photon peaks over 5000 mV. Source data also shows photonic emissions in the negative regions (de-excited state) of the detector, which are consistent with elastic and inelastic Compound Nucleus renormalization54. b Summary values of the experiments in conjunction with radioactive 55Fe and ambient background data points between run-time internals. c Photonic data zoomed in, which detects transient photonic residual ringing spikes. This calibrated photon data shows atomic absorption coefficient behavior during amalgamation as the data crosses the (0 v) plane reference during OFF 360 Hz gate pulses. Note: Spectrum values (ac), are from the SW experiments using stainless steel electrodes.

Changes in electrodes weight pre and post experiments

Next, we describe changes in electrode weights to provide context on how electrode composition influences water chemistry responses to our treatment. Weight measurements were taken of electrodes sets with both S/S304 and Al6061. This was done with pre-test, chamber-blank and treated samples. The S/S304 electrode weights were taken post CB, but not with Al6061. The S/S T304 SW-T cathode recorded a weight increase by an average of 0.125 g while the anode showed an average reduction in weight by 0.424 g. FW-SS experiments showed an average cathode reduction of 0.005 g. Anode average weight reduction was 0.027 g. Al6061 electrode weight changes pre- and post-exposure to FW and SW weight values all increased except for the Cathode-2 from experiment. The average weight increase in SW-Al anodes was 0.99 g. No CB weight values were taken for FW-Al and SW-Al due to apparent redundancies (Table 2).

Table 2 Average gain (positive values) or loss (negative values) of electrode mass in grams.

Precipitate weight values vs. electrode weight lose values

Accumulation of sediments is described here to provide context on the processes driving removal of dissolved metals. Post treatment FW-SS samples visually showed light-brown and yellow sedimentation, while SW-SS showed dark brown, green, and black sedimentation. Precipitates were collected from all experiments by centrifugation of treated water.

When averaging the three FW-SS experiments, there was a net average loss when compared to the other experiments’ averages. The FW-SS experiment showed an average net weight loss of 0.0238 g over 8 hours, while SW-SS experiment showed an average weight net gain of 1.50 g. The Al6061 experiment with SW showed the largest average net gain of 1.98 g (See Fig. 4). This is consistent with prior art understanding of Al6061 as a non-transitional low redox reacting metal alloy which does not show degradation during low current density (<1 A cm−2) electrical stimulation i.e., anode pitting/cracking.

Fig. 4: Electrode and sediment mass gain and loss.
figure 4

The only experiment that showed net average loss was FW-SS, but the amount lost was negligible. The largest sediment collected was 2.68 g, which was collected from SW-SS experiment set #1. A larger sedimentation average weight gain was established with Al6061 electrodes. Trace amounts of Ag were detected on all electrodes surfaces post experiment with Al electrodes. Error bars denote ± 1 standard deviation.

Current density of electrodes, overall operational readings & smart Geiger (uS/h) Readings

The current density of the electrodes during operation is reported in order to compare the energy efficiency of this water purification approach with the current state of the art. The total current was 0.04275 A at 40 v input, which converts to 1.9 W of power. The total electro-statically active surface area of the electrodes is approximately 300 cm2 +/−5 cm2. The total current density per surface area is 0.142 mA cm−2. The current density is 126.5% lower than current electro-coagulation water purification applications24. During experimental operations the magnetic field lines fluctuated with a swing between ~100 and 300 mG - (Tri-Field Meter − 100XE). The fluxing magnetic field was induced by a constant 360 Hz-Gate frequency. Magnetic field detector was placed ~15 cm from the operating QKF device. DC electric voltage was monitored to the electrode’s anode and cathode (~3–4 V) was recorded. Once the Triplett 630-PL multi-meter selector was switched over to AC detection mode, there was a biased AC electrical voltage between the anode and Cathode-2 during operation. No AC voltage was detected between anode and cathode, just between anode and Cathode-2. Temperature of the device stayed relatively consistent (0.5 °C) with ambient environment. The temperature of the dielectric post treatment i.e., 8 h exposure was only 0.8 to 1.1 °C warmer that the outside surface of the apparatus. Smart Geiger detector was able to detect a reading of ~370 uSv h−1 during a 60-s exposure to operational device. The Smart Geiger was placed 5–10 cm away from operating core of device (Fig. 5). The Smart Geiger detector device was calibrated using 55Fe and 137Cs before and after operational use in experiments. See Supplemental Fig. 4 for calibration of Smart Geiger.

