Skip to main content
Log in

Plasma-Chemical and Reactive-Ion Etching of Silicon in Tetrafluoromethane with Argon

  • Published:
Russian Microelectronics Aims and scope Submit manuscript

Abstract

An experimental study is conducted of the influence of the etching time and external parameters of the discharge (bias potential, input power, gas pressure) on the etching rate of silicon in a CF4/Ar mixture. It is shown that the silicon etching process proceeds in the stationary mode. It is found that when a bias potential (–100 or –160 V) is applied to the substrate holder, the silicon etching rate increases significantly.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.

Similar content being viewed by others

REFERENCES

  1. Galperin, V.A., Danilkin, E.V., and Mochalov, A.I., Protsessy plazmennogo travleniya v mikro- i nanotekhnologiyakh (Plasma Etching Processes in Micro- and Nanotechnologies), Timoshenkov, S.P., Ed., Moscow: BINOM, 2018.

    Google Scholar 

  2. Danilin, B.S. and Kireev, V.Yu., Primenenie nizkotemperaturnoi plazmy dlya travleniya i ochistki materialov (Application of Low-Temperature Plasma for Etching and Cleaning of Materials), Danilin, B.S., Ed., Moscow: Energoatomizdat, 1987.

    Google Scholar 

  3. Svettsov, V.I. and Efremov, A.M., Vakuumnaya i plazmennaya elektronika: ucheb. posobie (Vacuum and Plasma Electronics, The School-Book), Ivanovo: Ivan. Gos. Khim.-Tekhnol. Univ., 2003.

  4. Pivovarenok, S.A., Effect of Ar and He additives on the kinetics of GaAs etching in CF2Cl2 plasma, Russ. Microelectron., 2017, vol. 46, no. 3, pp. 211–215.

    Article  Google Scholar 

  5. Pivovarenok, S.A., The effect of an N2 additive on the GaAs etching rate in CF2Cl2 plasma, Russ. Microelectron., 2019, vol. 48, no. 4, pp. 236–239.

    Article  Google Scholar 

  6. Pivovarenok, S.A. and Korol’kova, K.A., Effect of external discharge parameters on polyimide etching rate, in Sbornik tezisov dokladov na III Vserossiiskoi molodezhnoi konferentsii Uspekhi khimicheskoi fiziki (Proceedings of the 3rd All-Russia Youth Conference on Achievements of Chemical Physics), Moscow: Granitsa, 2016, p. 124.

  7. Christophorou, L.G., Olthoff, J.K., and Rao, M., Electron interactions with CF4, J. Phys. Chem. Ref. Data, 1996, vol. 25, no. 5, pp. 1341–1388.

    Article  Google Scholar 

  8. Christophorou, L.G. and Olthoff, J.K., Electron interactions with plasma processing gases: An update for CF4, CHF3, C2F6, and C3F8, J. Phys. Chem. Ref. Data, 1999, vol. 28, no. 4, pp. 967–982.

    Article  Google Scholar 

  9. Efremov, A.M., Kim, D.P., and Kim, C.I., Effect of gas mixing ratio on gas-phase composition and etch rate in an inductively coupled CF4/Ar plasma, Vacuum, 2004, vol. 75, no. 2, pp. 133–142.

    Article  Google Scholar 

  10. Zhang, D. and Kushner, M.J., Mechanisms for CF2 radical generation and loss on surfaces in fluorocarbon plasmas, J. Vacuum Sci. Technol. A, 2000, vol. 18, no. 6, pp. 2661–2668.

    Article  Google Scholar 

  11. Efremov, A.M., Pivovarenok, S.A., and Svettsov, V.I., Plasma parameters and etching mechanisms of metals and semiconductors in hydrogen chloride, Russ. Microelectron., 2009, vol. 38, no. 3, pp. 147–159.

    Article  Google Scholar 

Download references

Funding

This study was carried out as part of a state task for the implementation of research; subject no. FZZW-2020-0007. The study was carried out using the resources of the Center for Shared Use of Scientific Equipment of the ISUCT (with the support of the Ministry of Science and Higher Education of Russia, grant no. 075-15-2021-671).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to D. B. Murin.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Murin, D.B., Pivovarenok, S.A. & Kozin, A.S. Plasma-Chemical and Reactive-Ion Etching of Silicon in Tetrafluoromethane with Argon. Russ Microelectron 51, 243–246 (2022). https://doi.org/10.1134/S106373972203009X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S106373972203009X

Keywords:

Navigation