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Effect of Pressure on the Temperature Dependence of the Effective Thermal Conductivity of Gallium Antimonide with Different Degrees of Ordering

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Abstract

The results of experimental measurements of the temperature dependence of the effective thermal conductivity of various forms of gallium antimonide (single crystal, polycrystals) are analyzed. The thermal conductivity is measured by the absolute steady-state method in the temperature and pressure ranges 273–423 K and 0.1–350 MPa, respectively. For polycrystalline compounds, the temperature dependence of the effective thermal conductivity in the entire investigation range is shown to decrease with pressure, retaining a pronounced power-law character. The pressure dependences of both the relative effective thermal conductivity at a fixed temperature and the dependence of the relative change in the power-law coefficient of the temperature dependence within the experimental error could be approximated by two-parameter power functions. A description of the PT dependence of the effective thermal conductivity in the entire investigation range is proposed, for which the correlative relationship of the pressure components is found. The anomalous behavior of the temperature dependence of the thermal conductivity of a single-crystal GaSb sample with an increase in pressure is revealed, for which a significant increase in the absolute value of the power-law coefficient of the temperature dependence is observed up to ~1.5 at P = 330 MPa. The pressure dependences of the effective thermal conductivity demonstrate a significantly greater and nonlinear relative increase in the thermal conductivity compared to a single crystal, which indicates a large contribution to the effective thermal conductivity of the grain boundaries.

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ACKNOWLEDGMENTS

The paper is dedicated to the memory of Prof. S.N. Emirov (1935–2020).

Funding

The work was carried out within the framework of planned topics of the state assignment at the Institute for Geothermal Research and Renewable Energy, a Branch of the Joint Institute for High Temperatures, Russian Academy of Sciences, with partial support from the Russian Foundation for Basic Research (grant no. 20-08-00319a).

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Authors and Affiliations

  1. Institute for Geothermal Research and Renewable Energy, a Branch of the Joint Institute for High Temperatures, Russian Academy of Sciences, 367030, Makhachkala, Russia

    R. M. Aliev, A. A. Aliverdiev & V. D. Beybalaev

  2. Dagestan State Technical University, 367003, Makhachkala, Russia

    R. M. Aliev & E. N. Ramazanova

  3. Dagestan State University, 367025, Makhachkala, Russia

    A. A. Aliverdiev & V. D. Beybalaev

  4. National Research University of Information Technologies, Mechanics and Optics, 197101, Saint Petersburg, Russia

    Yu. P. Zarichnyak

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  1. R. M. Aliev
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  2. A. A. Aliverdiev
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  3. Yu. P. Zarichnyak
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  4. E. N. Ramazanova
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  5. V. D. Beybalaev
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Correspondence to A. A. Aliverdiev.

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We declare that we have no conflict of interest.

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In memory of Subkhanverdi Nurmagomedovich Emirov, Doctor of Engineering Sciences.

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Aliev, R.M., Aliverdiev, A.A., Zarichnyak, Y.P. et al. Effect of Pressure on the Temperature Dependence of the Effective Thermal Conductivity of Gallium Antimonide with Different Degrees of Ordering. J. Surf. Investig. 16, 338–342 (2022). https://doi.org/10.1134/S1027451022030211

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