Fig. 5: Temperature and Geiger counter signatures of device before and after energizing.
figure 5

The three images are from one of the FW-AL experiments. a Shows the FLIR temperature signature of device before energizing FW-AL experiment 7/23/2021 at 5:56am. b Shows the Smart Geiger counter next to device detecting 367 uS h−1 within 60 s of exposure to operational device. c Shows FLIR temperature readings 3 h into experiment. The temperature of dielectric value was 10.5 C while the vessel was 11.5 °C. The final temperature reading after 8 h was 15.3 °C to dielectric and 15.8 °C to vessel. The device and dielectric steady increased in temperature in accordance with the ambient air within the lab.

Atomic isotopic composition & dissolved metal and ion concentration changes

Due to the photon radiation detection previously described, we decided to investigate the isotope values of water pre and post treatment. The values investigated were d18O, dD, and 3H (Fig. 6). In the natural environment, temperature is the primary control on the isotopic composition of precipitation. With increasing temperature, precipitation becomes enriched in the heavier isotopes, d18O and dD, in a linear relationship. It is also known that not only temperature, but also solar wind flux intensities are associated with cosmic radiation influences, which change aquatic d18O, dD and temperature values. The temperature of solar wind characteristics in the North and South Pole regions vs. equator regions determines d18O and dD signatures.

Fig. 6: Water stable isotope changes following water treatment.
figure 6

dD values in the a FW and b SW experiments and d18O values in the c FW and d SW experiments with stainless steel (SS) and aluminum (Al) electrodes. SW experiments show diverging patterns of dD and d18O between SS and Al electrodes. Data suggests the isotope manipulation occurs during OFF modes with CB. The box and whisker plots denote the median value (line within each box), upper and lower quartiles (top and bottom of box), and minimum and maximum values (whiskers).

There was a steady decrease in heavy isotopes of d18O, dD and even 3H post treatment. Isotopic readjustments are observable in the CB and as well as treated samples. This is also supported by a steady linear increase in pH (decreased value present of H + ions) values of water during CB and Treated water dielectrics.

FW-SS treated d18O values dropped from −13.5‰ in the source blank to −13.8‰ while dD values dropped from −97‰ in the source blank to −100‰ in the treated samples (Fig. 6). 3H showed reduction in FW-SS values of 0.58 TU to 0.53 TU. Standard deviation for Tritium Enrichment Electrolytic (TEE) is 0.25 TU. In this test, average 3H value fell by approximately 9% within just 8 hours of treatment. That is over 1% per hour of exposure to a current density of 0.142 mA/cm−2 or 1.9 watts of power. This observation is not statistically significant, however it is an observable trend that warrants further investigation due its initial small concentration value. As described previously, photon energizes average value was ~5.7 KeV while the maximum value reached was 18.4 KeV for the FW-SS experiment. This photon excitation level of this nature (1–20 KeV) is associated with 3H to Helium beta-decay events24,25,26,27,28,29,30,31,32,33,34. SW-SS d18O values showed little change. SW-SS dD values steadily decreased from −11‰ in the source blank to −12.5‰ in the chamber blank, and −14.7‰ in the treated samples. Overall trending of isotopic changes show that SS and Al electrodes reduce heavy isotopes of dD and d18O, except for the exception of SW-Al dielectric. The isotopes tend to increase dramatically with SW-Al experiments. CB has an influence on the isotopic values as well.

Changes in dissolved metal concentrations seem to be supported by the isotopic characteristic transformations in addition to photonic excitations observed. A decrease in As, Ba, and Cu were observed in FW-SS treated samples. No significant changes were observed in Cd levels, which were below the detection limit in all but one FW-SS experiments.

