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A study for the selection of NPE-free cocktails for LSC routine measurements

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Abstract

In this paper a study for the selection of an NPE (nonylphenol ethoxylates)—free cocktail is discussed in order to be used for our routine liquid scintillation counting measurements. The NPE are added in the REACH (Registration, Evaluation, Authorization and Restriction of Chemicals)—list of amendments to Annex XIV, as chemicals which can’t be used anymore (Commission Regulation (EU) 2017/999). Nine NPE-free cocktails were bought from different producers and investigated with respect to the homogeneity, background level and influence on counting efficiency for different radionuclides. Several sample matrices were considered for direct measurement of 3H and 14C. Based on this study we could select the best cocktail which fulfills our requirements for routine analyses.

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References

  1. Hou X (2018) Liquid scintillation counting for determination of radionuclides in environmental and nuclear application. J Radioanal Nucl Chem 318(3):1597–1628

    Article  CAS  Google Scholar 

  2. L’Annunziata FM (1998) Handbook of radioactivity analysis. Academic Press, San Diego

    Google Scholar 

  3. Varlam C, Vagner I, Faurescu D (2019) Performance of nonylphenol-ethoxylates-free liquid scintillation cocktail for trtium determination in aqueous samples. J Radioanal Nucl Chem 322:585–595

    Article  CAS  Google Scholar 

  4. Commission Regulation (EU) 2017/999 of 13 June 2017, amending Annex XIV to Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)

  5. Broda R, Cassette P, Kossert K (2007) Radionuclide metrology using liquid scintillation counting. Metrologia 44:S36–S52

    Article  CAS  Google Scholar 

  6. Tarancón A, Bagán H, García JF (2017) Plastic scintillators and related analytical procedures for radionuclide analysis. J Radioanal Nucl Chem 312–314:555–572. https://doi.org/10.1007/s10967-017-5494-5

    Article  CAS  Google Scholar 

  7. Lluch E, Barrera J, Tarancón A, Bagán H, García JF (2016) Analysis of 210Pb in water samples with plastic scintillation resins. Anal Chim Acta 940:38–45

    Article  CAS  Google Scholar 

  8. Bagán H, Tarancón A, Rauret G, García JF (2011) Radiostrontium separation and measurement in a single step using plastic scintillators plus selective extractants. Application to aqueous sample analysis. Anal Chim Acta 686:50–56

    Article  Google Scholar 

  9. Tarancón A, García JF, Rauret G (2004) Determination of beta emitters (90Sr, 14C and 3H) in routine measurements using plastic scintillation beads. Nucl Inst Methods Phys Res A 516:602–609

    Article  Google Scholar 

  10. Bagán H, Tarancón A, Rauret G, García JF (2011) Mixture quantification using PLS in plastic scintillation measurements. Appl Radiat Isot 69:898–903

    Article  Google Scholar 

  11. L’Annunziata FM (2020) Handbook of radioactivity analysis, Volume 1: Radiation Physics and Detectors, 4th Edition, Chapter 6, pp 742–748

  12. Verrezen F, Loots H, Hurtgen C (2008) A performance comparison of nine selected liquid scintillation cocktails. Appl Radiat Isot 66:1038–1042

    Article  CAS  Google Scholar 

  13. L’Annunziata FM (1998) Handbook of radioactivity analysis, Chapter 7, pp 411–413, ISBN 0-12-436255-9

  14. https://www.meridian-biotech.com/which-cocktail

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Acknowledgements

The authors would like to thank to the LSC laboratory colleagues and to Laura Vercammen since most of the laboratory work was performed during her internship.

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Correspondence to M. Vasile.

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Vasile, M., Loots, H., Vercammen, L. et al. A study for the selection of NPE-free cocktails for LSC routine measurements. J Radioanal Nucl Chem 331, 3349–3357 (2022). https://doi.org/10.1007/s10967-022-08405-y

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  • DOI: https://doi.org/10.1007/s10967-022-08405-y

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