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Stimuli-responsive metal–organic frameworks enabled by intrinsic molecular motion

Synthetic stimuli-responsive systems have become increasingly sophisticated and elegant at the nanoscale. This Comment discusses how rationally designed molecular systems capable of dynamic motions can be deployed in macroscopically porous metal–organic frameworks and respond to various stimuli.

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Fig. 1: Rationally designed SR-MOFs.
Fig. 2: Stimuli-responsive peptide-MOFs.
Fig. 3: Dynamic characterizations of SR-MOFs.
Fig. 4: Potential applications of SR-MOFs.

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Acknowledgements

This work was supported by the Ministry of Education - Singapore (MOE2018-T2-2-148, MOE2019-T2-1-093), the Energy Market Authority (EMA-EP009-SEGC-020), and the Agency for Science, Technology and Research (U2102d2004, U2102d2012).

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Correspondence to Jinqiao Dong or Dan Zhao.

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Nature Materials thanks Stefan Kaskel and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.

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Dong, J., Wee, V. & Zhao, D. Stimuli-responsive metal–organic frameworks enabled by intrinsic molecular motion. Nat. Mater. 21, 1334–1340 (2022). https://doi.org/10.1038/s41563-022-01317-y

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