Pb and Al substantially increased in the chamber blanks for both SW and FW experiments with SS electrodes but did not increase in the treated samples. It is likely that the chamber blanks had these metals leached into the water, which the treatments subsequently removed. This may also be further evidence to support the notion that external E.M.F. (radio, microwave and cell phone towers) simulation to the apparatus influences dielectric renormalization. This increase within the CB was also observed with SW and FW in Zn values. More study is required to determine the exact reasons are for this phenomenon.

Cu had divergent patterns in FW and SW experiments, decreasing in FW-SS and increasing in SW-SS. Cu levels increased in the chamber blank during the 8-hour soak with SW-SS. Ni values increased in FW-SS by 212–239 µg L−1 (Tables 34). In addition, Ni in the SW-SS experiment increased by 10,581 µg L−1, which is likely related to electrode pitting, whereas Ni only marginally increased in the FW-Al experiment by 0.334 µg L−1. In the SW-Al experiment the values of Ni were too low to detect.

Table 3 Change in metal concentrations (µg L−1) following treatment measured by ICP-OES.
Table 4 Change in metal concentrations (µg L−1) following treatment measured by ICP-MS.

K concentrations were elevated only SW experiments, whereas slight decreases were observed in the FW experiments. SW-SS experienced an increase in potassium levels by 3643 µg L−1 and SW-Al detected an increase of 7167 µg L−1. Salinity was reduced by 1.8% in SW-Al while SW-SS dropped by 3%, perhaps related to the large decrease in observed dissolved Mg concentrations (Table 3). The reduction of salinity and the increase of potassium are, potentially, due to a transmutation metabolic ATP cycling i.e. [Na + O + H+ = P] byproduct. This suggests a type of synthetic stimulated photosynthetic process35. See Table 3, Supplemental Figs. 5 and 6. Ca values decreased in all experiments and Ca ions were collected/observed on the cathode post experiments for both Al and SS electrodes. FW-SS showed a slight increase in Ag. Very slight increases in Se were observed in the FW-SS treated samples compared to a slight decrease in the treated FW-Al samples. It should be noted that Ag, Ca and Cl was detected on all Al electrode surfaces post experiment. We observed arsenic reduction of 93.7% and strontium reduction of 13% in the FW-SS experiment.

Post experiments of FW-Al, we observed and collected paramagnetic sedimentation from electrodes to be composed of trace elements comprising of Re, Yb, Sn, Ag, Nb, Zr, Ni, Br, Zn, Ni, Fe, Ti, V, Cr, In, Si, Pb, and S. C saturation values of paramagnetic sediment was between 88.6 and 12.8%36,37,38,39,40. A titanium-vanadium nano-sphere was also detected in the paramagnetic sedimentation post experiment with FW-Al (Fig. 7a).

Fig. 7: SEM and EDS values post-treatment for the FW-Al experiment paramagnetic sediment.
figure 7

a Shows the nano-sphere of titanium-vanadium b is the EDS spectrum of the nano-sphere. c Is the overview SEM image of sediment on carbon tray d is the overview SEM image of sediment group 2 on the carbon try. e Shows the spectrum analysis of specimen 34 (f) while depicts the spectrum analysis of specimen 43.

Changes in Water pH Levels

For FW samples, we observed a steady increase in pH values throughout the experiments with both SS and Al electrodes (Fig. 8). On the other hand, a drop in pH was detected when SW dielectric was energized. This occurred with both SS and Al electrodes in SW. The pH elevation during FW experiments is expressed as H + ions either off gassed as hydrogen from the resonant cavity or some other ionic exchange or atomic reaction or FW carbonate buffering destabilizations. Regardless, SW pH significantly acidifies, which shifts the carbonate system towards CO2. More study is necessary to confirm the potential of biosphere purification applications of the QKF device. Data does suggest that, at some level, biological index stimulation values increase post treatment. CDOM (non-filterable organic matter), BIX, humic matter, fluorescence, and cyanobacteria values increased in both Al and SS with SW experiment. See Supplemental Figs. 5 and 6.

