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Crystal Structure and Optical Properties of New Hybrid Halobismuthates of 2,2'-Bipyridinium Derivatives

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Abstract

New hybrid 2,2'-bipyridinium halobismuthates ([bipyH]+) (I and II), 7,8-dihydro-6H-dipyrido[1,2-a:2',1'-c][1,4]diazepine-5,9-diium ([bipyC3]2+) (III), 6,7,8,9-tetrahydrodipyrido[1,2-a:2',1'-c][1,4]diazocin-5,10-diium ([bipyC4]2+) (IV), and 1,1'-(pentanediyl)bis(2,2'-bipyridinium) ((bipyH)2C5]4+) (V) have been isolated and characterized by X-ray diffraction. The structure of I contains a monoprotonated cation 2,2'-bipyridinium and the isolated [Bi2Br10]4– anion. 2,2'-Bipyridinium bromobismuthate II contains a polymeric anion and is isostructural to the previously described iodobismuthate. Bromobismuthate III includes [BiBr6]3– anions and water molecules. Iodobismuthate [bipyC3]2[Bi2I10] (VI) is isostructural to IV. The structure of V contains [(bipyH)2C5]4+ cations and three types of anions: [Bi2Br10]4–, [BiBr6]3–, and Br–. Compounds I, III, and VI have been isolated in pure form. The values of the optical band gap for them are 2.84, 2.88, and 2.11 eV, respectively.

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ACKNOWLEDGMENTS

The studies were carried out using the equipment at the Center for Collective Use of the Physic Methods of Investigation of the Kurnakov Institute of General and Inorganic Chemistry RAS, which operates with the support of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry RAS in the field of fundamental scientific research, and the Center for Collective Use of the Nesmeyanov Institute of Organoelement Compounds RAS.

Funding

The work was carried out within the framework of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental scientific research.

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Authors and Affiliations

  1. National Research University Higher School of Economics, 101000, Moscow, Russia

    S. P. Balabanova, P. A. Buikin & V. Yu. Kotov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    P. A. Buikin, A. B. Ilyukhin & V. Yu. Kotov

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    P. A. Buikin & A. A. Korlyukov

  4. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. Yu. Rudenko

  5. National Research Center “Kurchatov Institute, 123182, Moscow, Russia

    P. V. Dorovatovskii

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  1. S. P. Balabanova
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Correspondence to P. A. Buikin.

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Translated by V. Avdeeva

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Balabanova, S.P., Buikin, P.A., Ilyukhin, A.B. et al. Crystal Structure and Optical Properties of New Hybrid Halobismuthates of 2,2'-Bipyridinium Derivatives. Russ. J. Inorg. Chem. 67, 1018–1024 (2022). https://doi.org/10.1134/S0036023622070038

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