Fig. 8: Shifts in pH following treatment.
figure 8

pH values of experiments with FW and SW with two different electrode compositions i.e., SS and Al. a Depicts the FW and SW samples treated with stainless steel electrodes. b Depicts the FW and SW samples treated with aluminum electrodes. The box and whisker plots denote the median value (line within each box), upper and lower quartiles (top and bottom of box), and minimum and maximum values (whiskers).

SW water samples for both electrode types showed complete removal of calculated CO3 values with HCO3 values dropping by approximately 50%. Calcite (CaCO3) was deposited on cathode and Cathode-2 of the electrodes set in all Al experiments. See Supplementary Fig. 10. Calculated CO2 values increased accordingly during SW experiments with both the SS and Al electrodes.

The device increases pH levels of SW and FW. This is further evidence of free H + ions interacting via isotopic re-arrangement within the device. This apparatus can be used to renormalize pH levels of rivers, ground water, and even ocean water. Evidence suggests that pH levels rise even during CB experiments with SW-SS (no power and not connected to electrical mains).

Discussion

The electro-transmutation (ET) device described here shows promise in industries associated with isotopic water purification, energy harvesting, element transmutation, and in radioactive wastewater treatment. Results indicate that utilization of the resonant magnetic fields focused in conjunction with electrostatic temporal flux lines aid in dissociation of water, both FW and SW, with no electrolyte present. Current density levels are unprecedentedly low (0.142 mA cm−2) as compared to prior art technologies in these sectors, even cell membrane devices41. It is open for discussion that this might be a synthetically driven mechanical hydrostatic carbon burning process (synthetic gravity). This postulation is driven by the increase in carbon, silver, sodium, magnesium, titanium, lead, and oxygen present upon dried electrodes. SEM values detect nanostructures associated with metal hydrides including a hyper magnetic meteorite characteristic-like black rock post treatment. However, more study is necessary to confirm these findings.

The resonant electro-transmutation process is most likely caused by electrode intra-band electron transitions interacting with the dielectric medium’s free electron intra-band known as space-charge polarization. A free particle may absorb/emit a photon, thereby remaining free. This means, the field interacts only with the scattering part of the one-particle spectrum. In solids, this corresponds to intra-band transitions. Absorption of a photon also leads to excitation of a bound particle into the continuum, i.e. to photo-ionization, (or to recombination in case of emission of a photon) Finally, Absorption/emission of a photon leads to transitions of a particle in the discrete part of the spectrum, from one level (band) to another42. The resonance electro-transmutation Space-Charge Polarization induces emission/absorption of photons to become trapped and/or exchange intra-bands electron transitions i.e., transmutation between solids (electrodes) and interfacing liquids (dielectric mediums). This would be classified as a Quantum Thermodynamic reaction.

Radiation signatures associated with these values are typically signatures associated with tritium to helium-3 β+ elastic scattering, solar winds (1 KeV), carbon ion flux (12 KeV), and inelastic scattering interactions (x-process: cosmic-ray-spallation i.e. 5.66 KeV). It should be noted that, “stellar cores possess high enough temperatures for the thermal excitation of low-energy nuclear levels of magnetic type (~1 KeV scale), which could emit axions during the de-excitation (g-an coupling)”. These research findings suggest that element fusion is being produced in the resonant cavity. After all, particle accelerators, which fuse light elements together, share similar soft x-ray emissions within cyclotrons and synchrotron43 during atomic syntheses procedures.

This is suggestive of positron atomic tritium ± beta-decay events. Rare, morphological heavy metallic, were detected post treatment indicating an atomic or low energy yield nuclear event is occurring inside the resonant cavity. The ET products and byproducts have shown to be a variety product including and not limited to: hydrogen powered propulsion engines/rockets, carbon sequestering, carbonaceous chondrite magnetite formation, pollution treatment, nano-oxide shapes including spheroids, hexagons, cubes and quasi-crystals; wastewater remediation, simulation of 4th phase of water44, magneto-tactic bacteria enlargement, nano-sphere magnetite technology for stealth coatings (RAM), phytoplankton stimulation, hydrides, radioactive tritium harvesting/purification and more. See Supplemental Figs. 7 and 8. Prior to these SW and FW test experiments, the resonant cavities devices were tested with a CO2 gas injection (3–5 psi) with distilled water as the dielectric between electrodes. Transparent paramagnetic crystallization of CO2 graphite morphologies was discovered post treatment45. See Supplemental Fig. 9.

The range of technological applications of this system is only limited by the human imagination. Again, more testing and research are required to confirm and re-confirm these findings and discoveries. Additional research should be focused on deuterium oxide dielectric mediums.

This research suggests that the illusive Zitterbewegung wobbling architecture of the electron can be tapped into mechanically through ET effects (nano-technology electron cavitation events – negative differential electron pressures). As such, it may be a viable alternative to the star building fusion device(s) currently in development around the world46, that rely on the violent smashing together of atoms at extreme velocities and at temperatures potentially too intense to control safely and efficiently. Rather, the ET method proposed here entails a naturally gentle approach to electron transmutation by relying upon low temperature, low energy inputs simulating nature’s own transformation schemes. This approach may provide a basis for greater optimism for a clean and abundant energy future, as well as an alternative method for water isotopic purification on a universal scale47,48,49.

Here we demonstrate one potential application for the resonant electro-transmutation (ET) process in a heterodyne stance with the Quantum Kinetic Well™. Based on a series of experiments we demonstrate that the ET process can effectively influence changes in the isotopic composition of both freshwater and seawater. Likewise, the process removed a variety of contaminants such as arsenic from water. These outcomes are accomplished using an unprecedentedly low current density value of 0.142 mA cm−2. Thus, the technology shows promise for being an efficient means for purifying water for a variety of purposes. Future research should examine how the ET process modifies the chemistry of water with diverse chemistries. For example, we observed purification of relatively pristine water sources, effectively removing trace levels of certain elements. A key question remains as to how this process functions as contaminant levels increase and likewise how scalable is the technology to handle large quantities of water? Finally, these preliminary findings suggest that in addition to showing promise for water purification applications, the ET process may be applicable to a variety of other industrial applications, including stand-alone, pristine energy generation systems, which should be explored in the future studies.

Methods

Quantum kinetic fusor device

The QKF™ device is a modular designed resonant cavity machined out of polyoxymethylene Delrin (Acetal) material (Fig. 1; 13) (Interstate Plastics). The device is 6-inches in diameter and 6-inches tall. Externally, the design houses the tri-coil resonant coils, while internally seated two (anode 11 & cathode 12) electrodes in a proportional linear stance. Delrin (Acetal) 13 acts as an insulating material and a stable neutron moderator during operations. The tri-coils (C1, C2, and S) are composed of either magnetic copper wire (TEMCo Industrial LLC) or resistive stainless steel wire (SANDVIK – Alloy Kanthal A-1) coil wrapped around the external cavities of the modular Delrin housing. A Helmholtz or Maxwell coil (S, P, C1, and C2) stance can be arranged around the electro-conductive electrodes 12, 11, and 20, which is typical Stainless Steel T304 (Fig. 1). Many other electrode materials may be used to form unique oxide nanostructures. Acrylic lens 14 holds a fabricated LED cluster array (30 × 5 mm LEDs) concentrically beneath the electrodes 11, 12, and 20 respectfully. LED cluster array is pulsed in sync with primary coil P unipolar pulse bursts into the QKF™. This effect enhances and causes inner atomic emission/absorption of the electron of the hydrogen atoms to further promote dissociation of dielectric medium such as water. This also aids in targeting not just liquids, solids but also gaseous matter targets50,51.

The positive electrode, i.e., anode is constructed from a seamless S/S - T304 seamless tube with an outer diameter of 1.9 cm that is 10.1 cm long (Shanghai Baoluo Stainless Steel Tube Co., LTF). The negative electrode, i.e., cathode is 1.3 cm diameter round bar stock S/S - T304 with a length of 12.7 cm. Longitudinal gap spacing between electrodes is ~0.16 cm. A second cathode tubular 2.5 cm outer diameter electrode is placed on the outside of the anode with a gap spacing of ~0.32 cm. This electrode is referred to as Cathode-2 electrode. The QKF’s current density is 0.142 mA cm−2 (i.e., total electrode surface area of 300.09 cm2). A Delrin cap is placed over the electrodes to limit electrostatic charge leakage throughout the dielectric medium. The non-conducting Delrin cap also aids in buoyancy trapping of dissociated (ionized) gaseous matter from liquid dielectrics such as protium, deuterium, tritium, oxygen-16, nitrogen, neon, argon and oxygen-18 for a secondary electrode exposure i.e. recycling exposure effect52. This allows for an atomic-recycling effect; in which liberated gaseous matter is re-exposed to electrically energize electrostatic and magnetic field lines. See Supplemental Fig. 1.

Operational resonant frequencies can vary from 1 Khz to 1 Mhz depending on the coil turn counts, waveguide size-length ratios and the cavity’s coil ohmic values.

This apparatus utilizes electrical phenomenon including electron spin rate disturbances, Electrostatic/Magnetic Bremsstrahlung, Zitterbewegung 11, Stark effect, Auger effect, Zeeman effect, Quantum Tunneling and Hall effects, Electron Bifurcation Destabilization 12, Compound Nucleus, Elastic, and Inelastic atomic electron scattering. The physical force of the electrons within the “closed-loop” resistive, inductive capacitive tri-coil transformer (T.C.T.) circuit utilizes a low power on-demand approach to dissociate dielectric medium(s) of liquid, air, and metallic liquids.

In addition to the unipolar inputs to the device, a new form of electrical input is also superimposed (heterodyne mixing) onto/into the voltage zones (Radiotron). This negative differential electron pressure relies on The Quantum Kinetic Well™ (USPTO# 11,233,421 - track-one status, issued 1/25/2022) 13. See Supplemental Fig. 2. The resonant electrostatic force(s), during operations, manufacture a fluxing perpendicular bisector uniform magnetic field superimposed onto the electrodes surface (free electrons) by the resonating tri-coil transformer (TCT) wires during operations. Dielectric electron cloud bifurcation matrices are agitated and ultimately plucked (i.e., micro-cavitated) at the quantum level by electric and magnetic field lines (Poynting Vectors) directly into the dielectric within a resonant closed-loop TCT circuit. The fluxing field lines create a Fluxing-Capacitor effect between the two excited electrodes. This physical phenomenon promotes radioactive atomic destabilization/renormalization E.M.F. work to be done with little to zero amperage in flux from the pulsing power supply. This can be referred to as photodisintegration radiation or dielectric cavitations, which are induced from resonant standing wave motion, not by ground-state electric current i.e., amperage, but from cavitating negative differential electron transient pressure of the dielectric substance.

Simply attenuate the power supply voltage (Powerstat Variable Autotransformer - Type 21) to enhance the probability of the temporal polarization perturbations i.e., electron-capture (dielectric cavitation) events. This process can be classified as a mechanical electro-physical Electron-Pump or Electrostatic Venturi. For further details of operations please refer to submitted utility patent documents 20210156037 - USPTO. See Table 1 for electrolysis parameters.

Experimental design

Electrolysis experiments were run in triplicate with freshwater collected from a residential well in western Washington state, USA, representing a potable water source, and seawater collected from Sequim Bay in western Washington state, USA, representing a relatively pristine marine setting with limited human-derived pollution. Well water was filled from a residential tap. The seawater was collected from the Pacific Northwest National Laboratory’s seawater intake located at the bottom of Sequim Bay. The fresh and saline source waters were collected in 10 L carboys that were soaked in MilliQ water for 24 h, rinsed with MilliQ, and again rinsed with the source water prior to collection. Electrode sets were soaked in nitric acid for 1 h followed by MilliQ water soak for 24 h pre-experiment run. For each experiment, a source water blank, was collected in which water from the carboy was directly placed into bottles for analytical measurements. This served as an indicator for pre-treatment water chemistry. A chamber blank was also collected for each experimental replicate, whereby the source water was soaked in the experimental chamber for an equivalent period as the electrolysis experiment (8 hours) with no voltage applied to the electrodes to evaluate any chemical changes related to exposure to the chamber materials. Finally, electrolysis experiments were conducted for 8 h.

A 500 mL amber HDPE bottle soaked and rinsed with MilliQ water was used for measurements of the stable isotopic composition of water (i.e., dD and d18O), pH, alkalinity (and associated calculations of carbonate speciation) and conductivity (and associated calculations of salinity). A 250 mL Teflon bottle, pre-cleaned in hot concentrated nitric acid (85 °C) and rinsed with deionized water, was used for dissolved metal samples. The following abbreviations are used throughout this manuscript to refer to each experimental sample: FW-SB = Freshwater Source Blank; FW-CB = Freshwater Chamber Blank; FW-T = Freshwater Treated Sample; SW-SB = Seawater Source Blank; SW-CB = Seawater Chamber Blank; SW-T = Seawater Treated Sample. Additionally, the qualifiers SS and AL indicate experiments performed with stainless steel and aluminum electrodes, respectively.

Analytical methods

Prior to removing solids from the samples, freshwater samples were analyzed for pH and electrical conductivity using an Oakton PCTSTestr 50 meter. For seawater samples, pH, Alkalinity, and conductivity were measured using a Mettler Toledo T7 auto titrator. Seawater conductivity was converted to salinity in practical salinity units (PSU). Carbonate speciation was calculated based on the pH and alkalinity data using CO2sys software53.

Samples collected in the amber HDPE bottles were filtered with GF/F filters (nominal pore size of 0.7 µm) for isotopic analyses. A portion of the filtrate was added to combusted 40 mL amber glass vials for analysis of water stable isotopic composition using a Los Gatos Research Liquid Water Isotope Analyzer. These samples were also analyzed for dissolved organic carbon (DOC) concentrations using a Shimadzu Total Carbon Analyzer.

Samples collected in the Teflon bottles were centrifuged in nitric acid cleaned 50 mL centrifuge tubes and the liquid fraction was decanted into clean tubes and acidified to 1% nitric acid for preservation and metals analyses. The solids were dried at 80 °C for 24 h and weighed. The liquid samples were analyzed for major ions and trace metals via ICP-OES (Perkin Elmer Optima 7300) and ICP-MS (Thermo Elemental iCAP Q with SeaFast sample introduction system).

To evaluate the operating conditions of the device and potential mechanisms underlying the observed water chemistry changes during the experiments, an Amptek SiPIN - XR-100CR detector was used to detect photon signatures ranging from 1 KeV to 20 KeV. The XR-100CR was placed 2–5 cm away from the device at a ~45° angle upwards towards the device’s under-belly. Before each experimental session, the XR-100CR was calibrated with a 60-s exposure to a small sample of radioactive 55Fe and checked with background radiation values. The radioactive 55Fe spectrum calibration can be seen in Fig. 2 as the red spectrum peak at 6.2 KeV. In addition to the XR-100CR detector, the Enshey Smart Geiger Counter Nuclear Radiation Dosimeter was calibrated before and after experiments with an exposure of 60 s to samples of 55Fe and 137Cs. See Supplemental Fig. 4.

Post experiment, electrodes were rinsed with MilliQ water and gently scrubbed with sterilized gloves to remove sediment. Electrode sediment was dried for 24 h in a cell strainer 40 um micro-filter. Dried sediment and rinsed electrodes were then analyzed with Electron-Dispersive X-Ray Spectroscopy (EDS) (Oxford X-max80) and Scanning Electron Microscope SEM (Apreo VP—Thermofisher Scientific). The University of Washington’s Molecular Analytics Facility SEM evaluated dried sediment from post treatments and electrode analysis. Sediment and electrodes weight measurements were conducted with a lab grade LEADzM Electronic Scale: model #B073CFGSZL with a tolerance of 0.002±.